JHU X-ray Crystallography Facility


"All we have discovered is that it starts with a single individual - always a child - and then spreads explosively, like the formation of crystals round the first nucleus in a saturated solution." Arthur C. Clarke (Childhood's End, 1953)


Dr. Maxime A. Siegler

X-ray Facility Manager
Small-Molecule Crystallography (Service)

Rooms 240 (Office), 211 (X-ray lab), New Chemistry Building
Phone: 410 516 8569
Fax: 410 516 7044
Email: xray@jhu.edu

Ph.D. Dissertation - link

Education

2007 Ph.D., University of Kentucky, Lexington, KY, USA
2002 B.S./M.Sc., Hautes Études d'Ingenieur, Lille, France

Publications




2024

  • 353 | P. K. Hota, S. Panda, H. Phan, B. Kim, M. A. Siegler, K. D. Karlin
    Dioxygenase Chemistry in Nucleophilic Aldehyde Deformylations Utilizing Dicopper O2-Derived Peroxide Complexes
    J. Am. Chem. Soc. (2024), , - link
  • 352 | J. S. Wagner, M. A. Siegler, Aimée. L. Tomlinson, J. R. Reynolds
    Controlling Charged State Colors in Triphenylamine-Based Anodically Coloring Electrochromes
    Adv. Opt. Mater. (2024), , - link
  • 351 | S. Abyar, L. Huang, Y. Husiev, L. Bretin, B. Chau, V. Ramu, J. Hendricus Wildeman, K. Belfor, L. S. Wijaya, V. E. van der Noord, A. C. Harms, M. A. Siegler, S. E. Le Dévédec, S. Bonnet
    Oxygen-Dependent Interactions between the Ruthenium Cage and the Photoreleased Inhibitor in NAMPT-Targeted Photoactivated Chemotherapy
    J. Med. Chem. (2024), 67, 11086-11102 - link
  • 350 | M. Wang, N. Garrison, P. Minh Nguyen, A. Prasad, Y. Wang, H-K. Kwon, G. Kim, M. A. Siegler, T. Lectka
    Can the −CF3 Group Act as a Tight, Well-Defined Hydrogen Bond Acceptor? A Clear Crystallographic CF2–F···H–N+ Interaction Says Yes
    J. Org. Chem. (2024), 89, 9681-9685 - link
  • 349 | A. T. Stoltzfus, J. G. Ballot, T. Vignane, H. Li, M. M. Worth, L. Muller, M. A. Siegler, M A. Kane, M. R. Filipovic, D. P. Goldberg, S. L. J. Michel
    Chemoselective Proteomics, Zinc Fingers, and a Zinc(II) Model for H2S Mediated Persulfidation
    Angew. Chem. Int. Ed. (2024), 63, e202401003 - link
  • 348 | N. Ng, M. A. Siegler, S. Bernier, W. Bunstine, T. M. McQueen
    Disordered layers and dimerization in the crystal structure of TaOCl2
    J. Solid State Chem. (2024), 337, 124771 - link
  • 347 | S. Panda, H. Phan, E. M. Dunietz, M. T. Brueggemeyer, P. Kumar Hota, M. A. Siegler, A. Jose, M. Bhadra, E. I. Solomon, K. D. Karlin
    Intramolecular Phenolic H-Atom Abstraction by a N3ArOH Ligand-Supported (μ-η2:η2-Peroxo)dicopper(II) Species Relevant to the Active Site Function of oxy-Tyrosinase
    J. Am. Chem. Soc. (2024), 146, 14942–14947 - link
  • 346 | T. Wu, A. Puri, Y. Lin Qiu, D. Ye, R. Sarma, Y. Wang, T. Kowalewski, M. A. Siegler, M. Swart, I. Garcia-Bosch
    Tuning the Thermochemistry and Reactivity of a Series of Cu-Based 4H,+/4e- Electron-Coupled-Proton Buffers
    Inorg. Chem. (2024), 63, 9014-9025 - link
  • 345 | H. Wakefield IV, S. J. Melvin, J. Jiang, I. Kevlishvili, M. A. Siegler, S. L. Craig, H. J. Kulik, R. S. Klausen
    Angle-strained sila-cycloalkynes
    Chem. Commun. (2024), 60, 4842-4845 - link
  • 344 | S. Yadav, V. Yadav, M. A. Siegler, P. Moënne-Loccoz, G. N. L. Jameson, D P. Goldberg
    A Nonheme Iron(III) Superoxide Complex Leads to Sulfur Oxygenation
    J. Am. Chem. Soc. (2024), 146, 7915–7921 - link
  • 343 | X-Q. Zhou, S. Abyar, I. Carbo-Bague, L. Wang, S. Türck, M. A. Siegler, U. Basu, I. Ott, R. Liu, A. P. IJzerman, S. Bonnet
    Multitarget Thiol-Activated Tetrapyridyl Gold(III) Complexes for Hypoxic Cancer Therapy
    CCS Chem. (2024), 6, 783–797 - link
  • 342 | K. Sagar, M. Kim, T. Wu, S. Zhang, E. L. Bominaar, M. A. Siegler, M. Hendrich, I. Garcia-Bosch
    Mimicking the Reactivity of LPMOs with a Mononuclear Cu Complex
    Eur. J. Inorg. Chem. (2024), 27, e202300774 - link
  • 341 | R. F. J. Epping, F. J. de Zwart, N. P. van Leest, J. I. van der Vlugt, M. A. Siegler, S. Mathew, J. N. H. Reek, B. de Bruin
    PhenTAA: A Redox-Active N4-Macrocyclic Ligand Featuring Donor and Acceptor Moieties
    Inorg. Chem. (2024), 63, 1974–1987 - link
  • 340 | J. de Jong, M. A. Siegler, S. J. Wezenberg
    A Photoswitchable Macrocycle Controls Anion-Templated Pseudorotaxane Formation and Axle Relocalization
    Angew. Chem. Int. Ed. (2024), 63, e202316628 - link
  • 339 | A. Puri, A. McAninch, S. Shu, K. Rajabimoghadam, M. A. Siegler, M. Swart, I. Garcia-Bosch
    Geometric control of Cu, Ni and Pd complexes in the solid state via intramolecular H-bonding interactions
    Inorg. Chem. (2024), 561, 121844 - link
  • 338 | D. den Boer, H. Stegman, C. J. C. Peeters, M. A. Siegler, D. G. H. Hetterscheid
    Electronic Structure Variations of Cu-Based Water Oxidation Catalysts Bearing Redox-Active Ligands
    Eur. J. Inorg. Chem. (2024), 27, e202300475 - link


2023

  • 337 | M. Langerman, P. H. van Langevelde, J. J. van de Vijver, M. A. Siegler, D. G. H. Hetterscheid
    Scaling Relation between the Reduction Potential of Copper Catalysts and the Turnover Frequency for the Oxygen and Hydrogen Peroxide Reduction Reactions
    Inorg. Chem. (2023), 62, 19593–19602 - link
  • 336 | E. Yang, X. E. Shen, H. West-Foyle, T-H. Hahm, M. A. Siegler, D. R. Brown, Cole C. Johnson, J. H. Kim, L. A. Roker, C. M. Tressler, I. Barman, S. C. Kuo, K. Glunde
    FluoMALDI Microscopy: Matrix Co-Crystallization Simultaneously Enhances Fluorescence and MALDI Imaging
    Adv. Sci. (2023), 10, 2304343 - link
  • 335 | N. G. Garrison, S. A. Harry, M. A. Siegler, G. Cariello, R. A. Cormanich, T. Lectka
    The C-F⋅⋅⋅H-CF2 interaction: A combination of hydrogen bonding and n → σ* stabilization
    J. Fluor. Chem. (2023), 272, 110191 - link
  • 334 | V. Yadav, L. Wen, S. Yadav, M. A. Siegler, D. P. Goldberg
    Selective Radical Transfer in a Series of Nonheme Iron(III) Complexes
    Inorg. Chem. (2023), 62, 17830–17842 - link
  • 333 | L. A. Pressley, M. Sinha, M. A. Siegler, N. Edmiston, S. Bernier, A. M. Ferrenti, S. Das, R. Ramesh, S. Kushwaha, T. M. McQueen
    Tunable W5+ Absorbance in Laser Floating Zone Grown Bismuth Tungstate
    J. Phys. Chem. C (2023), 127, 19386–19395 - link
  • 332 | A. M. Ferrenti, M. A. Siegler, S. Ghosh, X. Zhang, N. Kintop, H. K. Vivanco, C. Lygouras, T. Halloran, S. Klemenz, C. Broholm, N. Drichko, T. M. McQueen
    Chemical tuning of a honeycomb magnet through a critical point
    Phys. Rev. B (2023), 108, 064433 - link
  • 331 | K. K. Singh, C. S. Gerke, S. S. Saund, A. M. Zito, M. A. Siegler, V. Sara Thoi
    CO2 Activation with Manganese Tricarbonyl Complexes by an H-Atom Responsive Benzimidazole Ligand
    Chem. Eur. J. (2023), 29, e202300796 - link
  • 330 | N. Duindam, M. van Dongen, M. A. Siegler, S. J. Wezenberg
    Monodirectional Photocycle Drives Proton Translocation
    J. Am. Chem. Soc. (2023), 145, 21020–21026 - link
  • 329 | M. Kazim, Z. Feng, S. Vemulapalli, M. A. Siegler, A. Chopra, P. M. Nguyen, M. G. Holl, L. Guan, T. Dudding, D. J. Tantillo, T. Lectka
    Through-Space, Lone-Pair Promoted Aromatic Substitution: A Relay Mechanism Can Beat Out Direct Activation
    Chem. Eur. J. (2023), 28, e202301550 - link
  • 328 | H. Man, A. Ghasemi, M. Adnani, M. A. Siegler, E. A. Anber, Y. Li, C-L. Chien, M. L. Taheri, C-W. Chu, C. L. Broholm, S. M. Koohpayeh
    Quantum paramagnetism in a non-Kramers rare-earth oxide: Monoclinic Pr2Ti2O7
    Phys. Rev. Mater. (2023), 7, 063401 - link
  • 327 | D. Villarón, G. E. A. Brugman, M. A. Siegler, S. J. Wezenberg
    Photoswitching of halide-binding affinity and selectivity in dithienylethene-strapped calix[4]pyrrole
    Chem. Commun. (2023), 56, 8688-8691 - link
  • 326 | M. L. A. Hakkennes, M. S. Meijer, J. P. Menzel, A-C. Goetz, R. Van Duijn, M. A. Siegler, F. Buda, S. Bonnet
    Ligand Rigidity Steers the Selectivity and Efficiency of the Photosubstitution Reaction of Strained Ruthenium Polypyridyl Complexes
    J. Am. Chem. Soc. (2023), 145, 13420–13434 - link
  • 325 | M. Kazim, M. Wang, S. Vemulapalli, P. Minh Nguyen, Y. Wang, M. A. Siegler, T. Dudding, T. Lectka
    How Do Face-to-Face Stacked Aromatic Rings Activate Each Other to Electrophilic Aromatic Substitution?
    Org. Lett. (2023), 25, 4318-4322 - link
  • 324 | L. A. Pressley, H. K. Vivanco, T. Berry, M. A. Siegler, T. M. McQueen
    Transition metal (dis)order in single crystal multicomponent rare earth perovskites
    J. Cryst. Growth (2023), 617, 127262 - link
  • 323 | B. Kim, M. T. Brueggemeyer, W. J. Transue, Y. Park, J. Cho, M. A. Siegler, E. I. Solomon, K. D. Karlin
    Fenton-like Chemistry by a Copper(I) Complex and H2O2 Relevant to Enzyme Peroxygenase C-H Hydroxylation
    J. Am. Chem. Soc. (2023), 145, 11735–11744 - link
  • 322 | X-Q. Zhou, P. Wang, V. Ramu, L. Zhang, S. Jiang, X. Li, S. Abyar, P. Papadopoulou, Y. Shao, L. Bretin, M. A. Siegler, F. Buda, A. Kros, J. Fan, X. Peng, W. Sun, S. Bonnet
    In vivo metallophilic self-assembly of a light-activated anticancer drug
    Nat. Chem. (2023), 15, 980-987 - link
  • 321 | H. Wakefield IV, I. Kevlishvili, K. E. Wentz, Y. Yao, T. B. Kouznetsova, S. J. Melvin, E. G. Ambrosius, A. Herzog-Arbeitman, M. A. Siegler, J. A. Johnson, S. L. Craig, H. J. Kulik, R. S. Klausen
    Synthesis and Ring-Opening Metathesis Polymerization of a Strained trans-Silacycloheptene and Single-Molecule Mechanics of Its Polymer
    J. Am. Chem. Soc. (2023), 145, 10187-10196 - link
  • 320 | K. K. Singh, A. Bhattacharyya, S. Havenridge, M. Ghabin, H. Ausmann, M. A. Siegler, C. M. Aikens, A. Das
    A first glance into mixed phosphine–stibine moieties as protecting ligands for gold clusters
    Nanoscale (2023), 15, 6934-6940 - link
  • 319 | D. den Boer, A. I. Konovalov, M. A. Siegler, D. G. H. Hetterscheid
    Unusual Water Oxidation Mechanism via a Redox-Active Copper Polypyridyl Complex
    Inorg. Chem. (2023), 62, 5303–5314 - link
  • 318 | M. Wang, R. K. Sachs, S. A. Harry, E. Holt, M. A. Siegler, T. Lectka
    Bifurcated hydrogen bonding to fluorine in an all cis-difluoro-hydroxy array
    J. Fluor. Chem. (2023), 267, 110104 - link
  • 317 | R-D. Gao, M. Taylor, T. McInnis, Z. Chen, S. S. Gori, H. M. LaPorte, M. A. Siegler, J. L. Neisewander, R. H. Mach, M. Singh, B. S. Slusher, R. Rais, R. R. Luedtke, T. Tsukamoto
    Synthesis and Pharmacological Characterization of a Difluorinated Analogue of Reduced Haloperidol as a Sigma-1 Receptor Ligand
    ACS Chem. Neurosci. (2023), 14, 947–957 - link
  • 316 | J. B. Gordon, T. Albert, S. Yadav, J. Thomas, M. A. Siegler, P. Moënne-Loccoz*, D. P. Goldberg
    Oxygen versus Sulfur Coordination in Cobalt Superoxo Complexes: Spectroscopic Properties, O2 Binding, and H-Atom Abstraction Reactivity
    Inorg. Chem. (2023), 62, 392-400 - link
  • 315 | E. P. van Geest, S. K. Götzfried, D. M. Klein, N. Salitra, S. Popal, Y. Husiev, C. J. Van der Griend, X. Zhou, M. A. Siegler, G. F. Schneider, S. Bonnet
    A Lock-and-Kill Anticancer Photoactivated Chemotherapy Agent
    Photochem. Photobiol. (2023), 99, 777-786 - link
  • 314 | A. E. Castillo, E. Pérez-Gutiérrez, P. Ceballos, P. Venkatesan, S. Thamotharan, M A. Siegler, M. J. Percino
    Non-covalent interactions towards 2-(4-(2,2-dicyanovinyl) benzylidene)malononitrile packing polymorphism due to solvent effect. Experimental and theoretical spectroscopy approach
    J. Mol. Struct. (2023), 1275, 134674 - link


2022

  • 313 | A. F. Gittens, Q. Jiang, M. A. Siegler, R. S. Klausen
    Conjugation in Isomeric Cyclosilane Thioethers
    Organometallics (2022), 41, 3762–3769 - link
  • 312 | S. Banerjee, X. Han, M. A. Siegler, E. M. Miller, N. M. Bedford, B. C. Bukowski, V. Sara Thoi
    Flexible 2D Boron Imidazolate Framework for Polysulfide Adsorption in Lithium–Sulfur Batteries
    Chem. Mater. (2022), 34, 10451–10458 - link
  • 311 | V. Yadav, L. Wen, R. J. Rodriguez, M. A. Siegler, D. P. Goldberg
    Nonheme Iron(III) Azide and Iron(III) Isothiocyanate Complexes: Radical Rebound Reactivity, Selectivity, and Catalysis
    J. Am. Chem. Soc. (2022), 144, 20641-20652 - link
  • 310 | M. T.Scerba, D. Tweedie, D. Lecca, M. A.Siegler, R. Rais, N. H.Greig
    Thionated aminofluorophthalimides reduce classical markers of cellular inflammation in LPS-challenged RAW 264.7 cells
    Bioorg. Med. Chem. Lett. (2022), 76, 128972 - link
  • 309 | C. van de Griend, J. J. van de Vijver, M. A. Siegler, R. T. Dame, S. Bonnet
    Ruthenium-Locked Helical Chirality: A Barrier of Inversion and Formation of an Asymmetric Macrocycle
    Inorg. Chem. (2022), 61, 16045–16054 - link
  • 308 | S. A. Harry, N. G. Garrison, A. Zhu, M. R. Xiang, M. A. Siegler, T. Lectka
    C–F Bonds as “Frozen” Nucleophiles: Unconsummated SN2 Reactions
    J. Org. Chem. (2022), 87, 13406–13410 - link
  • 307 | C. Marvelous, L. de Azevedo Santos, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
    Redox Conversion of Cobalt(II)-Diselenide to Cobalt(III)-Selenolate Compounds: Comparison with Their Sulfur Analogs
    Eur. J. Inorg. Chem. (2022), 2022, e202200445 - link
  • 306 | T. Wu, K. Rajabimoghadam, A. Puri, D. D. Hebert, Y. Lin Qiu, S. Eichelberger, M. A. Siegler, M. Swart, M. P. Hendrich, I. Garcia-Bosch
    A 4H+/4e– Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex
    J. Am. Chem. Soc. (2022), 144, 16905–16915 - link
  • 305 | C. Marvelous, M. A.Siegler, E. Bouwman
    Structural investigations and reactivity of cobalt(II)–disulfide compounds
    Inorg. Chim. Acta (2022), 543, 121193 - link
  • 304 | S. Banerjee, J. M. Gorham, P. Beccar-Varela, H. G. Hackbarth, M. A. Siegler, N. Drichko, J. T. Wright, N. M. Bedford, V. Sara Thoi
    Atomically Dispersed CuNx Sites from Thermal Activation of Boron Imidazolate Cages for Electrocatalytic Methane Generation
    ACS Appl. Energy Mater. (2022), , - link
  • 303 | S. A. Harry, M. Kazim, P. M. Nguyen, A. Zhu, M. R. Xiang, J. Catazaro, M. Siegler, T. Lectka
    The Close Interaction of a C−F Bond with an Amide Carbonyl: Crystallographic and Spectroscopic Characterization
    Angew. Chem. Int. Ed. (2022), 61, e202207966 - link
  • 302 | C. Marvelous, L. de Azevedo Santos, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
    Cleaner and stronger: how 8-quinolinolate facilitates formation of Co(III)–thiolate from Co(II)–disulfide complexes
    Dalton Trans. (2022), 51, 11675-11684 - link
  • 301 | Q. Jiang, A. F. Gittens, S. Wong, M. A. Siegler, R. S. Klausen
    Highly selective addition of cyclosilanes to alkynes enabling new conjugated materials
    Chem. Sci. (2022), 13, 7587-7593 - link
  • 300 | A. M. Ferrenti, M. A. Siegler, S. Gao, N. Ng, T. M. McQueen
    ScSI: A New Exfoliatable Semiconductor
    Chem. Mater. (2022),34, 5443-5451 - link
  • 299 | C. Marvelous, L. de Azevedo Santos, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
    Probing the redox-conversion of Co(II)-disulfide to Co(III)-thiolate complexes: the effect of ligand-field strength
    Dalton Trans. (2022), 51, 8046-8055 - link
  • 298 | D. den Boer, Q. Siberie, M. A. Siegler, T. H. Ferber, D. C. Moritz, J. P. Hofmann, D. G. H. Hetterscheid
    On the Homogeneity of a Cobalt-Based Water Oxidation Catalyst
    ACS Catal. (2022), 12, 4597–4607 - link
  • 297 | F. Jiang, C. Marvelous, A. C. Verschuur, M. A. Siegler, S J. Teat, E. Bouwman
    Cobalt(II)-disulfide compounds with the unusual PF2O2– anion. ligand-dependent redox conversion to a cobalt(III)-thiolate complex
    Inorg. Chim. Acta (2022), 535, 120880 - link
  • 296 | N. V. Machushynets, S. S. Elsayed, C. Du, M. A. Siegler, M. de la Cruz, O. Genilloud, T. Hankemeier, G. P. van Wezel
    Discovery of actinomycin L, a new member of the actinomycin family of antibiotics
    Sci. Rep. (2022), 12, 2813 - link
  • 295 | J. N. Capilato, S. A. Harry, M. A. Siegler, T. Lectka
    Spectroscopic and Crystallographic Characterization of the R3N+−C−H⋅⋅⋅X Interaction
    Chem. Eur. J. (2022), 28, e202103922 - link
  • 294 | J. J. D. Sacramento, T. Albert, M. Siegler, P. Moënne-Loccoz, D. P. Goldberg
    An Iron(III) Superoxide Corrole from Iron(II) and Dioxygen
    Angew. Chem. Int. Ed. (2022), 61, e202111492 - link
  • 293 | N. W. G. Smits, D. Rademaker, A. I. Konovalov, M. A. Siegler, D. G. H. Hetterscheid
    Influence of the spatial distribution of copper sites on the selectivity of the oxygen reduction reaction
    Dalton Trans. (2022), 51, 1206-1215 - link
  • 292 | J. B. Patty, S. Havenridge, D. Tietje-Mckinney, M. A. Siegler, K. K. Singh, R. Hajy Hosseini, M. Ghabin, C. M. Aikens, A. Das
    Crystal Structure and Optical Properties of a Chiral Mixed Thiolate/Stibine-Protected Au18 Cluster
    J. Am. Chem. Soc. (2022), 144, 478-484 - link
  • 291 | S. J. Wezenberg, L-J. Chen, J. E. Bos, B. L. Feringa, E. N. W. Howe, X. Wu, M. A. Siegler, P. A. Gale
    Photomodulation of Transmembrane Transport and Potential by Stiff-Stilbene Based Bis(thio)ureas
    J. Am. Chem. Soc. (2022), 144, 331-338 - link


2021

  • 290 | J. B. Gordon, T. Albert, A. Dey, S. Sabuncu, M. A. Siegler, E. Bill, P. Moënne-Loccoz, D. P. Goldberg
    A Reactive, Photogenerated High-Spin (S = 2) FeIV(O) Complex via O2 Activation
    J. Am. Chem. Soc. (2021), 143, 21637-21647 - link
  • 289 | D. M. Klein, S. Rodríguez-Jiménez, M. E. Hoefnagel, A. Pannwitz, A. Prabhakaran, M. A. Siegler, Tia E. Keyes, E. Reisner, A. M. Brouwer, S. Bonnet
    Shorter Alkyl Chains Enhance Molecular Diffusion and Electron Transfer Kinetics between Photosensitisers and Catalysts in CO2-Reducing Photocatalytic Liposomes
    Chem. Eur. J. (2021), 27, 17203-17212 - link
  • 288 | G. W. Farley, M. A. Siegler, D. P. Goldberg
    Halogen Transfer to Carbon Radicals by High-Valent Iron Chloride and Iron Fluoride Corroles
    Inorg. Chem. (2021), 60, 17288–17302 - link
  • 287 | J. G. Alvarado, D. C. Cummins, A. C. Diaconescu, M. A. Siegler, D. P. Goldberg
    The selective monobromination of a highly sterically encumbered corrole: Structural and spectroscopic properties of Fe(Cl)(2-bromo-5,10,15-tris(triphenyl)phenyl corrole)
    J. Porphyr. Phthalocyanines (2021), 25, 1176-1185 - link
  • 286 | E. Ballestero-Martínez, J. T. Ferguson, M. A. Siegler, R. S. Klausen
    Isolation of a Cyclopentasilane from Magnesium Reduction of a Linear Hexasilane
    Eur. J. Org. Chem. (2021), 33, 4641-4646 - link
  • 285 | R. Trammell, A. Cordova, S. Zhang, S. Goswami, R. Murata, M. A. Siegler, I. Garcia-Bosch
    Practical One-Pot Multistep Synthesis of 2H-1,3-Benzoxazines Using Copper, Hydrogen Peroxide, and Triethylamine
    Eur. J. Org. Chem. (2021), 32, 4536-4540 - link
  • 284 | A. Dey, J. B. Gordon, T. Albert, S. Sabuncu, M. A. Siegler, S. N. MacMillan, K. M. Lancaster, P. Moënne-Loccoz, D. P. Goldberg
    A Nonheme Mononuclear {FeNO}7 Complex that Produces N2O in the Absence of an Exogenous Reductant
    Angew. Chem. Int. Ed. (2021), 60, 21558-21564 - link
  • 283 | A. E.Castillo, P. Ceballos, M. Cerón, E. Pérez-Gutiérrez, Martha Sosa-Rivadeneyra, W. Bernal, S. Thamotharan, M. A.Siegler, M. J. Percino
    Spectroscopic characterization of 4,5-diphenyl-2-(2,4,5-trimethoxyphenyl)-1H-imidazole obtained from the condensation of benzyl. Experimental and DFT approach
    J. Mol. Struct. (2021), 1246, 131269 - link
  • 282 | X-Q. Zhou, M. Mytiliniou, J. Hilgendorf, Y. Zeng, P. Papadopoulou, Y. Shao, M. Paradiz Dominguez, L. Zhang, M. B. S. Hesselberth, E. Bos, M. A. Siegler, F. Buda, A. M. Brouwer, A. Kros, R. I. Koning, D. Heinrich, S. Bonnet
    Intracellular Dynamic Assembly of Deep-Red Emitting Supramolecular Nanostructures Based on the Pt…Pt Metallophilic Interaction
    Adv. Mater. (2021), 33, 2008613 - link
  • 281 | S. S. Saund, M. A. Siegler, V. S. Thoi
    Electrochemical Degradation of a Dicationic Rhenium Complex via Hoffman-Type Elimination
    Inorg. Chem. (2021), 60, 13011-13020 - link
  • 280 | A. Busemann, I. Flaspohler, X-Q. Zhou, C. Schmidt, S. K. Goetzfried, V. H. S. van Rixel, I. Ott, M. A. Siegler, S. Bonnet
    Ruthenium-based PACT agents based on bisquinoline chelates: synthesis, photochemistry, and cytotoxicity
    J. Biol. Inorg. Chem. (2021), 26, 667-674 - link
  • 279 | S. Zhang, R. Trammell, A. Cordova, M. A. Siegler, I. Garcia-Bosch
    Cu-promoted intramolecular hydroxylation of Csingle bondH bonds using directing groups with varying denticity
    J. Inorg. Biochem. (2021), 223, 111557 - link
  • 278 | M. Sinha, H. K. Vivanco, C. Wan, M. A. Siegler, V. J. Stewart, E. A. Pogue, L. A. Pressley, T. Berry, Z. Wang, I. Johnson, M. Chen, T. T. Tran, W. A. Phelan, T. M. McQueen
    Twisting of 2D Kagomé Sheets in Layered Intermetallics
    ACS Cent. Sci. (2021), 7, 1381-1390 - link
  • 277 | A. Shirvan, H. Golchoubian, M. A.Siegler, E. Bouwman
    Copper (II) halide complexes with NNO tridentate ligand as chromotropic probes; synthesis, structural characterization and spectroscopic properties
    J. Mol. Struct. (2021), 1243, 130930 - link
  • 276 | T. Wu, J. Musgrove, M. A. Siegler, I. Garcia-Bosch
    Mononuclear and Dinuclear Copper Complexes of Tridentate Redox-active Ligands with Tunable H-bonding Donors: Structure, Spectroscopy and H+/e− Reactivity
    Chem. Asian J. (2021), 16, 1608-1618 - link
  • 275 | M. T. Scerba, M. A. Siegler, N. H. Greig
    Thionation of Aminophthalimide Hindered Carbonyl Groups and Application to the Synthesis of 3,6′-Dithionated Pomalidomides
    Synlett (2021), 60, Ahead of Print - link
  • 274 | J. B. Gordon, J. P. McGale, M. A. Siegler, D. P. Goldberg
    Proton-Coupled Electron-Transfer Reactivity Controls Iron versus Sulfur Oxidation in Nonheme Iron–Thiolate Complexes
    Inorg. Chem. (2021), 60, 6255-6265 - link
  • 273 | A. Castillo, P. Ceballos, P. Santos, M. Cerón, P. Venkatesan, E. Pérez-Gutiérrez, M. Sosa-Rivadeneyra, S. Thamotharan, M. A. Siegler, M. J. Percino
    Solution and Solid-State Photophysical Properties of Positional Isomeric Acrylonitrile Derivatives with Core Pyridine and Phenyl Moieties: Experimental and DFT Studies
    Molecules (2021), 26, 1500 - link
  • 272 | X-Q. Zhou, I. Carbo-Bague, M. A. Siegler, J. Hilgendorf, U. Basu, I. Ott, R. Liu, L. Zhang, V. Ramu, A. P. IJzerman, S. Bonnet
    Rollover Cyclometalation vs Nitrogen Coordination in Tetrapyridyl Anticancer Gold(III) Complexes: Effect on Protein Interaction and Toxicity
    JACS Au (2021), 1, 380-395 - link
  • 271 | M. Bhadra, W. J. Transue, H. Lim, R. E. Cowley, J. Y. C. Lee, M. A. Siegler, P. Josephs, G. Henkel, M. Lerch, S. Schindler, A. Neuba, K. O. Hodgson, B. Hedman, E. I. Solomon, K. D. Karlin
    A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity
    J. Am. Chem. Soc. (2021), 143, 3707-3713 - link
  • 270 | D. Villarón, M. A. Siegler, S. J. Wezenberg
    A photoswitchable strapped calix[4]pyrrole receptor: highly effective chloride binding and release
    Chem. Sci. (2021), 12, 3188-3193 - link
  • 269 | A. Pannwitz, H. Saaring, N. Beztsinna, X. Li, M. A. Siegler, S. Bonnet
    Mimicking Photosystem I with a Transmembrane Light Harvester and Energy Transfer‐Induced Photoreduction in Phospholipid Bilayers
    Chem. Eur. J. (2021), 27, 3013–3018 - link
  • 268 | V. Yadav , M. A. Siegler, D. P. Goldberg
    Temperature-Dependent Reactivity of a Non-heme FeIII(OH)(SR) Complex: Relevance to Isopenicillin N Synthase
    J. Am. Chem. Soc. (2021), 143, 46–52 - link
  • 267 | J. N. Capilato, M. A. Siegler, R. Rowshanpour, T. Dudding, T. Lectka
    Cooperative Noncovalent Interactions Lead to a Highly Diastereoselective Sulfonyl-Directed Fluorination of Steroidal α,β-Unsaturated Hydrazones
    J. Org. Chem. (2021), 86, 1300–1307 - link
  • 266 | E. Pérez–Gutiérrez, M. J. Percino, W. Bernal, M. Cerón, P. Ceballos, M. S. Rivadeneyra, M. A.Siegler, S. Thamotharane
    Fluorescence tuning with a single dye embedded in a polymer matrix and its Application on multicolor OLEDs
    Dyes Pigm. (2021), 186, 108979 - link


2020

  • 265 | F. J. Claire, M. A. Solomos, J. Kim, G. Wang, M. A. Siegler, M. F. Crommie, Thomas J. Kempa
    Structural and electronic switching of a single crystal 2D metal-​organic framework prepared by chemical vapor deposition
    Nat. Commun (2020), 11, 5524 - link
  • 264 | H. Lim, M. L. Baker, R. E. Cowley, S. Kim, M. Bhadra, M. A. Siegler, T. Kroll, D. Sokaras, T-C. Weng, D. R. Biswas, D. M. Dooley, K. D. Karlin, B. Hedman, K. O. Hodgson, E. I. Solomon
    Kβ X-​ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase
    Inorg. Chem. (2020), 59, 16567–16581 - link
  • 263 | N. W. G. Smits, B. van Dijk, I. de Bruin, S. L. T. Groeneveld, M. A. Siegler, D. G. H. Hetterscheid
    Influence of Ligand Denticity and Flexibility on the Molecular Copper Mediated Oxygen Reduction Reaction
    Inorg. Chem. (2020), 59, 16398–16409 - link
  • 262 | Y. Hu, F. Florio, Z. Chen, W. Adam Phelan, M. A. Siegler, Z. Zhou1, Y. Guo, R. Hawks, J. Jiang, J. Feng, L. Zhang, B. Wang, Y. Wang, D. Gall, E. F. Palermo, Z. Lu, X. Sun, T-M. Lu, H. Zhou, Y. Ren, E. Wertz,R. Sundararaman, J. Shi
    A chiral switchable photovoltaic ferroelectric 1D perovskite
    Science Advances (2020), 6, eaay4213 - link
  • 261 | J. T. Ferguson, Q. Jiang, Eric A. Marro, Ma. A. Siegler, R. S. Klausen
    Long-range coupling in cyclic silanes
    Dalton Trans. (2020), 49, 14951-14961 - link
  • 260 | N. P. van Leest, W. Stroek, M. A. Siegler, J. I. van der Vlugt, B. de Bruin
    Ligand-Mediated Spin-State Changes in a Cobalt-Dipyrrin-Bisphenol Complex
    Inorg. Chem. (2020), 59, 12903–12912 - link
  • 259 | F. Ghorbani, S. Andrew Harry, J. N. Capilato, C. Ross Pitts, J. Joram, G. N. Peters, J. D. Tovar, I. Smajlagic, M. A. Siegler, T. Dudding, T. Lectka
    Carbonyl-Directed Aliphatic Fluorination: A Special Type of Hydrogen Atom Transfer Beats Out Norrish II
    J. Am. Chem. Soc. (2020), 142, 14710–14724 - link
  • 258 | S. S. Elsayed, G. Genta-Jouve, V. J. Carrión, P. H. Nibbering, M. A. Siegler, W. de Boer, T. Hankemeier, G. P. van Wezel
    Atypical Spirotetronate Polyketides Identified in the Underexplored Genus Streptacidiphilus
    J. Org. Chem. (2020), 85, 10648–10657 - link
  • 257 | M. Kazim, L. Guan, A. Chopra, R. Sun, M. A. Siegler, T. Lectka
    Switching a HO···π Interaction to a Nonconventional OH···π Hydrogen Bond: A Completed Crystallographic Puzzle
    J. Org. Chem. (2020), 85, 9801–9807 - link
  • 256 | C. A. Evans, A. Zuluaga, D. Vasquez Matute, S. Baradaran-Noviri, N. Perez-Cervantes, M. A.Siegler
    Synthesis and biological evaluation of thioadatanserin and its dialkylated products as partial 5-HTR1A agonists and 5-HTR2A antagonists for potential use in depression and anxiety disorders
    Bioorganic Med. Chem. Lett. (2020), 30, 127358 - link
  • 255 | T. Wu, S. N. MacMillan, K. Rajabimoghadam, M. A. Siegler, K. M. Lancaster, I. Garcia-Bosch
    Structure, Spectroscopy, and Reactivity of a Mononuclear Copper Hydroxide Complex in Three Molecular Oxidation States
    J. Am. Chem. Soc. (2020), 142, 12265–12276 - link
  • 254 | A. Busemann, C. Araman, I. Flaspohler, A. Pratesi, X-Q. Zhou, V. H. S. van Rixel, M. A. Siegler, L. Messori, S. I. van Kasteren, S. Bonnet
    Alkyne Functionalization of a Photoactivated Ruthenium Polypyridyl Complex for Click-Enabled Serum Albumin Interaction Studies
    Inorg. Chem. (2020), 59, 7710–7720 - link
  • 253 | X-Q. Zhou, M. Xiao, V. Ramu, J. Hilgendorf, X. Li, P. Papadopoulou, M. A. Siegler, A. Kros, W. Sun, S. Bonnet
    The Self-Assembly of a Cyclometalated Palladium Photosensitizer into Protein-Stabilized Nanorods Triggers Drug Uptake In Vitro and In Vivo
    J. Am. Chem. Soc. (2020), 142, 10383–10399 - link
  • 252 | V. Yadav, R. J. Rodriguez, M. A. Siegler, D. P. Goldberg
    Determining the Inherent Selectivity for Carbon Radical Hydroxylation versus Halogenation with FeIII(OH)(X) Complexes: Relevance to the Rebound Step in Non-heme Iron Halogenases
    J. Am. Chem. Soc. (2020), 142, 7259-7264 - link
  • 251 | M. Kazim, M. A. Siegler, T. Lectka
    Close Amide NH···F Hydrogen Bonding Interactions in 1,8-Disubstituted Naphthalenes
    J. Org. Chem. (2020), 85, 6195-6200 - link
  • 250 | W. D. Kerber, D. S. Hartnett, A. Wanga, C. Hawkins Mafrice, M. A.Siegler
    Enhanced relative stability of heterobimetallic Fe(II)​, Zn(II)​, and Mg(II) clusters supported by a μ-​phenoxo bridge
    Inorg. Chim. Acta (2020), 506, 119547 - link
  • 249 | K. K. Singh, M. A. Siegler, V. Sara Thoi
    Unusual Reactivity of a Thiazole-Based Mn Tricarbonyl Complex for CO2 Activation
    Organometallics (2020), 39, 988-994 - link
  • 248 | N. P. van Leest, M. A. Tepaske, J-P. H. Oudsen, B. Venderbosch, N. R. Rietdijk, M. A. Siegler. M. Tromp, J. I. van der Vlugt, B. de Bruin
    Ligand Redox Noninnocence in [CoIII(TAML)]0/–) Complexes Affects Nitrene Formation
    J. Am. Chem. Soc. (2020), 142, 552–563 - link
  • 247 | D. A. Burns, E. M. Press, M. A. Siegler, R. S. Klausen, V. Sara Thoi
    2D Oligosilyl Metal–Organic Frameworks as Multi‐state Switchable Materials
    Angew. Chem. Int. Ed. (2020), 59, 763–768 - link


2019

  • 246 | J. P. T. Zaragoza, D. C. Cummins, M. Q. E. Mubarak, M. A. Siegler, S. P. de Visser, D. P. Goldberg
    Hydrogen Atom Abstraction by High-Valent Fe(OH) versus Mn(OH) Porphyrinoid Complexes: Mechanistic Insights from Experimental and Computational Studies
    Inorg. Chem. (2019), 58, 16761-16770 - link
  • 245 | G. D. York, M. A. Siegler, D. D. Patel, T. Lectka
    Synthesis and X-Ray crystallography of a substituted trityl fluoride: Ordering power of a C-F bond
    J. Fluor. Chem. (2019), 228, 109377 - link
  • 244 | G. B. Wijeratne, M. Bhadra, M. A. Siegler, K. D. Karlin
    Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release
    J. Am. Chem. Soc. (2019), 141, 17962-17967 - link
  • 243 | E. A. Marro, C. P. Folster, E. M. Press, H. Im, J. T. Ferguson, M. A. Siegler, R. S. Klausen
    Stereocontrolled Syntheses of Functionalized cis- and trans-Siladecalins
    J. Am. Chem. Soc. (2019), 141, 17926-17936 - link
  • 242 | M. Kazim, H. Foy, M. A. Siegler, T. Dudding, T. Lectka
    Discovery and Mechanistic Study of a Totally Organic C(aryl)–C(alkyl)Oxygen Insertion Reaction
    J. Org. Chem. (2019), 84, 14349-14353 - link
  • 241 | R. Plessius, N. Orth, I. Ivanović-Burmazović, M. A. Siegler, J. N. H. Reek, J. I. van der Vlugt
    Reversible multi-electron storage in dual-site redox-active supramolecular cages
    Chem. Commun. (2019), 55, 12619-12622 - link
  • 240 | K. M. van Vliet, L. H. Polak, M. A. Siegler, J. I. van der Vlugt, C. Fonseca Guerra, B. de Bruin
    Efficient Copper-Catalyzed Multicomponent Synthesis of N-Acyl Amidines via Acyl Nitrenes
    J. Am. Chem. Soc. (2019), 141, 15240-15249 - link
  • 239 | C. Rebreyend, V. Mouarrawis, M. A. Siegler, J. I. van der Vlugt, B. de Bruin
    Steric Protection of Rhodium‐Nitridyl Radical Species
    Eur. J. Inorg. Chem. (2019), 2019, 4249-4255 - link
  • 238 | M. Lankelma, V. Vreeken, M. A. Siegler, J. I. van der Vlugt
    Dinuclear Gold Complexes Supported by Wide Bite Angle Diphosphines for Preorganization-Induced Selective Dual-Gold Catalysis
    Inorganics (2019), 7, 28 - link
  • 237 | C. P. Folster, P. N. Nguyen, M. A. Siegler, R. S. Klausen
    Tunable SiN Hybrid Conjugated Materials
    Organometallics (2019), 38, 2902-2909 - link
  • 236 | A. M. Confer, S. Sabuncu, M. A. Siegler, P. Moënne-Loccoz, D. P. Goldberg
    Mononuclear, Nonheme, High-Spin {FeNO}7/8 Complexes Supported by a Sterically Encumbered N4S-Thioether Ligand
    Inorg. Chem. (2019), 58, 9576-9580 - link
  • 235 | J. J. Liu, M. A. Siegler, K. D. Karlin, P. Moënne‐Loccoz
    Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O2 and NO and Mechanistic Insights into Metal‐Mediated Peroxynitrite Decomposition
    Angew. Chem. Int. Ed. (2019), 58, 10936-10940 - link
  • 234 | V. Yadav, J. B. Gordon, M. A. Siegler, D. P. Goldberg
    Dioxygen-Derived Nonheme Mononuclear FeIII(OH) Complex and Its Reactivity with Carbon Radicals
    J. Am. Chem. Soc. (2019), 141, 10148-10153 - link
  • 233 | K. Rajabimoghadam, Y. Darwish, U. Bashir, D. Pitman,S. Eichelberger, M. A. Siegler, I. Garcia-Bosch
    Tunable intramolecular multicenter H-bonding interactions in first-row metal complexes bearing bidentate redox-active ligands
    J. Coord. Chem. (2019), 72, 1346-1357 - link
  • 232 | V. H. S. van Rixel, A. Busemann, M. F. Wissingh, S. L. Hopkins, B. Siewert, C. van de Griend, Ma. A. Siegler, T. Marzo, F. Papi, M. Ferraroni, P. Gratteri, C. Bazzicalupi, L. Messori, S. Bonnet
    Induction of a Four‐Way Junction Structure in the DNA Palindromic Hexanucleotide 5′‐d(CGTACG)‐3′ by a Mononuclear Platinum Complex
    Angew. Chem. Int. Ed. (2019), 58, 9378-9382 - link
  • 231 | M. M. Li, F. J. Claire, M. A. Solomos, S. M. Tenney, S. A. Ivanov, M. A. Siegler, T. J. Kempa
    Molecular chains of coordinated dimolybdenum isonicotinate paddlewheel clusters
    RSC Adv. (2019), 9, 16492-16495 - link
  • 230 | M. Kazim, M. A. Siegler, T. Lectka
    A Protonated Quinone Methide Stabilized by a Combination of Partial Aromatization and π-Interaction: Spectroscopic and Crystallographic Analysis
    J. Org. Chem. (2019), 84, 8284-8288 - link
  • 229 | R. Trammell, L. D’Amore, A. Cordova, P. Polunin, N. Xie, M. A. Siegler, P. Belanzoni, M. Swart, I. Garcia-Bosch
    Directed Hydroxylation of sp2 and sp3 C–H Bonds Using Stoichiometric Amounts of Cu and H2O2
    Inorg. Chem. (2019), 58, 7584-7592 - link
  • 228 | M. J. Percino, M. Cerón, E. Pérez‐Gutiérrez, V. Perumal, M. A. Siegler, T. Subbiah, P. Ceballos, P. Gordillo‐Guerra, J. Bonilla‐Cruz, F. E. Longoria, T. Lara
    Preferential Orientation of Crystals and its Influence on the Emission Wavelength of Acrylonitrile Derivatives Treated with Polar Solvents
    Cryst. Res. Technol. (2019), 54, - link
  • 227 | P. Venkatesan, M. Cerón, E. Pérez‐Gutiérrez, A. E. Castillo, S. Thamotharan, F. Robles, M. A. Siegler, J. Percino
    Experimental and Theoretical Insights into the Optical Properties and Intermolecular Interactions in Push‐Pull Bromide Salts
    ChemistryOpen (2019), 8, 483-496 - link
  • 226 | X-Q. Zhou, A. Busemann, M. S. Meijer, M. A. Siegler, S. Bonnet
    The two isomers of a cyclometallated palladium sensitizer show different photodynamic properties in cancer cells
    Chem. Commun. (2019), 55, 4695-4698 - link
  • 225 | M. Kazim, M. A. Siegler, T. Lectka
    A Case of Serendipity: Synthesis, Characterization, and Unique Chemistry of a Stable, Ring-Unsubstituted Aliphatic p-Quinone Methide
    Org. Lett. (2019), 21, 2326-2329 - link
  • 224 | J. B. Gordon, A. C. Vilbert, M. A. Siegler, K. M. Lancaster, P. Moënne-Loccoz, David P. Goldberg
    A Nonheme Thiolate-​Ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity
    J. Am. Chem. Soc. (2019), 141, 3641-3653 link
  • 223 | M. Devillard, A. Ehlers, M. A. Siegler, J. I. van der Vlugt
    Selective Carbanion–Pyridine Coordination of a Reactive P,N Ligand to RhI
    Chem. Eur. J. (2019), 25, 3875-3883 - link
  • 222 | S. Luo, M. A. Siegler, E. Bouwman
    Transition Metal Compounds of Pyridine‐Amide‐Functionalized Carbene Ligands: Synthesis, Structure, and Electrocatalytic Properties in Proton Reduction
    Eur. J. Inorg. Chem. (2019), 2019, 617-627 - link
  • 221 | S. S. Saund, S. L. Goldschmid, K. Ng, V. J. Stewart, M. A Siegler, V. S. Thoi
    Exploring Ligand Non-Innocence of Coordinatively-Versatile Diamidodipyrrinato Cobalt Complexes
    Chem. Commun. (2019), 55, 1825-1828 - link
  • 220 | T. K. Purkait, E. M. Press, E. A. Marro, M. A. Siegler, R. S. Klausen
    Low-Energy Electronic Transition in SiB Rings
    Organometallics (2019), 38, 1688-1698 - link
  • 219 | J‐A. Cuello‐Garibo, C. C. James, M. A. Siegler, S. L. Hopkins, S. Bonnet
    Selective Preparation of a Heteroleptic Cyclometallated Ruthenium Complex Capable of Undergoing Photosubstitution of a Bidentate Ligand
    Chem. Eur. J. (2019), 25, 1260-1268 - link
  • 218 | L. N. Lameijer, C. van de Griend, S L. Hopkins, A-G. Volbeda, S. H. C. Askes, M. A. Siegler, S Bonnet
    Photochemical Resolution of a Thermally Inert Cyclometalated Ru(phbpy)(N–N)(Sulfoxide)+ Complex
    J. Am. Chem. Soc. (2019), 141, 352-362 - link
  • 217 | F. Jiang, M. A. Siegler, E. Bouwman
    Synthesis and characterization of a series of transition metal compounds of thioether and disulfide ligands
    Inorg. Chim. Acta (2019), 486, 135–140 - link


2018

  • 216 | F. Jiang, M. A. Siegler, E. Bouwman
    The Reactivity of FeII and CoII Disulfide Compounds with Dihydrogen Peroxide
    Eur. J. Inorg. Chem. (2018), 2018, 4696-4701 - link
  • 215 | K. Rajabimoghadam, Y. Darwish, U. Bashir, D. Pitman, S. Eichelberger, M. A. Siegler, M. Swart, I. Garcia-Bosch
    Catalytic Aerobic Oxidation of Alcohols by Copper Complexes Bearing Redox-Active Ligands with Tunable H-Bonding Groups
    J. Am. Chem. Soc. (2018), 140, 16625-16634 - link
  • 214 | J. B. Gordon, J. P. McGale, J. R. Prendergast, Z. Shirani-Sarmazeh, M. A. Siegler, G. N. L. Jameson, D. P. Goldberg
    Structures, Spectroscopic Properties, and Dioxygen Reactivity of 5- and 6-Coordinate Nonheme Iron(II) Complexes: A Combined Enzyme/Model Study of Thiol Dioxygenases
    J. Am. Chem. Soc. (2018), 140, 14807–14822 - link
  • 213 | F. J. Claire, S. M. Tenney, M. M. Li, M. A. Siegler, J. S. Wagner, A. S. Hall, T. J. Kempa
    Hierarchically Ordered Two-Dimensional Coordination Polymers Assembled from Redox-Active Dimolybdenum Clusters
    J. Am. Chem. Soc. (2018), 140, 10673-10676 - link
  • 212 | F. Jiang, M. A. Siegler, X. Sun, L. Jiang, C. Fonseca Guerra, E. Bouwman
    Redox Interconversion between Cobalt(III) Thiolate and Cobalt(II) Disulfide Compounds
    Inorg. Chem. (2018), 57, 8796-8805 - link
  • 211 | M. Bhadra, J. Y. C. Lee, R. E. Cowley, S. Kim, M. A. Siegler, E. I. Solomon, K. D. Karlin
    Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes
    J. Am. Chem. Soc. (2018), 140, 9042-9045 - link
  • 210 | F. Jiang, M. A.Siegler, E. Bouwman
    A tetranuclear fluorido-bridged iron compound: Fluoride abstraction from the tetrafluoridoborate anion
    Inorg. Chem. Commun. (2018), 94, 53-56 - link
  • 209 | R. E. Messersmith, M. A. Siegler, J. D. Tovar
    A Heptacyclic Heptacycle: A Doubly Naphtho[b]thiophene Fused Borepin
    Synlett (2018), , Ahead of Print - link
  • 208 | E. A. Marro, E. M. Press, M. A. Siegler, R. S. Klausen
    Directional Building Blocks Determine Linear and Cyclic Silicon Architectures
    J. Am. Chem. Soc. (2018), 140, 5976-5986 - link
  • 207 | E. P. Hoffman, V. Riddle, M. A. Siegler, D. Dickerson, M. Backonja, W. G. Kramer, K. Nagaraju, H. Gordish-Dressman, J. M. Damsker, J. M. McCall
    Phase 1 trial of vamorolone, a first-in-class steroid, shows improvements in side effects via biomarkers bridged to clinical outcomes
    Steroids (2018), 134, 43-52 - link
  • 206 | J. P. T. Zaragoza, M. A. Siegler, D. P. Goldberg
    A Reactive Manganese(IV)–Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds
    J. Am. Chem. Soc. (2018), 140, 4380-4390 - link
  • 205 | T. M. Pangia, C. G. Davies, J. R. Prendergast, J. B. Gordon, M. A. Siegler, G. N. L. Jameson, D. P. Goldberg
    Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex
    J. Am. Chem. Soc. (2018), 140, 4191-4194 - link
  • 204 | S. Luo, D. F. Bruggeman, M. A. Siegler, E. Bouwman
    Can pendant pyridyl arm assist the proton delivery in electrocatalysis?
    Chem. Eur. J. (2018), 477, 24-30 - link
  • 203 | L. N. Lameijer, T. G. Brevé, V. H. S. van Rixel, Sven H. C. Askes, M. A. Siegler, S. Bonnet
    Effects of the Bidentate Ligand on the Photophysical Properties, Cellular Uptake, and (Photo)cytotoxicity of Glycoconjugates Based on the [Ru(tpy)(NN)(L)]2+ Scaffold
    Chem. Eur. J. (2018), , Ahead of Print - link
  • 202 | K. G. Kottrup, S. D’Agostini, P. H. van Langevelde, M. A. Siegler, D. G. H. Hetterscheid
    Catalytic Activity of an Iron-Based Water Oxidation Catalyst: Substrate Effects of Graphitic Electrodes
    ACS Catal. (2018), 8, 1052-1061 - link
  • 201 | V. H. S. van Rixel, G. F. Moolenaar, M. A Siegler, L. Messori, S. Bonnet
    Controlling with light the interaction between trans tetrapyridyl ruthenium complexes and an oligonucleotide
    Dalton Trans. (2018), 47, 507-516 - link
  • 200 | S. Luo, M. A. Siegler, E. Bouwman
    Dinuclear Nickel Complexes of Thiolate-Functionalized Carbene Ligands and Their Electrochemical Properties
    Organometallics (2018), 37, 740-747 - link


2017

  • 199 | G. Gezer, D. D. Jiménez, M. A. Siegler, E. Bouwman
    Synthesis and Characterization of Trinuclear [Ni2Ru] Complexes with Bridging Thiolate or Selenolate Donors for Electrocatalytic Proton Reduction
    Eur. J. Inorg. Chem. (2017), 2017, 5027-5032 - link
  • 198 | R. E. Messersmith, S. Yadav, M. A. Siegler, H. Ottosson, J. D. Tovar
    Benzo[b]thiophene Fusion Enhances Local Borepin Aromaticity in Polycyclic Heteroaromatic Compounds
    J. Org. Chem (2017), 82, 13440-13448 - link
  • 197 | E. A. Marro, E. M. Press, T. K. Purkait, D. Jimenez, M. A. Siegler, R. S. Klausen
    Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides
    Chem. Eur. J. (2017), 23, 15633-15637 - link
  • 196 | L. Guan, M. G. Holl, C. R. Pitts, M. D Struble, M. A. Siegler, T. Lectka
    Through-space Activation can Override Substituent Effects in Electrophilic Aromatic Substitution
    J. Am. Chem. Soc. (2017), 139, 14913-14916 - link
  • 195 | G. Gezer, S. Verbeek, M. A Siegler, E. Bouwman
    Nickel-Ruthenium-Based Complexes as Biomimetic Models of [NiFe] and [NiFeSe] Hydrogenases for Dihydrogen Evolution
    Dalton Trans. (2017), 46, 13590-13596 - link
  • 194 | J. P. T. Zaragoza, T. H. Yosca, M. A. Siegler, P. Moënne-Loccoz, M. T. Green, D. P. Goldberg
    Direct Observation of Oxygen Rebound with an Iron-Hydroxide Complex
    J. Am. Chem. Soc. (2017), 139, 13640-13643 - link
  • 193 | M. Devillard, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
    Transition-Metal-Free Cleavage of CO
    Chem. Eur. J. (2017), 23, 13628-13632 - link
  • 192 | D. D. Bume, C. R. Pitts, F. Ghorbani, S. A. Harry, J. N. Capilato, M. A. Siegler, T. Lectka
    Ketones as directing groups in photocatalytic sp3 C–H fluorination Disproportionation
    Chem. Sci. (2017), 8, 6918-6923 link
  • 191 | G. B. Wijeratne, S. Hematian, M. A. Siegler, K. D. Karlin
    Copper(I) / NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex – Redox Reversal Giving Copper(I) / NO(g) Disproportionation
    J. Am. Chem. Soc. (2017), 139, 13276-13279 link
  • 190 | H. J. Jang, S. L. Hopkins, M. A. Siegler, Sylvestre Bonnet
    Frontier orbitals of photosubstitutionally active ruthenium complexes: an experimental study of the spectator ligands’ electronic properties influence on photoreactivity
    Dalton Trans. (2017), 46, 9969-9980 - link
  • 189 | B. Siewert, M. Langerman, Y. Hontani, J. T. M. Kennis, V. H. S. van Rixel, B. Limburg, M. A. Siegler, V. Talens Saez, R. E. Kieltyka, S. Bonnet
    Turning on the red phosphorescence of a [Ru(tpy)(bpy)(Cl)]Cl complex by amide substitution: self-aggregation, toxicity, and cellular localization of an emissive ruthenium-based amphiphile
    Chem. Commun. (2017), 53, 11126-11129 - link
  • 188 | R. Trammell, Y. Y. See, A. T. Herrmann, N. Xie, D. E. Díaz, M A. Siegler, P S. Baran, I. Garcia-Bosch
    Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp3 C–H Bonds
    J. Org. Chem. (2017), 82, 7887-7904 - link
  • 187 | G. Gezer, D. Durán Jiménez, M. A. Siegler, Elisabeth Bouwman
    Electrocatalytic proton reduction by a model for [NiFeSe] hydrogenases
    Dalton Trans. (2017), 46, 7506-7514 - link
  • 186 | V. Vreeken, L. Baij, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
    N-Atom transfer via thermal or photolytic activation of a Co-azido complex with a PNP pincer ligand
    Dalton Trans. (2017), 46, 7145-7149 - link
  • 185 | T. F. van Dijkman, H. M. de Bruijn, T. G. Brevé, B. van Meijeren, M. A. Siegler, E. Bouwman
    Extremely bulky copper(I) complexes of [HB(3,5-{1-naphthyl}2pz)3]– and [HB(3,5-{2-naphthyl}2pz)3]– and their self-assembly on graphene
    Dalton Trans. (2017), 46, 6433-4446 - link
  • 184 | J.A. Cuello-Garibo, E. Pérez-Gallent, L. van der Boon, M. A. Siegler, and Sylvestre Bonnet
    Influence of the Steric Bulk and Solvent on the Photoreactivity of Ruthenium Polypyridyl Complexes Coordinated to L-​Proline
    Inorg. Chem (2017), 56, 4818-4828 - link
  • 183 | V. Vreeken, M. A. Siegler, J. I. van der Vlugt
    Controlled Interconversion of a Dinuclear Au Species Supported by a Redox-Active Bridging PNP Ligand Facilitates Ligand-to-Gold Electron Transfer
    Chem. Eur. J. (2017), 23, 5585-5594 - link
  • 182 | B. Bagh, D. L. J. Broere, V. Sinha, P. F. Kuijpers, N. van Leest, B. de Bruin, S. Demeshko, M. A. Siegler, J. I. van der Vlugt
    Catalytic Synthesis of N-Heterocycles via Direct C(sp3)−H Amination using an Air-stable Iron(III) Species with a Redox-Active Ligand
    J. Am. Chem. Soc. (2017), 139, 5117-5124 - link
  • 181 | C. R. Pitts, M. A. Siegler, T. Lectka
    Intermolecular Aliphatic C–F···H–C Interaction in the Presence of “Stronger” Hydrogen Bond Acceptors: Crystallographic, Computational, and IR Studies
    J. Org. Chem. (2017), 82, 3996-4000 - link
  • 180 | J. Percino, M. Cerón, P. Venkatesan, P. Ceballos, A. Bañuelos, O. Rodríguez, M. A. Siegler, F. Robles, V. M. Chapela, G. Soriano-Moro, E. Pérez-Gutiérrez, J. Bonilla-Cruz, S. Thamotharan
    Two Different Emissions of (2Z)-2-(4-Bromophenyl)-3-[4-(dimethylamino)phenyl]prop-2-enenitrile Due to Crystal Habit and Size: Synthesis, Optical, and Supramolecular Characterization
    Cryst. Growth Des. (2017), 17, 1679-1694 - link
  • 179 | D. R. Levine, R. E. Messersmith, M. A. Siegler, J. D. Tovar
    Ring fusion isomers of dithienoborepins: perturbations of electronic structure, aromaticity, and reactivity in boron-containing polycyclic heteroaromatics
    Can. J. Chem. (2017), 95, 381-389 - link
  • 178 | C. R. Pitts, D. D. Bume, S. A. Harry, M. A. Siegler, T. Lectka
    Multiple Enone-Directed Reactivity Modes Lead to the Selective Photochemical Fluorination of Polycyclic Terpenoid Derivatives
    J. Am. Chem. Soc. (2017), 139, 2208-2211 - link
  • 177 | E. E. Joslin, J. P. T. Zaragoza , M. A. Siegler, D. P. Goldberg
    meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine
    Chem. Commun. (2017), 53, 1961-1964 - link
  • 176 | S. M. Adam, I. Garcia-Bosch, A. W. Schaefer, S. K. Sharma, M. A. Siegler, E. I. Solomon, K. D. Karlin
    Critical Aspects of Heme-​Peroxo-​Cu Complex Structure and Nature of Proton Source Dictate Metal-​Operoxo Breakage versus Reductive O-​O Cleavage Chemistry
    J. Am. Chem. Soc. (2017), 139, 472-481 - link
  • 175 | E. M. Press, E. A. Marro, S. K. Surampudi, M. A. Siegler, J. A. Tang, R. S. Klausen
    Synthesis of a Fragment of Crystalline Silicon: Poly(Cyclosilane)
    Angew. Chem. Int. Ed. (2017), 56, 568-572 - link

2016

  • 174 | X. Liu, M. A. Siegler, M. Hilbers, E. Bouwman
    Synthesis, structure and photoluminescence properties of lanthanoid coordination polymers based on tetra(3,5-dicarboxyphenoxymethyl)methane
    Polyhedron (2016), 123, 1-8 - link
  • 173 | S. Sahu, B. Zhang, C. J. Pollock, M. Dürr, C. G. Davies, A. M. Confer, I. Ivanović-Burmazović, M. A. Siegler, G. N. L. Jameson, C. Krebs, D. P. Goldberg
    Aromatic C–F Hydroxylation by Nonheme Iron(IV)–Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations
    J. Am. Chem. Soc. (2016), 138, 12791-12802 - link
  • 172 | M. J. Percino, M. Cerón, O. Rodríguez, G Soriano-Moro, M. E. Castro, V. M. Chapela, M. A. Siegler, E. Pérez-Gutiérrez
    Conformational and molecular structures of α,​β-​unsaturated acrylonitrile derivatives: photophysical properties and their frontier orbitals
    Molecules (2016), 21, 389/1-389/19 - link
  • 171 | I. Garcia-Bosch, M. A. Siegler
    Copper-​Catalyzed Oxidation of Alkanes with H2O2 under a Fenton-​like Regime
    Angew. Chem. Int. Ed. (2016), 55, 12873-12876 - link
  • 170 | S. Luo, M. A. Siegler, E. Bouwman
    Nickel Complexes of Pyridine-​Functionalized N-​Heterocyclic Carbenes: Syntheses, Structures, and Activity in Electrocatalytic Hydrogen Production
    Eur. J. Inorg. Chem. (2016), 2016, 4693-4700 - link
  • 169 | J. Percino, M. Cerón, P. Ceballos, G. Soriano-Moro, O. Rodríguez, V. M. Chapela, M. E. Castro, J. Bonilla-Cruz, Maxime A. Siegler
    Changes in the luminescence emission of α,β-unsaturated acrylonitrile derivatives: morphology, polymorphism and solvent effect
    CrystEngComm (2016), 18, 7554-7572 - link
  • 168 | D. L. J. Broere, R. Plessius, J. Tory, S. Demeshko, B. de Bruin, M. A. Siegler, F. Hartl, J. I. van der Vlugt
    Localized Mixed-Valence and Redox Activity within a Triazole-Bridged Dinucleating Ligand upon Coordination to Palladium
    Chem. Eur. J. (2016), 22, 13965-13975 - link
  • 167 | D. L. J. Broere, N. P. van Leest, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
    Reversible Redox Chemistry and Catalytic C(sp3)–H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand
    Inorg. Chem. (2016), 55, 8603-8611 - link
  • 166 | E. E. Joslin, J. P. T. Zaragoza, R. A. Baglia, M. A. Siegler, D. P. Goldberg
    The Influence of Peripheral Substituent Modification on PV, MnIII, and MnV(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities
    Inorg. Chem. (2016), 55, 8646-8660 - link
  • 165 | M. D. Struble, L. Guan, M. A. Siegler, T. Lectka
    A C–F Bond Directed Diels–Alder Reaction
    J. Org. Chem. (2016), 81, 8087-8090 - link
  • 164 | L. S. Jongbloed, D. García-López, R. van Heck, M. A. Siegler, J. J. Carbó, J. I. van der Vlugt
    Arene C(sp2)-H Metalation at NiII Modeled with a Reactive PONCPh Ligand
    Inorg. Chem. Int. Ed. (2016), 55, 8041-8047 - link
  • 163 | V. Vreeken,D. L. J. Broere, A. C. H. Jans, M. Lankelma, J. N. H. Reek, M. A. Siegler, J. I. van der Vlugt
    Well-Defined Dinuclear Gold Complexes for Preorganization-Induced Selective Dual Gold Catalysis
    Angew. Chem. Int. Ed. (2016), 55, 10042-10046 - link
  • 162 | S. K. Sharma, H. Kim, P. J. Rogler, M. A. Siegler, K. D. Karlin
    Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization
    J. Biol. Inorg. Chem. (2016), 21, 729-743 - link
  • 161 | M. G. Holl, M. D. Struble, M. A. Siegler, T. Lectka
    The close interaction of a C-F bond with a carbonyl π–system: Attractive, repulsive, or both?
    J. Fluorine Chem. (2016), 188, 126-130 - link
  • 160 | B. Siewert, V. H. S. van Rixel, E. J. van Rooden, S. L. Hopkins, M. J. B. Moester, F. Ariese, M. A. Siegler, S. Bonnet
    Chemical Swarming: Depending on Concentration, an Amphiphilic Ruthenium Polypyridyl Complex Induces Cell Death via Two Different Mechanisms
    Chem. Eur. J. (2016), 22, 10960-10968 - link
  • 159 | R. C. Conyers, J. R. Mazzone, M. A. Siegler, G. H. Posner
    Highly regiocontrolled and stereocontrolled syntheses of polysubstituted aminocyclohexanes: mild inverse-electron-demand Diels–Alder cycloadditions of electrophilic 2-pyridones
    Tetrahedron Lett. (2016), 57, 3344-3348 - link
  • 158 | B. Bagh, D. L. J. Broere, M. A. Siegler, J. I. van der Vlugt
    Redox-Active-Ligand-Mediated Formation of an Acyclic Trinuclear Ruthenium Complex with Bridging Nitrido Ligands
    Angew. Chem. Int. Ed. (2016), 55, 8381-8385 - link
  • 157 | B. N. DiMarco, T. C. Motley, R. S. Balok, G. Li, M. A. Siegler, R. M O'Donnell, K. Hu, G. J. Meyer
    A Distance Dependence to Lateral Self-Exchange Across Nanocrystalline TiO2. A Comparative Study of Three Homologous RuIII/II Polypyridyl Compounds
    J. Phys. Chem. C,. (2016), 120, 14226-14235 - link
  • 156 | R. E. Messersmith, M. A. Siegler, J. D. Tovar
    Aromaticity Competition in Differentially Fused Borepin-Containing Polycyclic Aromatics
    J. Org. Chem. (2016), 81, 5595-5605 - link
  • 155 | R. Cao, C. Saracini, J. W. Ginsbach, M. T. Kieber-Emmons, M. A. Siegler, E. I. Solomon, S. Fukuzumi, K. D. Karlin
    RPeroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy
    J. Am. Chem. Soc. (2016), 138, 7055-7066 - link
  • 154 | X. Liu, M. A. Siegler, E. Bouwman
    Ratiometric Thermometer Based on a Lanthanoid Coordination Polymer
    Eur. J. Inorg. Chem. (2016), 2016, 2984-2988 - link
  • 153 | M. G. Holl, M. D. Struble, P. Singal, M. A. Siegler, T. Lectka
    Positioning a Carbon–Fluorine Bond over the π Cloud of an Aromatic Ring: A Different Type of Arene Activation
    Angew. Chem. Int. Ed. (2016), 55, 8266-8269 - link
  • 152 | V. H. S. van Rixel, B. Siewert, S. L. H. Hopkins, S. H.C. Askes, A. Busemann, M. A. Siegler, S. Bonnet
    Green light-induced apoptosis in cancer cells by a tetrapyridyl ruthenium prodrug offering two trans coordination sites
    Chem. Sci. (2016), 7, 4922-4929 - link
  • 151 | J. Jung, H. M. Neu, P. Leeladee, M. A. Siegler, K. Ohkubo, D. P. Goldberg, S. Fukuzumi
    Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine
    Inorg. Chem. (2016), 55, 3218-3228 - link
  • 150 | T. F. van Dijkman, M. A. Siegler, E. Bouwman
    Copper(I) Complexes of Naphthyl-Substituted Fluorinated Trispyr­azolylborate Ligands with Ethene and Carbon Monoxide
    Eur. J. Inorg. Chem. (2016), 2016, 2586-2594 - link
  • 149 | I. Garcia-Bosch, R. E. Cowley, D. E. Díaz, M A. Siegler, W. Nam, E. I. Solomon, K. D. Karlin
    Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity
    Chem. Eur. J. (2016), 22, 5133-5137 - link
  • 148 | A. C. McQuilken, H. Matsumura, M. Dürr, A. M. Confer, J/ P. Sheckelton, M. A. Siegler, T. M. McQueen, I. Ivanović-Burmazović, P. Moënne-Loccoz, D. P. Goldberg
    Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}7 Complex with Dioxygen
    J. Am. Chem. Soc. (2016), 138, 3107–3117 - link
  • 147 | H. L. van de Wouw, J. Y. Lee, M. A. Siegler, R. S. Klausen
    Innocent BN bond substitution in anthracene derivatives
    Org. Biomol. Chem. (2016), 14, 3256-3263 - link
  • 146 | W. A. Phelan, S. M. Koohpayeh, P. Cottingham, J. A. Tutmaher, J. C. Leiner, M. D. Lumsden, C. M. Lavelle, X. P. Wang, C. Hoffmann, M. A. Siegler, N. Haldolaarachchige, D. P. Young, T. M. McQueen
    On the Chemistry and Physical Properties of Flux and Floating Zone Grown SmB6 Single Crystals
    Sci. Rep. (2016), 6, 20860 - link
  • 145 | D. L. J. Broere, D. K. Modde, E. Blokker, M. A. Siegler, J. I. van der Vlugt
    Metal–Metal Interactions in Heterobimetallic Complexes with Dinucleating Redox-Active Ligands
    Angew. Chem. Int. Ed. (2016), 55, 2406-2410 link
  • 144 | W.D. Kerber, J. T. Goheen, K. A. Perez, M. A. Siegler
    Enhanced Stability of the FeII/MnII State in a Synthetic Model of Heterobimetallic Cofactor Assembly
    Inorg. Chem. (2016), 55, 848–857 - link
  • 143 | S. Zheng, N. R. M. Reintjens, M. A. Siegler, O. Roubeau, E. Bouwman, A. Rudavskyi, R. W. A. Havenith, S Bonnet
    Stabilization of the Low-Spin State in a Mononuclear Iron(II) Complex and High-Temperature Cooperative Spin Crossover Mediated by Hydrogen Bonding
    Chem. Eur. J. (2016), 22, 331-339 - link
  • 142 | J. P. T. Zaragoza, M. A. Siegler, D. P. Goldberg
    Rhenium(V)–oxo corrolazines: isolating redox-active ligand reactivity
    Chem. Commun. (2016), 52, 167-170 - link

2015

  • 141 | T. F. van Dijkman, M. A. Siegler, E. Bouwman
    Highly tunable fluorinated trispyrazolylborates [HB(3-CF3-5-{4-RPh}pz)3]– (R = NO2, CF3, Cl, F, H, OMe and NMe2) and their copper(I) complexes
    Dalton Trans. (2015), 44, 21109-21123 - link
  • 140 | A. E. Pascui, K. van Rees, D. W. Zant, D. L. J. Broere, M. A. Siegler, J. I. van der Vlugt
    Macrocyclic Platinum(II) Complexes with a Bifunctional Diphosphine Ligand
    Eur. J. Inorg. Chem. (2015), 34, 5687-5693 - link
  • 139 | T. F. van Dijkman, H. M. de Bruijn, M. A. Siegler, E. Bouwman
    Bright Cyan Phosphorescence of a (Phosphane)copper(I) Complex of the Tri­hydrido­pyrazolylborate Ligand H3B(3,5-Ph2Pz)–
    Eur. J. Inorg. Chem. (2015), 2015, 5387-5394 - link
  • 138 | R. A. Baglia, K. A. Prokop-Prigge, H. M. Neu, M. A. Siegler, D. P. Goldberg
    Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction
    J. Am. Chem. Soc. (2015), 137, 10874-10877 - link
  • 137 | M. D. Struble, M. Gargiulo Holl, M. T. Scerba, M. A. Siegler, T. Lectka
    Search for a Symmetrical C-F-C Fluoronium Ion in Solution: Kinetic Isotope Effects, Synthetic Labeling, Computational, Solvent and Rate Studies
    J. Am. Chem. Soc. (2015), 137, 11476-11490 - link
  • 136 | S. Hematian, I. Kenkel, T. E. Shubina, M. Dürr, J. J. Liu, M. A. Siegler, I. Ivanovic-Burmazovic, K. D. Karlin
    Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-FeIII–O–CuII(L) Constructs
    J. Am. Chem. Soc. (2015), 137, 6602-6615 - link
  • 135 | J. P. T. Zaragoza, R. A. Baglia, M. A. Siegler, D. P. Goldberg
    Strong Inhibition of O-Atom Transfer Reactivity for MnIV(O)(π-Radical-Cation)(Lewis Acid) versus MnV(O) Porphyrinoid Complexes
    J. Am. Chem. Soc. (2015), 137, 6531-6540 - link
  • 134 | V. Vreeken, M. A. Siegler, B. de Bruin, J. N. H. Reek, M. Lutz, J. I. van der Vlugt
    C-H Activation of Benzene by a Photoactivated NiII(azide): Formation of a Transient Nickel Nitrido Complex
    Angew. Chem. Int. Ed. (2015), 54, 7055-7059 - link
  • 133 | E.C.M. Ording-Wenker, M. A. Siegler, M. Lutz, E. Bouwman
    Catalytic Catechol Oxidation by Copper Complexes: Development of a Structure-Activity Relationship
    Dalton Trans. (2015), 44, 12196-12209 - link
  • 132 | H. M. Neu, J. Jung, R. A. Baglia, M. A. Siegler, K. Ohkubo, S. Fukuzumi, D. P. Goldberg
    Light-Driven, Proton-Controlled, Catalytic Aerobic C–H Oxidation Mediated by a Mn(III) Porphyrinoid Complex
    J. Am. Chem. Soc (2015), 137, 4614-4617 - link
  • 131 | M. D. Struble, M. G. Holl, G. Coombs, M. A. Siegler, T. Lectka
    Synthesis of a Tight Intramolecular OH---Olefin Interaction, Probed by IR, 1H NMR and Quantum Chemistry
    J. Org. Chem. (2015), 80, 4803-4807 - link
  • 130 | P. Kumar, Y-M. Lee, Y J. Park, M. A. Siegler, K. D. Karlin, W. Nam
    Reactions of Co(III)–Nitrosyl Complexes with Superoxide and Their Mechanistic Insights
    J. Am. Chem. Soc (2015), 137, 4284-4287 - link
  • 129 | D. L. J. Broere, S. Demeshko, B. de Bruin, E. A. Pidko, J. N. H. Reek, M. A. Siegler, M. Lutz, J. I. van der Vlugt
    Dinuclear Palladium Complexes with Two Ligand-CenteredRadicals and a Single Bridging Ligand: Subtle Tuning of MagneticProperties
    Chem. Eur. J. (2015), 21, 5879-5886 - link
  • 128 | X. Guo, J. Zhou, M. A. Siegler, A. E. Bragg, H. E. Katz
    Visible-Light-Triggered Molecular Photoswitch Based on Reversible E/Z Isomerization of a 1,2-Dicyanoethene Derivative
    Angew. Chem. Int. Ed. (2015), 54, 4782-4786 - link
  • 127 | S. Kim, J. W. Ginsbach, J. Yoon Lee, R. L. Peterson, J. J. Liu, M. A. Siegler, A. A. Sarjeant, E. I. Solomon, K. D. Karlin
    Amine Oxidative N-Dealkylation via Cupric Hydroperoxide Cu-OOH Homolytic Cleavage Followed by Site-Specific Fenton Chemistry
    J. Am. Chem. Soc. (2015), 137, 2867-2874 - link
  • 126 | S. Kim, J. Yoon Lee, R. E. Cowley, J. W. Ginsbach, M. A. Siegler, E. I. Solomon, K. D. Karlin
    A N3S(thioether)-Ligated CuII-Superoxo with Enhanced Reactivity
    J. Am. Chem. Soc. (2015), 137, 2796-2799 - link
  • 125 | E. C.M. Ording-Wenker, M. A. Siegler, E. Bouwman
    Coordination of new disulfide ligands to CuI and CuII: Does a CuIIμ-thiolate complex form?
    Inorg. Chim. Acta (2015), 428, 193-202 - link
  • 124 | S. Kakuda, C. Rolle, K. Ohkubo, M. A. Siegler, K. D. Karlin , S. Fukuzumi
    Lewis Acid-Induced Change from Four- to Two-Electron Reduction of Dioxygen Catalyzed by Copper Complexes Using Scandium Triflate
    J. Am. Chem. Soc. (2015), 137, 3330-3337 - link
  • 123 | S. Long, P. Zhou, K. L Theiss, M. A Siegler and T. Li
    Solid-State Identity of 2-Hydroxynicotinic Acid and Its Polymorphism
    CrystEngComm (2015), 17, 5195-5205 - link
  • 122 | S. Surampudi, M.-L. Yeh, M. A. Siegler, J. F. Martinez Hardigree, T. A. Kasl, H. E. Katz, R.S. Klausen
    Increased Carrier Mobility in End-Functionalized Oligosilanes
    Chem. Sci. (2015), 6, 1905-1909 - link
  • 121 | A. M. Fry, O. T. Sweeney, W. A. Phelan, N. Drichko, M A. Siegler, T. M. McQueen
    Unique edge-sharing sulfate-transition metal coordination in Na2M(SO4)2 (M=Ni and Co)
    J. Solid State Chem. (2015), 222, 129-135 - link
  • 120 | D. L. J. Broere, L. L. Metz, B. de Bruin, J. N. H. Reek, M. A. Siegler, J. I. van der Vlugt
    Redox-Active Ligand-Induced Homolytic Bond Activation
    Angew. Chem. Int. Ed. (2015), 54, 1516-1520 - link

2014

  • 119 | S. Hong, K. D. Sutherlin, J. Park, E. Kwon, M. A. Siegler, E. I. Solomon, W. Nam
    Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex
    Nat. Commun. (2014), 5:5440, link
  • 118 | A. Khrimian, S. Shirali, K. E. Vermillion, M. A. Siegler, F. Guzman, K. Chauhan, J. R. Aldrich, D. C. Weber
    Determination of the Stereochemistry of the Aggregation Pheromone of Harlequin Bug, Murgantia histrionica
    J. Chem. Ecol. (2014), 40, 1260-1268 - link
  • 117 | S. Zheng, M. A. Siegler, O. Roubeau, S. Bonnet
    Influence of Selenocyanate Ligands on the Transition Temperature and Cooperativity of bapbpy-Based Fe(II) Spin-Crossover Compounds
    Inorg. Chem. (2014), 53, 13162-13173 - link
  • 116 | E. C. M. Ording-Wenker, M. van der Plas, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
    Protonation of a Biologically Relevant CuII μ-Thiolate Complex: Ligand Dissociation or Formation of a Protonated CuI Disulfide Species?
    Chem. Eur. J. (2014), 51, 16913-16921 - link
  • 115 | W. D. Kerber, K. A. Perez, C. Ren, M. A. Siegler
    Speciation of Ferric Phenoxide Intermediates during the Reduction of Iron(III)−μ-Oxo Dimers by Hydroquinone
    Inorg. Chem. (2014), 53, 11507-11516 - link
  • 114 | S. Sahu, M. G. Quesne, C. G. Davies, M. Dürr, I. Ivanović-Burmazović, M. A. Siegler, G. N. L. Jameson, S. P. de Visser, D. P. Goldberg
    Direct Observation of a Nonheme Iron(IV)−Oxo Complex That Mediates Aromatic C−F Hydroxylation
    J. Am. Chem. Soc. (2014), 136, 13542-13545 - link
  • 113 | E. C.M. Ording-Wenker, M. van der Plas, M. A. Siegler, S. Bonnet, F. M. Bickelhaupt, C. Fonseca Guerra, E. Bouwman
    Thermodynamics of the CuII μ-Thiolate and CuI Disulfide Equilibrium: A Combined Experimental and Theoretical Study
    Inorg. Chem. (2014), 53, 8494-8504 - link
  • 112 | M. D. Struble, C. Kelly, M. A. Siegler, T. Lectka
    Search for a Strong, Virtually “No-Shift” Hydrogen Bond: A Cage Molecule with an Exceptional OH...F Interaction
    Angew. Chem. Int. Ed. (2014), 53, 8924-8928 - link
  • 111 | A. Khrimian, A. Zhang, D. C. Weber, H-Y. Ho, J. R. Aldrich, K. E. Vermillion, M. A. Siegler, S. Shirali, F. Guzman, T. C. Leskey
    Discovery of the Aggregation Pheromone of the Brown Marmorated Stink Bug (Halyomorpha halys) through the Creation of Stereoisomeric Libraries of 1-Bisabolen-3-ols
    J. Nat. Prod. (2014), 77, 1708-1717 - link
  • 110 | C. R. Pitts, S. Bloom, R. Woltornist, D. Auvenshine, L. R. Ryzhkov, M. A. Siegler, T. Lectka
    Direct, Catalytic Monofluorination of sp3 C H Bonds: A Radical-Based Mechanism with Ionic Selectivity
    J. Am. Chem. Soc. (2014), 136, 9780-9791 - link
  • 109 | M. J. Percino, M. Cerón, P. Ceballos, G. Soriano-Moro, M. E. Castro, V. M. Chapela, J. Bonilla-Cruz, M. Reyes-Reyes, R. López-Sandoval, M. A. Siegler
    Important role of molecular packing and intermolecular interactions in two polymorphs of (Z)-2-phenyl-3-(4-(pyridin-2-yl)phenyl)acrylonitrile. Preparation, structures, and optical properties
    J. Mol. Struct. (2014), 1078, 74-82 - link
  • 108 | S. Kim, J. W. Ginsbach, A. I. Billah, M. A. Siegler, C. D. Moore, E. I. Solomon, K. D. Karlin
    Tuning of the Copper-Thioether Bond in Tetradentate N3S(thioether) Ligands; O-O Bond Reductive Cleavage via a [CuII2(µ-1,2-peroxo)]2+/[CuIII2(µ-oxo)2]2+ Equilibrium
    J. Am. Chem. Soc. (2014), 136, 8063-8071 - link
  • 107 | L. R. Widger, Y. Jiang, A. C. McQuilken, T. Yang, M. A. Siegler, H. Matsumura, P. Moenne-Loccoz, S. P. de Visser, D. P. Goldberg
    Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere
    Dalton Trans. (2014), 43, 7522-7532 - link
  • 106 | D. R. Levine, M. A. Siegler, J. D. Tovar
    Thiophene-fused borepins as directly functionalizable boron-containing p-electron systems
    J. Am. Chem. Soc. (2014), 136, 7132–7139 - link
  • 105 | A. Talanov, W. A. Phelan, Z. A. Kelly, M. A. Siegler, T. M. McQueen
    Control of the Iridium Oxidation State in the Hollandite Iridate Solid Solution K1-xIr4O8
    Inorg. Chem. (2014), 53, 4500-4507 - link
  • 104 | S. Kim, M. A. Siegler, K. D. Karlin
    Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction
    Chem. Commun. (2014), 50, 2844-2846 - link
  • 103 | R. C. Conyers, J. R. Mazzone, M. A. Siegler, A. K. Tripathi, D. J. Sullivan, B. T. Mott, G. H. Posner
    The survival times of malaria-infected mice are prolonged more by several new two-carbon-linked artemisinin-derived dimer carbamates than by the trioxane antimalarial drug artemether
    Bioorg. Med. Chem. Lett. (2014), 24, 1285-1289 - link
  • 102 | L. R. Widger, C. G. Davies, T. Yang, M. A. Siegler, O. Troeppner, G. N. L. Jameson, I. Ivanovic-Burmazovic, D. P. Goldberg
    Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres
    J. Am. Chem. Soc. (2014), 136, 2699-2702 - link
  • 101 | S. Hematian, M. A. Siegler, K. D. Karlin
    Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity
    J. Biol. Inorg. Chem. (2014), 19, 515-528 - link
  • 100 | A. Garza-Ortiz, P. U. Maheswari, M. Lutz, M. A. Siegler, J. Reedijk
    Tuning the cytotoxic properties of new ruthenium(III) and ruthenium(II) complexes with a modified bis(arylimino)pyridine Schiff base ligand using bidentate pyridine-based ligands
    J. Biol. Inorg. Chem. (2014), 19, 675-689 - link
  • 99 | S. Akerboom, M. S. Meijer, M. A. Siegler, W. T. Fu, E. Bouwman
    Structure, photo- and triboluminescence of the lanthanoid dibenzoylmethanates: HNEt3[Ln(dbm)4]
    J. Lumin. (2014), 145, 278-282 - link
  • 98 | M. D. Struble, J. Strull, K. Patel, M. A. Siegler, T. Lectka
    Modulating 'Jousting' C-F---H-C interactions with a Bit of Hydrogen Bonding
    J. Org. Chem. (2014), 79, 1-6 - link


2013

  • 97 | S. Akerboom, Jos J. M. H. van den Elshout, I. Mutikainen, M. A. Siegler, W. T. Fu, E. Bouwman
    Substituted Phenanthrolines as Antennae in Luminescent EuIII Complexes
    Eur. J. Inorg. Chem. (2013), 2013, 6137-6146- link
  • 96 | E. C. M. Ording-Wenker, M. A. Siegler, M. Lutz, E. Bouwman
    CuI Thiolate Reactivity with Dioxygen: The Formation of CuII Sulfinate and CuII Sulfonate Species via a CuII Thiolate Intermediate
    Inorg. Chem. (2013), 52, 13113-13122 - link
  • 95 | R. L. Peterson, J. W. Ginsbach, R. E. Cowley, M. F. Qayyum, R. A. Himes, M. A. Siegler, C. D. Moore, B. Hedman, K. O. Hodgson, S. Fukuzumi, E. L. Solomon, K. D. Karlin
    Stepwise Protonation and Electron-Transfer Reduction of a Primary Copper-Dioxygen Adduct
    J. Am. Chem. Soc. (2013), 135, 16454-16467 - link
  • 94 | A. Garza-Ortiz, P. Uma Maheswari, M. Siegler, A. L. Spek, J. Reedijk
    A new family of Ru(II) complexes with a tridentate pyridine Schiff-base ligand and bidentate co-ligands: synthesis, characterization, structure and in vitro cytotoxicity studies
    New J. Chem. (2013), 37, 3450-3460 - link
  • 93 | R. D. Slack, M. A. Siegler, G. H. Posner
    Highly stereocontrolled and regiocontrolled syntheses of polyoxygenated [2.2.2]oxabicyclic synthons
    Tetrahedron Letters (2013), 54, 6267-6270 - link
  • 92 | A. C. McQuilken, Y. Ha, K. D. Sutherlin, M. A. Siegler, K. O. Hodgson, B. Hedman, E. I. Solomon, G. N. L. Jameson, D. P. Goldberg
    Preparation of Non-heme {FeNO}7 Models of Cysteine Dioxygenase: Sulfur versus Nitrogen Ligation and Photorelease of Nitric Oxide
    J. Am. Chem. Soc. (2013), 135, 14024–14027 - link
  • 91 | L. R. Widger, Y. Jiang, M. A. Siegler, D. Kumar, R. Latifi, S. P. de Visser, G. N. L. Jameson, D. P. Goldberg
    Synthesis and Ligand Non-Innocence of Thiolate-Ligated (N4S) Iron(II) and Nickel(II) Bis(imino)pyridine Complexes
    Inorg. Chem. (2013), 52, 10467-10480 - link
  • 90 | W. Ward, B. H. Farnum, M. A. Siegler, G. J. Meyer
    Chloride Ion-Pairing with Ru(II) Polypyridyl Compounds in Dichloromethane
    J. Phys. Chem. A (2013), 117, 8883-8894 - link
  • 89 | A. Bahreman, B. Limburg, M. A. Siegler, E. Bouwman, S. Bonnet
    Spontaneous Formation in the Dark, and Visible Light-Induced Cleavage, of a Ru-S Bond in Water: A Thermodynamic and Kinetic Study
    Inorg. Chem. (2013), 52, 9456-9469 - link
  • 88 | S. Oldenhof, B. de Bruin, M. Lutz, M. A. Siegler, F. Patureau, J. I. van der Vlugt, J. N. H. Reek
    Base-Free Production of H2 by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex
    Chem. Eur. J. (2013), 19, 11507-11511 - link
  • 87 | S. Sahu, L. R. Widger, M. G. Quesne, S. P. de Visser, H. Matsumura, P. Moenne-Loccoz, M. A. Siegler, D. P. Goldberg
    Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach
    J. Am. Chem. Soc. (2013), 135, 10590-10593 - link
  • 86 | M. D. Struble, M. T. Scerba, M. Siegler, T. Lectka
    Evidence for a Symmetrical Fluoronium Ion in Solution
    Science (2013), 340, 57-60 - link
  • 85 | P. Leeladee, G. N. L. Jameson, M. A. Siegler, D. Kumar, Sam P. de Visser, D. P. Goldberg
    Generation of a High-Valent Iron Imido Corrolazine Complex and NR Group Transfer Reactivity
    Inorg. Chem. (2013), 52, 4668-4682 - link
  • 84 | L. R. Widger, M. A. Siegler, D. P. Goldberg
    Sulfide oxidation by O2: Synthesis, structure and reactivity of novel sulfide-incorporated Fe(II) bis(imino)pyridine complexes
    Polyhedron (2013), 58, 179-189 - link
  • 83 | B. T. Mott, A. Tripathi, M. A. Siegler, C. D. Moore, D. J. Sullivan, G. H. Posner
    Synthesis and Antimalarial Efficacy of Two-Carbon-Linked, Artemisinin-Derived Trioxane Dimers in Combination with Known Antimalarial Drugs
    J. Med. Chem, (2013), 56, 2630-2641 - link
  • 82 | S. Zheng, M. A. Siegler, J. C. Sanchez , W-T. Fu, S. Bonnet
    Effect of Metal Dilution on the Thermal Spin Transition of [FexZn1-x(bapbpy)(NCS)2]
    Eur. J. Inorg. Chem. (2013), 5-6, 1033-1042 - link


2012

  • 81 | S. Kim, C. Saracini, M. A. Siegler, N. Drichko, K. D. Karlin
    Coordination Chemistry and Reactivity of a Cupric Hydroperoxide Species Featuring a Proximal H-Bonding Substituent
    Inorg. Chem. (2012), 51, 12603-12605. Link

  • 80 | S. Hematian, M. A. Siegler, K. D. Karlin
    Heme/Copper Assembly Mediated Nitrite and Nitric Oxide Interconversion
    J. Am. Chem. Soc. (2012), 134, 18912-18915. Link

  • 79 | A. Yokoyama, J. E. Han, J. Cho, M. Kubo, T. Ogura, M. A. Siegler, K. D. Karlin, W. Nam
    Chromium(IV)-Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity
    J. Am. Chem. Soc. (2012), 134, 15269-15272. Link

  • 78 | M. A. Siegler, S. Parkin, C. P. Brock
    [Ni(MeCN)(H2O)2(NO3)2].(15-crown-5).MeCN: detailed study of a four-phase sequence that includes an intermediate modulated phase
    Acta Cryst. B (2012), 68, 389-400. Link

  • 77 | A. Bahreman, B. Limburg, M. A. Siegler, R. Koning, A. J. Koster, S. Bonnet
    Ruthenium Polypyridyl Complexes Hopping at Anionic Lipid Bilayers through a Supremolecular Bond Sensitive to Visible Light
    Chem. Eur. J. (2012), 18, 10271-10280. Link

  • 76 | R. A. Ghiladi, A. L. Rheingold, M. A. Siegler, K. D. Karlin
    Synthesis and characterization of new trinuclear copper complexes
    Inorg. Chim. Acta (2012), 389, 131-137. Link

  • 75 | D. R. Levine, A. Caruso, M. A. Siegler, J. D. Tovar
    Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings
    Chem. Commun. (2012), 48, 6256-6258. Link

  • 74 | A. C. McQuilken, Y. Jiang, M. A. Siegler and D. P. Goldberg
    Addition of Dioxygen to an N4S(thiolate) Iron(II) Cysteine Dioxygenase Model Gives a Structurally Characterized Sulfinato-Iron(II) Complex
    J. Am. Chem. Soc. (2012), 134, 8758-8761. Link

  • 73 | W. B. Heuer, H-L. Xia, W. Ward, Z. Zhou, W. H. Pearson, M. A. Siegler, A. A. Narducci Sarjeant, M. Abrahamsson, G. J. Meyer
    New Dicarboxylic Acid Bipyridine Ligand for Ruthenium Polypyridyl Sensitization of TiO2
    Inorg. Chem. (2012), 51, 3981-3988. Link

  • 72 | Y. M. Badiei, Y. Jiang, L. R. Widger, M. A. Siegler, D. P. Goldberg
    Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: Unexpected transmetalation mediated by LiAlH4
    Inorg. Chim. Acta (2012), 382, 19-26. Link

  • 71 | F. W. Patureau, C. Worch, M. A. Siegler, A. L. Spek, C. Bolm, J. N. H. Reek
    SIAPhos: Phosphorylated Sulfonimidamides and their Use in Iridium-Catalized Aymmetric Hydrogenations of Sterically Hindered Cyclic Enamides
    Adv. Synth. Catal. (2012), 354, 59-64. Link

  • 70 | M. Scerba, S. Bloom, N. Haselton, M. Siegler, J. Jake, T. Lectka
    Interaction of a C-F Bond with the pi-System of a C=C Bond or "Head On" with a Proximate C-H Bond
    J. Org. Chem. (2012), 77, 1605-1609. Link

  • 69 | D. Guthrie, N. Kim, M. Siegler, C. Moore, J. Toscano
    Development of N-Substitued Hydroxylamines as Efficient Nitroxyl (HNO) Donors
    J. Am. Chem. Soc. (2012), 134, 1962-1965. Link

  • 68 | F. W. Patureau, M. A. Siegler, A. L. Spek, A. J. Sandee, S. Juge, S. Aziz, A. Berkessel, J. N. H. Reek
    Supramolecular Hydrogen-Bonding Tautomeric Sulfonamido-Phosphinamides: A Perfect P-Chirogenic Memory
    Eur. J. Inorg. Chem. (2012), 3, 496-503. Link


2011

  • 67 | Z. Arcis-Castíllo, S. Zheng, M. A. Siegler, O. Roubeau, S. Bedoui and S. Bonnet
    Tuning the Transition Temperature and Cooperativity of bapbpy-Based Mononuclear Spin-Crossover Compounds: Interplay between Molecular and Crystal Engineering
    Chem. Eur. J. (2011), 17, 14826-14836. Link

  • 66 | M. A. Siegler, X. Hao, S. Parkin, C. P. Brock
    [Ni(H2O)6](NO3)2.(15-crown-5).2H2O: three phase transitions and an intermediate modulated phase stable over a range of ca. 40 K
    Acta Cryst. B (2011), 67, 486-498. Link

  • 65 | N. J. M. Pijnenburg, M. Lutz, M. A. Siegler, A. Spek, G. van Koten, R. J. M. Klein Gebbink
    The role of the dendritic support in the catalytic performance of peripheral pincer Pd-complexes
    New J. Chem. (2011), 35, 2356-2365. Link

  • 64 | M. T. Scerba, C. M. Leavitt, M. E. Diener, A. F. DeBlase, T. L. Guasco, M. A. Siegler, N. Bair, M. A. Johnson, T. Lectka
    NH+-F Hydrogen Bonding in a Fluorinated "Proton Sponge" Derivative: Integration of Solution, Solid-State, Gas-Phase, and Computational Studies
    J. Org. Chem. (2011), 76, 7975-7984. Link

  • 63 | R. E. Goldbach, I. Rodriguez-Garcia, J. H. van Lenthe, M. A. Siegler, S. Bonnet
    N-Acetylmethionine and Biotin as Photocleavable Protective Groups for Ruthenium Polypyridyl Complexes
    Chem. Eur. J. (2011), 17, 9924-9929. Link

  • 62 | C. P. Hencken, D. T. Genna, M. A. Siegler, G. H. Posner
    Highly Stereocontrolled and Regiocontrolled Syntheses of 2,3,4-Trisubstituted Alkanoates and Lactones
    J. Org. Chem. (2011), 76, 5149-5155. Link

  • 61 | M. Hojahmat, G. Zheng, M. Siegler, S. Parkin, M. Biermann, P. A. Crooks
    (S)-1-(2-Chlorophenyl)-2-oxocyclohexan-1-aminium D-tartrate
    Acta Cryst. E (2011), 67, 736. Link

  • 60 | J. A. van Rijn, E. Gouré, M. A. Siegler, A. L. Spek, E. Drent, E. Bouwman
    The intriguing substitution behavior of CO with bidentate phosphine ligands induced by a gem-dialkyl effect
    J. Organ. Chem. (2011), 696, 1899-1903. Link

  • 59 | D. K. Moon, A. Tripathi, D. Sullivan, M. A. Siegler, S. Parkin, G. H. Posner
    A single, low, oral dose of a 5-carbon-linked trioxane dimer orthoester plus mefloquine cures malaria-infected mice
    Bioorg. Med. Chem. Lett. (2011), 21, 2773-2775. Link

  • 58 | M. A. Siegler, S. Parkin, R. J. Angel, C. P. Brock
    Detailed study of the phase transition in [Ni(H2O)6](NO3)2.(15-crown-5).H2O and analysis in terms of mean-field theory
    Acta Cryst. B (2011), 67, 130-143. Link

  • 57 | W. I. Dzik, A. L. Fuente, M. A. Siegler, A. L. Spek, J. N. H. Reek, B. de Bruin
    Open-Shell Organometallic [MII(dbcot(bislutidylamine)]2+ Complexes (M = Rh, Ir): Unexpected Base-Assisted Reduction of the Metal Instead of Amine Ligand Deprotonation
    Organometallics (2011), 30, 1902-1913. Link

  • 56 | D. J. M. Snelders, M. A. Siegler, L. von Chrzanowski, A. L. Spek, G. van Koten, R. J. M. Klein Gebbink
    Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines
    Dalton Trans. (2011), 40, 2588-2600. Link

  • 55 | D. Achey, S. Ardo, H-L. Xia, M. A. Siegler and G. J. Meyer
    Sensitization of TiO2 by the MLCT Excited State of Co(I) Coordination Compounds
    J. Phys. Chem. Lett. (2011), 2, 305-308. Link

  • 54 | R. L. Peterson, R. A. Himes, H. Kotani, T. Suenobu, L. Tian, M. A. Siegler, E. I. Solomon, S. Fukuzumi, K. D. Karlin
    Cupric-Superoxo Mediated Inter-Molecular C-H Activation Chemistry
    J. Am. Chem. Soc. (2011), 133, 1702-1705. Link

  • 53 | S. Long, M. A. Siegler, A. Mattei, T. Li
    Phase Transition from Two Z' = 1 Forms to a Z' = 2 Form of a Concomitant Conformational Polymorphic System
    Cryst. Growth & Des. (2011), 11, 414-421. Link

  • 52 | Y. M. Badiei, M. A. Siegler, D. P. Goldberg
    O2 Activation by Bis(imino)pyridine Iron(II)-Thiolate Complexes
    J. Am. Chem. Soc. (2011), 133, 1274-1277. Link


2010

  • 51 | J. Li, M. Siegler, M. Lutz, A. L. Spek, R. J. M. Klein Gebbink and G. van Koten
    PCN- and PCS-Pincer Palladium Complexes as Tandem Catalysts in Homoallylation Reactions
    Adv. Synth. Catal. (2010), 352, 2474-2488. Link

  • 50 | S. Bonnet, M. A. Siegler, J. H. van Lenthe, M. Lutz, A. L. Spek, G. van Koten, R. J. M. Klein Gebbink
    Ruthenium-to-Platinum Interactions in η6,η1 NCN-Pincer Arene Heterobimetallic Complexes: an Experimental and Theoretical Study
    Eur. J. Inorg. Chem. (2010), 29, 4667-4677. Link

  • 49 | D. T. Genna, C. P. Hencken, M. A. Siegler, G. H. Posner
    α-Chloro-β,γ-Ethylenic Esters: Enantiocontrolled Synthesis and Substitutions
    Org. Lett. (2010), 12, 4694-4697. Link

  • 48 | Y. Jiang, L. R. Widger, G. D. Kasper, M. A. Siegler, D. P. Goldberg
    Iron(II)-Thiolate S-Oxygenation by O2: Synthetic Models of Cysteine Dioxygenase
    J. Am. Chem. Soc. (2010), 132, 12214-12215. Link

  • 47 | M. A. Siegler, S. Bonnet, A. M. M. Schreurs, R. J. M. Klein Gebbink, G. van Koten, A. L. Spek
    On the two closely related phases of [Ru(C5Me5)(η6-1,3-(Me2NCH2)2C6H4)](BF4) and the reversible solid-solid order-disorder phase transition
    J. Chem. Cryst. (2010), 40, 753-760. Link

  • 46 | M. A. Siegler, E. Stavitski
    On the sequence of three related phases of [Ni(H2O)2(15-crown-5)](HSO4)2 in the T-range 110-295 K
    Acta Cryst. B (2010), 66, 430-440. Link

  • 45 | J. Meeuwissen, R. Detz, A. J. Sandee, B. de Bruin, M. A. Siegler, A. L. Spek, J. N. H. Reek
    Ureaphosphanes as Hybrid, Anionic or Supramolecular Bidentate Ligands for Asymmetric Hydrogenation Reactions
    Eur. J. Inorg. Chem. (2010), 19, 2992-2997. Link

  • 44 | J. Wassenaar, M. A. Siegler, A. L. Spek, B. de Bruin, J. N. H. Reek, J. I. van der Vlugt
    Versatile New C3-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize CuI and RhI Species and Tune Their Reactivity
    Inorg. Chem. (2010), 49, 6495-6508. Link

  • 43 | A. Caruso Jr., M. A. Siegler, J. D. Tovar
    Synthesis of Functionalizable Boron-Containing -Electron Materials that Incorporate Formally Aromatic Fused Borepin Rings
    Angew. Chem. Int. Ed. (2010), 49, 4213-4217. Link

  • 42 | M. Rubio, M. A. Siegler, A. L. Spek, J. N. H. Reek
    Heterotopic silver-NHC complexes: from coordination polymers to supramolecular assemblies
    Dalton Trans. (2010), 39, 5432-5435. Link

  • 41 | J. Meeuwissen, A. J. Sandee, B. de Bruin, M. A. Siegler, A. L. Spek, J. N. H. Reek
    Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde
    Organometallics (2010), 29, 2413-2421. Link

  • 40 | J. Wassenaar, E. Jansen, W-J. van Zeist, F. M. Bickelhaupt, M. A. Siegler, A. L. Spek, J. N. H. Reek
    Catalyst selection based on intermediate stability measured by mass spectrometry
    Nat. Chem. (2010), 2, 417-421. Link

  • 39 | M. A. Siegler, J. H. Prewitt, S. P. Kelley, S. Parkin, J. P. Selegue, C. P. Brock
    More examples of the 15-crown-5...H2O-M-OH2...15-crown-5 motif, M = Al3+, Cr3+ and Pd2+
    Acta Cryst. B (2010), 66, 213-221. Link

  • 38 | Y. Cabon, H. Kleijn, M. A. Siegler, A. L. Spek, R. J. M. Klein Gebbink, B-J. Deelman
    Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands
    Dalton Trans. (2010), 39, 2423-2427. Link

  • 37 | J. Wassenaar, B. de Bruin, M. A. Siegler, A. L. Spek, J. N. H. Reek, J. I. van der Vlugt
    Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand
    Chem. Commun. (2010), 46, 1232-1234. Link

  • 36 | G. Berthon-Gelloz, M. A. Siegler, A. L. Spek, B. Tinanta, J. N. H. Reek, I. E. Markó
    IPr* an easily accessible highly hindered N-heterocyclic carbene
    Dalton Trans. (2010), 39, 1444-1446. Link


2009

  • 35 | J. I. van der Vlugt, M. A. Siegler, M. Janssen, D. Vogt, A. L. Spek
    A Cationic AgI(PNPtBu) Species Acting as PNP Transfer Agent: Facile Synthesis of Pd(PNPtBu)(alkyl) Complexes and Their Reactivity Compared to PCPtBu Analogues
    Organometallics (2009), 28, 7025-7032. Link

  • 34 | J. A. van Rijn, M. A. Siegler, A. L. Spek, E. Bouwman, E. Drent
    Ruthenium-Diphosphine-Catalyzed Allylation of Phenols: A gem-Dialkyl-Type Effect Induces High Selectivity toward O-Allylation
    Organometallics (2009), 28, 7006-7014. Link

  • 33 | Y. Lee, G-Y. Park, H. R. Lucas, P. L. Vajda, K. Kamaraj, M. A. Vance, A. E. Milligan, J. S. Woertink, M. A. Siegler, A. A. Narducci Sarjeant, L. N. Zakharov, A. L. Rheingold, E. I. Solomon, K. D. Karlin
    Copper(I)/O2 Chemistry with Imidazole Containing Tripodal Tetradentate Ligands Leading to µ-1,2-Peroxo-Dicopper(II) Species
    Inorg. Chem. (2009), 48, 11297-11309. Link

  • 32 | M. Rubio, E. Jellema, M. A. Siegler, A. L. Spek, J. N. H. Reek, B. de Bruin
    Supramolecular NHC ligands: on the influence of ZnII-templates on the activity of RhI(cod) complexes in 'carbene polymerization'
    Dalton Trans. (2009), 41, 8970-8976. Link

  • 31 | M. A. N. Virboul, M. Lutz, M. A. Siegler, A. L. Spek, G. van Koten, R. J. M. Klein Gebbink
    One-Pot Synthesis and Immobilisation of Sulfonate-Tethered N-Heterocyclic Carbene Complexes on Polycationic Dendrimers
    Chem. Eur. J. (2009), 15, 9981-9986. Link

  • 30 | J. Li, M. A. Siegler, M. Lutz, A. L. Spek, R. J. M. Klein Gebbink, G. van Koten
    Chiral ortho-Palladated and -Platinated Arylphosphite Complexes
    Organometallics (2009), 28, 5323-5332. Link

  • 29 | S. Warsink, P. Hauwert, M. A. Siegler, A. L. Spek, C. J. Elsevier
    Palladium(0) pre-catalysts with heteroditopic NHC-amine ligands by transmetallation from their silver(I) complexes
    Appl. Organometal. Chem. (2009), 23, 225-228. Link

  • 28 | R. Angamuthu, L. L. Gelauff, M. A. Siegler, A. L. Spek, E. Bouwman
    A molecular cage of nickel(II) and copper(I): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes
    Chem. Commun. (2009), 19, 2700-2702. Link

  • 27 | F. W. Patureau, S. de Boer, M. Kuil, J. Meeuwissen, PA. R. Breuil, M. A. Siegler, A. L. Spek, A. J. Sandee, B. de Bruin, J. N. H. Reek
    Sulfonamido-Phosphoramidite Ligands in Cooperative Dinuclear Hydrogenation Catalysis
    J. Am. Chem. Soc. (2009), 131, 6683-6685. Link

  • 26 | J. Wassenaar, S. van Zutphen, G. Mora, P. Le Floch, M. A. Siegler, A. L. Spek, J. N. H. Reek
    INDOLPhosphole and INDOLPhos Palladium-Allyl Complexes in Asymmetric Allylic Alkylations
    Organometallics (2009), 28, 2724-2734. Link

  • 25 | S. Bonnet, J. Li, M. A. Siegler, L. S. von Chrzanowski, A. L. Spek, G. van Koten, R. J.M. Klein Gebbink
    Synthesis and Resolution of Planar-Chiral Ruthenium-Palladium Complexes with ECE' Pincer Ligands
    Chem. Eur. J. (2009), 15, 3340-3343. Link

  • 24 | S. Bonnet, J. H. van Lenthe, M. A. Siegler, A. L. Spek, G. van Koten, R. J. M. Klein Gebbink
    Bimetallic η6, η1 NCN-Pincer Ruthenium Palladium Complexes with η6-RuCp Coordination: Synthesis, X-ray Structures, and Catalytic Properties
    Organometallics (2009), 28, 2325-2333. Link

  • 23 | S. Bonnet, G. Molnár, J. Sánchez Costa, M. A. Siegler, A. L. Spek, A. Bousseksou, W. Fu, P. Gamez, J. Reedijk
    Influence of Sample Preparation, Temperature, Light, and Pressure on the Two-Step Spin Crossover Mononuclear Compound [Fe(bapbpy)(NCS)2]
    Chem. Mater. (2009), 21, 1123-1136. Link

  • 22 | M. A. Siegler, M. Lutz
    Ni(salen): a System That Forms Many Solvates with Interacting Ni Atoms
    Cryst. Growth & Des. (2009), 9, 1194-1200. Link


2008

  • 21 | M. A. Siegler, X. Hao, S. Parkin, C. P. Brock
    Five more phases of the structural family [M(H2O)2(15-crown-5)](NO3)2
    Acta Cryst. B (2008), 64, 738-749. Link

  • 20 | M. A. Siegler, S. Parkin, J. P. Selegue, C. P. Brock
    The elusive [Ni(H2O)(15-crown-5)]2+ cation and related co-crystals of Ni(II) hydrates and 15-crown-5
    Acta Cryst. B (2008), 64, 725-737. Link

  • 19 | S. Bonnet, M. A. Siegler, J. Sánchez Costa, G. Molnár, A. Bousseksou, A. L. Spek, P. Gamez, J. Reedijk
    A two-step spin-crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase
    Chem. Commun. (2008), 43, 5619-5621. Link

  • 18 | S. Long, S. Parkin, M. A. Siegler, A. Cammers, T. Li
    Polymorphism and Phase Behaviors of 2-(Phenylamino)nicotinic Acid
    Cryst. Growth & Des. (2008), 8, 4006-4013. Link

  • 17 | S. Long, S. Parkin, M. Siegler, C. P. Brock, A. Cammers, T. Li
    Polymorphism of an Organic System Effected by the Directionality of Hydrogen-Bonding Chains
    Cryst. Growth & Des. (2008), 8, 3137-3140. Link

  • 16 | SA. Garza-Ortiz, P. U. Maheswari, M. Siegler, A. L. Spek, J. Reedijk
    Ruthenium(III) Chloride Complex with a Tridentate Bis(arylimino)pyridine Ligand: Synthesis, Spectra, X-ray Structure, 9-Ethylguanine Binding Pattern, and In Vitro Cytotoxicity
    Inorg. Chem (2008), 47, 6964-6973. Link

  • 15 | J. Chen, S. Subramanian, S. Parkin, M. Siegler, K. Gallup, C. Haughn, D. C. Martin, J. E. Anthony
    The influence of side chains on the structures and properties of functionalized pentacenes
    J. Mater. Chem. (2008), 63, 1961-1969. Link

  • 14 | M. A. Siegler, H. Kooijman, A. L. Spek
    (S)-6-Methyl-ε-caprolactone
    Acta Cryst. E (2008), 64, 607. Link

  • 13 | M. A. Siegler, H. Kooijmam, A. L. Spek
    (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methylethenyl)perhydronaphthalen-2one
    Acta Cryst. E (2008), 64, 337. Link


2007

  • 12 | M. A. Siegler, Y. Fu, G. H. Simpson, D. P. King, S. Parkin, C. P. Brock
    An unexpected co-crystal with a variable degree of order: 1 :1 rac-1,2-cyclohexanediol/triphenylphosphine oxide
    Acta Cryst. B (2007), 63, 912-925. Link

  • 11 | Y-H Xu, M. Siegler, S. Long
    (3aR,7aR)-Bis(4-nitrophenyl) 2-oxoperhydrobenzo[d]imidazole-1,3-dicarboxylate
    Acta Cryst. E (2007), 63, 3835. Link

  • 10 | M. Zhong, M. Siegler, S. Long
    tert-Butyl N-[(1R,2R)-2-(isothiocyanato)-cyclohexyl]carbamate
    Acta Cryst. E (2007), 63, 3589. Link

  • 9 | S. Long, M. Siegler, T. Li
    2,4,6-Trimethylbenzenaminium chloride
    Acta Cryst. E (2007), 63, 3080. Link

  • 8 | V. N. Sonar, J. R. Ring, M. Siegler, P. A. Crooks
    (E)-1-[(2-Chlorophenyl)methyleneamino]guanidinium chloride
    Acta Cryst. E (2007), 63, 974-975. Link

  • 7 | V. N. Sonar, S. Neelakantan, M. Siegler, P. A. Crooks
    (E)-1-[(2-Methoxyphenyl)methyleneamino]guanidinium chloride
    Acta Cryst. E (2007), 63, 535-536. Link

  • 6 | S. Long, M. Siegler, T. Li
    6-Chloronicotinic acid
    Acta Cryst. E (2007), 63, 279-281. Link


2006

  • 5 | S. Long, M. Siegler, T. Li
    2-Oxo-1,2-dihydropyridine-3-carboxylic acid
    Acta Cryst. E (2006), 62, 5664-5665. Link

  • 4 | M. Siegler, S. Long
    (4R,5R)-4,5-Diphenylimidazolidin-2-one
    Acta Cryst. E (2006), 62, 5310-5311. Link

  • 3 | S. Long, M. Siegler, T. Li
    N-(3-Chloro-2-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxamide
    Acta Cryst. E (2006), 62, 4278-4279. Link

  • 2 | S. Long, M. Siegler, T. Li
    2-(2-Isopropylanilino)pyridine-3-carboxylic acid
    Acta Cryst. E (2006), 62, 4211-4213. Link


2005

  • 1 | X. Hao, M. A. Siegler, S. Parkin, C. P. Brock
    [M(H2O)2(15-crown-5)](NO3)2: A System Rich in Polymorphic and Modulated Phases
    Cryst. Growth & Des. (2005), 5, 2225-2232. Link

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