JHU X-ray Crystallography Facility

"All we have discovered is that it starts with a single individual - always a child - and then spreads explosively, like the formation of crystals round the first nucleus in a saturated solution." Arthur C. Clarke (Childhood's End, 1953)

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Dr. Maxime A. Siegler

X-ray Facility Manager
Small-Molecule Crystallography (Service)

Rooms 240 (Office), 211 (X-ray lab), New Chemistry Building
Phone: 410 516 8569
Fax: 410 516 7044
Email: xray@jhu.edu

Ph.D. Dissertation - link

Education

2007 Ph.D., University of Kentucky, Lexington, KY, USA
2002 B.S./M.Sc., Hautes Études d'Ingenieur, Lille, France

Publications

2025	2024	2023	2022	2021	2020	2019	2018	2017	2016	2015	2014	2013	2012	2011	2010	2009
2008	2007	2006	2005

2025

2024

• 356 | J. E. Bos, M. A. Siegler, S. J. Wezenberg
  Activity Control of a Synthetic Transporter by Photodynamic Modulation of Membrane Mobility and Incorporation
  J. Am. Chem. Soc. (2024), 146, 31085–31093 - link

• 355 | P. T. Orban, S. M. Bernier, T. Berry, M. A. Siegler, T. M. McQueen
  Random-exchange Heisenberg behavior in the electron-doped quasi-one-dimensional spin-1 chain compound AgVP₂⁢S₆
  Phys. Rev. B (2024), 110, 054423 - link

• 354 | G. Bassen, B. Wilfong, W. Bunstine, N. Edmiston, M. A. Siegler, T. M. McQueen
  Tolerance Factor Approach for the Design of Quaternary Materials as Applied to the A₂Ln₄Cu_2nQ_7+n Homologous Series
  J. Am. Chem. Soc. (2024), 146, 25190-25199 - link

• 353 | P. K. Hota, S. Panda, H. Phan, B. Kim, M. A. Siegler, K. D. Karlin
  Dioxygenase Chemistry in Nucleophilic Aldehyde Deformylations Utilizing Dicopper O₂-Derived Peroxide Complexes
  J. Am. Chem. Soc. (2024), 146, 23854-23871 - link

• 352 | J. S. Wagner, M. A. Siegler, Aimée. L. Tomlinson, J. R. Reynolds
  Controlling Charged State Colors in Triphenylamine-Based Anodically Coloring Electrochromes
  Adv. Opt. Mater. (2024), 12, 2400855 - link

• 351 | S. Abyar, L. Huang, Y. Husiev, L. Bretin, B. Chau, V. Ramu, J. Hendricus Wildeman, K. Belfor, L. S. Wijaya, V. E. van der Noord, A. C. Harms, M. A. Siegler, S. E. Le Dévédec, S. Bonnet
  Oxygen-Dependent Interactions between the Ruthenium Cage and the Photoreleased Inhibitor in NAMPT-Targeted Photoactivated Chemotherapy
  J. Med. Chem. (2024), 67, 11086-11102 - link

• 350 | M. Wang, N. Garrison, P. Minh Nguyen, A. Prasad, Y. Wang, H-K. Kwon, G. Kim, M. A. Siegler, T. Lectka
  Can the −CF₃ Group Act as a Tight, Well-Defined Hydrogen Bond Acceptor? A Clear Crystallographic CF₂–F···H–N⁺ Interaction Says Yes
  J. Org. Chem. (2024), 89, 9681-9685 - link

• 349 | A. T. Stoltzfus, J. G. Ballot, T. Vignane, H. Li, M. M. Worth, L. Muller, M. A. Siegler, M A. Kane, M. R. Filipovic, D. P. Goldberg, S. L. J. Michel
  Chemoselective Proteomics, Zinc Fingers, and a Zinc(II) Model for H₂S Mediated Persulfidation
  Angew. Chem. Int. Ed. (2024), 63, e202401003 - link

• 348 | N. Ng, M. A. Siegler, S. Bernier, W. Bunstine, T. M. McQueen
  Disordered layers and dimerization in the crystal structure of TaOCl₂
  J. Solid State Chem. (2024), 337, 124771 - link

• 347 | S. Panda, H. Phan, E. M. Dunietz, M. T. Brueggemeyer, P. Kumar Hota, M. A. Siegler, A. Jose, M. Bhadra, E. I. Solomon, K. D. Karlin
  Intramolecular Phenolic H-Atom Abstraction by a N₃ArOH Ligand-Supported (μ-η²:η²-Peroxo)dicopper(II) Species Relevant to the Active Site Function of oxy-Tyrosinase
  J. Am. Chem. Soc. (2024), 146, 14942–14947 - link

• 346 | T. Wu, A. Puri, Y. Lin Qiu, D. Ye, R. Sarma, Y. Wang, T. Kowalewski, M. A. Siegler, M. Swart, I. Garcia-Bosch
  Tuning the Thermochemistry and Reactivity of a Series of Cu-Based 4H,⁺/4e^- Electron-Coupled-Proton Buffers
  Inorg. Chem. (2024), 63, 9014-9025 - link

• 345 | H. Wakefield IV, S. J. Melvin, J. Jiang, I. Kevlishvili, M. A. Siegler, S. L. Craig, H. J. Kulik, R. S. Klausen
  Angle-strained sila-cycloalkynes
  Chem. Commun. (2024), 60, 4842-4845 - link

• 344 | S. Yadav, V. Yadav, M. A. Siegler, P. Moënne-Loccoz, G. N. L. Jameson, D P. Goldberg
  A Nonheme Iron(III) Superoxide Complex Leads to Sulfur Oxygenation
  J. Am. Chem. Soc. (2024), 146, 7915–7921 - link

• 343 | X-Q. Zhou, S. Abyar, I. Carbo-Bague, L. Wang, S. Türck, M. A. Siegler, U. Basu, I. Ott, R. Liu, A. P. IJzerman, S. Bonnet
  Multitarget Thiol-Activated Tetrapyridyl Gold(III) Complexes for Hypoxic Cancer Therapy
  CCS Chem. (2024), 6, 783–797 - link

• 342 | K. Sagar, M. Kim, T. Wu, S. Zhang, E. L. Bominaar, M. A. Siegler, M. Hendrich, I. Garcia-Bosch
  Mimicking the Reactivity of LPMOs with a Mononuclear Cu Complex
  Eur. J. Inorg. Chem. (2024), 27, e202300774 - link

• 341 | R. F. J. Epping, F. J. de Zwart, N. P. van Leest, J. I. van der Vlugt, M. A. Siegler, S. Mathew, J. N. H. Reek, B. de Bruin
  PhenTAA: A Redox-Active N₄-Macrocyclic Ligand Featuring Donor and Acceptor Moieties
  Inorg. Chem. (2024), 63, 1974–1987 - link

• 340 | J. de Jong, M. A. Siegler, S. J. Wezenberg
  A Photoswitchable Macrocycle Controls Anion-Templated Pseudorotaxane Formation and Axle Relocalization
  Angew. Chem. Int. Ed. (2024), 63, e202316628 - link

• 339 | A. Puri, A. McAninch, S. Shu, K. Rajabimoghadam, M. A. Siegler, M. Swart, I. Garcia-Bosch
  Geometric control of Cu, Ni and Pd complexes in the solid state via intramolecular H-bonding interactions
  Inorg. Chem. (2024), 561, 121844 - link

• 338 | D. den Boer, H. Stegman, C. J. C. Peeters, M. A. Siegler, D. G. H. Hetterscheid
  Electronic Structure Variations of Cu-Based Water Oxidation Catalysts Bearing Redox-Active Ligands
  Eur. J. Inorg. Chem. (2024), 27, e202300475 - link

2023

• 337 | M. Langerman, P. H. van Langevelde, J. J. van de Vijver, M. A. Siegler, D. G. H. Hetterscheid
  Scaling Relation between the Reduction Potential of Copper Catalysts and the Turnover Frequency for the Oxygen and Hydrogen Peroxide Reduction Reactions
  Inorg. Chem. (2023), 62, 19593–19602 - link

• 336 | E. Yang, X. E. Shen, H. West-Foyle, T-H. Hahm, M. A. Siegler, D. R. Brown, Cole C. Johnson, J. H. Kim, L. A. Roker, C. M. Tressler, I. Barman, S. C. Kuo, K. Glunde
  FluoMALDI Microscopy: Matrix Co-Crystallization Simultaneously Enhances Fluorescence and MALDI Imaging
  Adv. Sci. (2023), 10, 2304343 - link

• 335 | N. G. Garrison, S. A. Harry, M. A. Siegler, G. Cariello, R. A. Cormanich, T. Lectka
  The C-F⋅⋅⋅H-CF₂ interaction: A combination of hydrogen bonding and n → σ* stabilization
  J. Fluor. Chem. (2023), 272, 110191 - link

• 334 | V. Yadav, L. Wen, S. Yadav, M. A. Siegler, D. P. Goldberg
  Selective Radical Transfer in a Series of Nonheme Iron(III) Complexes
  Inorg. Chem. (2023), 62, 17830–17842 - link

• 333 | L. A. Pressley, M. Sinha, M. A. Siegler, N. Edmiston, S. Bernier, A. M. Ferrenti, S. Das, R. Ramesh, S. Kushwaha, T. M. McQueen
  Tunable W⁵⁺ Absorbance in Laser Floating Zone Grown Bismuth Tungstate
  J. Phys. Chem. C (2023), 127, 19386–19395 - link

• 332 | A. M. Ferrenti, M. A. Siegler, S. Ghosh, X. Zhang, N. Kintop, H. K. Vivanco, C. Lygouras, T. Halloran, S. Klemenz, C. Broholm, N. Drichko, T. M. McQueen
  Chemical tuning of a honeycomb magnet through a critical point
  Phys. Rev. B (2023), 108, 064433 - link

• 331 | K. K. Singh, C. S. Gerke, S. S. Saund, A. M. Zito, M. A. Siegler, V. Sara Thoi
  CO₂ Activation with Manganese Tricarbonyl Complexes by an H-Atom Responsive Benzimidazole Ligand
  Chem. Eur. J. (2023), 29, e202300796 - link

• 330 | N. Duindam, M. van Dongen, M. A. Siegler, S. J. Wezenberg
  Monodirectional Photocycle Drives Proton Translocation
  J. Am. Chem. Soc. (2023), 145, 21020–21026 - link

• 329 | M. Kazim, Z. Feng, S. Vemulapalli, M. A. Siegler, A. Chopra, P. M. Nguyen, M. G. Holl, L. Guan, T. Dudding, D. J. Tantillo, T. Lectka
  Through-Space, Lone-Pair Promoted Aromatic Substitution: A Relay Mechanism Can Beat Out Direct Activation
  Chem. Eur. J. (2023), 28, e202301550 - link

• 328 | H. Man, A. Ghasemi, M. Adnani, M. A. Siegler, E. A. Anber, Y. Li, C-L. Chien, M. L. Taheri, C-W. Chu, C. L. Broholm, S. M. Koohpayeh
  Quantum paramagnetism in a non-Kramers rare-earth oxide: Monoclinic Pr₂Ti₂O₇
  Phys. Rev. Mater. (2023), 7, 063401 - link

• 327 | D. Villarón, G. E. A. Brugman, M. A. Siegler, S. J. Wezenberg
  Photoswitching of halide-binding affinity and selectivity in dithienylethene-strapped calix[4]pyrrole
  Chem. Commun. (2023), 56, 8688-8691 - link

• 326 | M. L. A. Hakkennes, M. S. Meijer, J. P. Menzel, A-C. Goetz, R. Van Duijn, M. A. Siegler, F. Buda, S. Bonnet
  Ligand Rigidity Steers the Selectivity and Efficiency of the Photosubstitution Reaction of Strained Ruthenium Polypyridyl Complexes
  J. Am. Chem. Soc. (2023), 145, 13420–13434 - link

• 325 | M. Kazim, M. Wang, S. Vemulapalli, P. Minh Nguyen, Y. Wang, M. A. Siegler, T. Dudding, T. Lectka
  How Do Face-to-Face Stacked Aromatic Rings Activate Each Other to Electrophilic Aromatic Substitution?
  Org. Lett. (2023), 25, 4318-4322 - link

• 324 | L. A. Pressley, H. K. Vivanco, T. Berry, M. A. Siegler, T. M. McQueen
  Transition metal (dis)order in single crystal multicomponent rare earth perovskites
  J. Cryst. Growth (2023), 617, 127262 - link

• 323 | B. Kim, M. T. Brueggemeyer, W. J. Transue, Y. Park, J. Cho, M. A. Siegler, E. I. Solomon, K. D. Karlin
  Fenton-like Chemistry by a Copper(I) Complex and H2O2 Relevant to Enzyme Peroxygenase C-H Hydroxylation
  J. Am. Chem. Soc. (2023), 145, 11735–11744 - link

• 322 | X-Q. Zhou, P. Wang, V. Ramu, L. Zhang, S. Jiang, X. Li, S. Abyar, P. Papadopoulou, Y. Shao, L. Bretin, M. A. Siegler, F. Buda, A. Kros, J. Fan, X. Peng, W. Sun, S. Bonnet
  In vivo metallophilic self-assembly of a light-activated anticancer drug
  Nat. Chem. (2023), 15, 980-987 - link

• 321 | H. Wakefield IV, I. Kevlishvili, K. E. Wentz, Y. Yao, T. B. Kouznetsova, S. J. Melvin, E. G. Ambrosius, A. Herzog-Arbeitman, M. A. Siegler, J. A. Johnson, S. L. Craig, H. J. Kulik, R. S. Klausen
  Synthesis and Ring-Opening Metathesis Polymerization of a Strained trans-Silacycloheptene and Single-Molecule Mechanics of Its Polymer
  J. Am. Chem. Soc. (2023), 145, 10187-10196 - link

• 320 | K. K. Singh, A. Bhattacharyya, S. Havenridge, M. Ghabin, H. Ausmann, M. A. Siegler, C. M. Aikens, A. Das
  A first glance into mixed phosphine–stibine moieties as protecting ligands for gold clusters
  Nanoscale (2023), 15, 6934-6940 - link

• 319 | D. den Boer, A. I. Konovalov, M. A. Siegler, D. G. H. Hetterscheid
  Unusual Water Oxidation Mechanism via a Redox-Active Copper Polypyridyl Complex
  Inorg. Chem. (2023), 62, 5303–5314 - link

• 318 | M. Wang, R. K. Sachs, S. A. Harry, E. Holt, M. A. Siegler, T. Lectka
  Bifurcated hydrogen bonding to fluorine in an all cis-difluoro-hydroxy array
  J. Fluor. Chem. (2023), 267, 110104 - link

• 317 | R-D. Gao, M. Taylor, T. McInnis, Z. Chen, S. S. Gori, H. M. LaPorte, M. A. Siegler, J. L. Neisewander, R. H. Mach, M. Singh, B. S. Slusher, R. Rais, R. R. Luedtke, T. Tsukamoto
  Synthesis and Pharmacological Characterization of a Difluorinated Analogue of Reduced Haloperidol as a Sigma-1 Receptor Ligand
  ACS Chem. Neurosci. (2023), 14, 947–957 - link

• 316 | J. B. Gordon, T. Albert, S. Yadav, J. Thomas, M. A. Siegler, P. Moënne-Loccoz*, D. P. Goldberg
  Oxygen versus Sulfur Coordination in Cobalt Superoxo Complexes: Spectroscopic Properties, O₂ Binding, and H-Atom Abstraction Reactivity
  Inorg. Chem. (2023), 62, 392-400 - link

• 315 | E. P. van Geest, S. K. Götzfried, D. M. Klein, N. Salitra, S. Popal, Y. Husiev, C. J. Van der Griend, X. Zhou, M. A. Siegler, G. F. Schneider, S. Bonnet
  A Lock-and-Kill Anticancer Photoactivated Chemotherapy Agent
  Photochem. Photobiol. (2023), 99, 777-786 - link

• 314 | A. E. Castillo, E. Pérez-Gutiérrez, P. Ceballos, P. Venkatesan, S. Thamotharan, M A. Siegler, M. J. Percino
  Non-covalent interactions towards 2-(4-(2,2-dicyanovinyl) benzylidene)malononitrile packing polymorphism due to solvent effect. Experimental and theoretical spectroscopy approach
  J. Mol. Struct. (2023), 1275, 134674 - link

2022

• 313 | A. F. Gittens, Q. Jiang, M. A. Siegler, R. S. Klausen
  Conjugation in Isomeric Cyclosilane Thioethers
  Organometallics (2022), 41, 3762–3769 - link

• 312 | S. Banerjee, X. Han, M. A. Siegler, E. M. Miller, N. M. Bedford, B. C. Bukowski, V. Sara Thoi
  Flexible 2D Boron Imidazolate Framework for Polysulfide Adsorption in Lithium–Sulfur Batteries
  Chem. Mater. (2022), 34, 10451–10458 - link

• 311 | V. Yadav, L. Wen, R. J. Rodriguez, M. A. Siegler, D. P. Goldberg
  Nonheme Iron(III) Azide and Iron(III) Isothiocyanate Complexes: Radical Rebound Reactivity, Selectivity, and Catalysis
  J. Am. Chem. Soc. (2022), 144, 20641-20652 - link

• 310 | M. T.Scerba, D. Tweedie, D. Lecca, M. A.Siegler, R. Rais, N. H.Greig
  Thionated aminofluorophthalimides reduce classical markers of cellular inflammation in LPS-challenged RAW 264.7 cells
  Bioorg. Med. Chem. Lett. (2022), 76, 128972 - link

• 309 | C. van de Griend, J. J. van de Vijver, M. A. Siegler, R. T. Dame, S. Bonnet
  Ruthenium-Locked Helical Chirality: A Barrier of Inversion and Formation of an Asymmetric Macrocycle
  Inorg. Chem. (2022), 61, 16045–16054 - link

• 308 | S. A. Harry, N. G. Garrison, A. Zhu, M. R. Xiang, M. A. Siegler, T. Lectka
  C–F Bonds as “Frozen” Nucleophiles: Unconsummated S_N2 Reactions
  J. Org. Chem. (2022), 87, 13406–13410 - link

• 307 | C. Marvelous, L. de Azevedo Santos, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
  Redox Conversion of Cobalt(II)-Diselenide to Cobalt(III)-Selenolate Compounds: Comparison with Their Sulfur Analogs
  Eur. J. Inorg. Chem. (2022), 2022, e202200445 - link

• 306 | T. Wu, K. Rajabimoghadam, A. Puri, D. D. Hebert, Y. Lin Qiu, S. Eichelberger, M. A. Siegler, M. Swart, M. P. Hendrich, I. Garcia-Bosch
  A 4H+/4e– Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex
  J. Am. Chem. Soc. (2022), 144, 16905–16915 - link

• 305 | C. Marvelous, M. A.Siegler, E. Bouwman
  Structural investigations and reactivity of cobalt(II)–disulfide compounds
  Inorg. Chim. Acta (2022), 543, 121193 - link

• 304 | S. Banerjee, J. M. Gorham, P. Beccar-Varela, H. G. Hackbarth, M. A. Siegler, N. Drichko, J. T. Wright, N. M. Bedford, V. Sara Thoi
  Atomically Dispersed CuNx Sites from Thermal Activation of Boron Imidazolate Cages for Electrocatalytic Methane Generation
  ACS Appl. Energy Mater. (2022), , - link

• 303 | S. A. Harry, M. Kazim, P. M. Nguyen, A. Zhu, M. R. Xiang, J. Catazaro, M. Siegler, T. Lectka
  The Close Interaction of a C−F Bond with an Amide Carbonyl: Crystallographic and Spectroscopic Characterization
  Angew. Chem. Int. Ed. (2022), 61, e202207966 - link

• 302 | C. Marvelous, L. de Azevedo Santos, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
  Cleaner and stronger: how 8-quinolinolate facilitates formation of Co(III)–thiolate from Co(II)–disulfide complexes
  Dalton Trans. (2022), 51, 11675-11684 - link

• 301 | Q. Jiang, A. F. Gittens, S. Wong, M. A. Siegler, R. S. Klausen
  Highly selective addition of cyclosilanes to alkynes enabling new conjugated materials
  Chem. Sci. (2022), 13, 7587-7593 - link

• 300 | A. M. Ferrenti, M. A. Siegler, S. Gao, N. Ng, T. M. McQueen
  ScSI: A New Exfoliatable Semiconductor
  Chem. Mater. (2022),34, 5443-5451 - link

• 299 | C. Marvelous, L. de Azevedo Santos, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
  Probing the redox-conversion of Co(II)-disulfide to Co(III)-thiolate complexes: the effect of ligand-field strength
  Dalton Trans. (2022), 51, 8046-8055 - link

• 298 | D. den Boer, Q. Siberie, M. A. Siegler, T. H. Ferber, D. C. Moritz, J. P. Hofmann, D. G. H. Hetterscheid
  On the Homogeneity of a Cobalt-Based Water Oxidation Catalyst
  ACS Catal. (2022), 12, 4597–4607 - link

• 297 | F. Jiang, C. Marvelous, A. C. Verschuur, M. A. Siegler, S J. Teat, E. Bouwman
  Cobalt(II)-disulfide compounds with the unusual PF₂O₂^– anion. ligand-dependent redox conversion to a cobalt(III)-thiolate complex
  Inorg. Chim. Acta (2022), 535, 120880 - link

• 296 | N. V. Machushynets, S. S. Elsayed, C. Du, M. A. Siegler, M. de la Cruz, O. Genilloud, T. Hankemeier, G. P. van Wezel
  Discovery of actinomycin L, a new member of the actinomycin family of antibiotics
  Sci. Rep. (2022), 12, 2813 - link

• 295 | J. N. Capilato, S. A. Harry, M. A. Siegler, T. Lectka
  Spectroscopic and Crystallographic Characterization of the R₃N⁺−C−H⋅⋅⋅X Interaction
  Chem. Eur. J. (2022), 28, e202103922 - link

• 294 | J. J. D. Sacramento, T. Albert, M. Siegler, P. Moënne-Loccoz, D. P. Goldberg
  An Iron(III) Superoxide Corrole from Iron(II) and Dioxygen
  Angew. Chem. Int. Ed. (2022), 61, e202111492 - link

• 293 | N. W. G. Smits, D. Rademaker, A. I. Konovalov, M. A. Siegler, D. G. H. Hetterscheid
  Influence of the spatial distribution of copper sites on the selectivity of the oxygen reduction reaction
  Dalton Trans. (2022), 51, 1206-1215 - link

• 292 | J. B. Patty, S. Havenridge, D. Tietje-Mckinney, M. A. Siegler, K. K. Singh, R. Hajy Hosseini, M. Ghabin, C. M. Aikens, A. Das
  Crystal Structure and Optical Properties of a Chiral Mixed Thiolate/Stibine-Protected Au₁₈ Cluster
  J. Am. Chem. Soc. (2022), 144, 478-484 - link

• 291 | S. J. Wezenberg, L-J. Chen, J. E. Bos, B. L. Feringa, E. N. W. Howe, X. Wu, M. A. Siegler, P. A. Gale
  Photomodulation of Transmembrane Transport and Potential by Stiff-Stilbene Based Bis(thio)ureas
  J. Am. Chem. Soc. (2022), 144, 331-338 - link

2021

• 290 | J. B. Gordon, T. Albert, A. Dey, S. Sabuncu, M. A. Siegler, E. Bill, P. Moënne-Loccoz, D. P. Goldberg
  A Reactive, Photogenerated High-Spin (S = 2) Fe^IV(O) Complex via O₂ Activation
  J. Am. Chem. Soc. (2021), 143, 21637-21647 - link

• 289 | D. M. Klein, S. Rodríguez-Jiménez, M. E. Hoefnagel, A. Pannwitz, A. Prabhakaran, M. A. Siegler, Tia E. Keyes, E. Reisner, A. M. Brouwer, S. Bonnet
  Shorter Alkyl Chains Enhance Molecular Diffusion and Electron Transfer Kinetics between Photosensitisers and Catalysts in CO₂-Reducing Photocatalytic Liposomes
  Chem. Eur. J. (2021), 27, 17203-17212 - link

• 288 | G. W. Farley, M. A. Siegler, D. P. Goldberg
  Halogen Transfer to Carbon Radicals by High-Valent Iron Chloride and Iron Fluoride Corroles
  Inorg. Chem. (2021), 60, 17288–17302 - link

• 287 | J. G. Alvarado, D. C. Cummins, A. C. Diaconescu, M. A. Siegler, D. P. Goldberg
  The selective monobromination of a highly sterically encumbered corrole: Structural and spectroscopic properties of Fe(Cl)(2-bromo-5,10,15-tris(triphenyl)phenyl corrole)
  J. Porphyr. Phthalocyanines (2021), 25, 1176-1185 - link

• 286 | E. Ballestero-Martínez, J. T. Ferguson, M. A. Siegler, R. S. Klausen
  Isolation of a Cyclopentasilane from Magnesium Reduction of a Linear Hexasilane
  Eur. J. Org. Chem. (2021), 33, 4641-4646 - link

• 285 | R. Trammell, A. Cordova, S. Zhang, S. Goswami, R. Murata, M. A. Siegler, I. Garcia-Bosch
  Practical One-Pot Multistep Synthesis of 2H-1,3-Benzoxazines Using Copper, Hydrogen Peroxide, and Triethylamine
  Eur. J. Org. Chem. (2021), 32, 4536-4540 - link

• 284 | A. Dey, J. B. Gordon, T. Albert, S. Sabuncu, M. A. Siegler, S. N. MacMillan, K. M. Lancaster, P. Moënne-Loccoz, D. P. Goldberg
  A Nonheme Mononuclear {FeNO}⁷ Complex that Produces N₂O in the Absence of an Exogenous Reductant
  Angew. Chem. Int. Ed. (2021), 60, 21558-21564 - link

• 283 | A. E.Castillo, P. Ceballos, M. Cerón, E. Pérez-Gutiérrez, Martha Sosa-Rivadeneyra, W. Bernal, S. Thamotharan, M. A.Siegler, M. J. Percino
  Spectroscopic characterization of 4,5-diphenyl-2-(2,4,5-trimethoxyphenyl)-1H-imidazole obtained from the condensation of benzyl. Experimental and DFT approach
  J. Mol. Struct. (2021), 1246, 131269 - link

• 282 | X-Q. Zhou, M. Mytiliniou, J. Hilgendorf, Y. Zeng, P. Papadopoulou, Y. Shao, M. Paradiz Dominguez, L. Zhang, M. B. S. Hesselberth, E. Bos, M. A. Siegler, F. Buda, A. M. Brouwer, A. Kros, R. I. Koning, D. Heinrich, S. Bonnet
  Intracellular Dynamic Assembly of Deep-Red Emitting Supramolecular Nanostructures Based on the Pt…Pt Metallophilic Interaction
  Adv. Mater. (2021), 33, 2008613 - link

• 281 | S. S. Saund, M. A. Siegler, V. S. Thoi
  Electrochemical Degradation of a Dicationic Rhenium Complex via Hoffman-Type Elimination
  Inorg. Chem. (2021), 60, 13011-13020 - link

• 280 | A. Busemann, I. Flaspohler, X-Q. Zhou, C. Schmidt, S. K. Goetzfried, V. H. S. van Rixel, I. Ott, M. A. Siegler, S. Bonnet
  Ruthenium-based PACT agents based on bisquinoline chelates: synthesis, photochemistry, and cytotoxicity
  J. Biol. Inorg. Chem. (2021), 26, 667-674 - link

• 279 | S. Zhang, R. Trammell, A. Cordova, M. A. Siegler, I. Garcia-Bosch
  Cu-promoted intramolecular hydroxylation of Csingle bondH bonds using directing groups with varying denticity
  J. Inorg. Biochem. (2021), 223, 111557 - link

• 278 | M. Sinha, H. K. Vivanco, C. Wan, M. A. Siegler, V. J. Stewart, E. A. Pogue, L. A. Pressley, T. Berry, Z. Wang, I. Johnson, M. Chen, T. T. Tran, W. A. Phelan, T. M. McQueen
  Twisting of 2D Kagomé Sheets in Layered Intermetallics
  ACS Cent. Sci. (2021), 7, 1381-1390 - link

• 277 | A. Shirvan, H. Golchoubian, M. A.Siegler, E. Bouwman
  Copper (II) halide complexes with NNO tridentate ligand as chromotropic probes; synthesis, structural characterization and spectroscopic properties
  J. Mol. Struct. (2021), 1243, 130930 - link

• 276 | T. Wu, J. Musgrove, M. A. Siegler, I. Garcia-Bosch
  Mononuclear and Dinuclear Copper Complexes of Tridentate Redox-active Ligands with Tunable H-bonding Donors: Structure, Spectroscopy and H⁺/e⁻ Reactivity
  Chem. Asian J. (2021), 16, 1608-1618 - link

• 275 | M. T. Scerba, M. A. Siegler, N. H. Greig
  Thionation of Aminophthalimide Hindered Carbonyl Groups and Application to the Synthesis of 3,6′-Dithionated Pomalidomides
  Synlett (2021), 60, Ahead of Print - link

• 274 | J. B. Gordon, J. P. McGale, M. A. Siegler, D. P. Goldberg
  Proton-Coupled Electron-Transfer Reactivity Controls Iron versus Sulfur Oxidation in Nonheme Iron–Thiolate Complexes
  Inorg. Chem. (2021), 60, 6255-6265 - link

• 273 | A. Castillo, P. Ceballos, P. Santos, M. Cerón, P. Venkatesan, E. Pérez-Gutiérrez, M. Sosa-Rivadeneyra, S. Thamotharan, M. A. Siegler, M. J. Percino
  Solution and Solid-State Photophysical Properties of Positional Isomeric Acrylonitrile Derivatives with Core Pyridine and Phenyl Moieties: Experimental and DFT Studies
  Molecules (2021), 26, 1500 - link

• 272 | X-Q. Zhou, I. Carbo-Bague, M. A. Siegler, J. Hilgendorf, U. Basu, I. Ott, R. Liu, L. Zhang, V. Ramu, A. P. IJzerman, S. Bonnet
  Rollover Cyclometalation vs Nitrogen Coordination in Tetrapyridyl Anticancer Gold(III) Complexes: Effect on Protein Interaction and Toxicity
  JACS Au (2021), 1, 380-395 - link

• 271 | M. Bhadra, W. J. Transue, H. Lim, R. E. Cowley, J. Y. C. Lee, M. A. Siegler, P. Josephs, G. Henkel, M. Lerch, S. Schindler, A. Neuba, K. O. Hodgson, B. Hedman, E. I. Solomon, K. D. Karlin
  A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity
  J. Am. Chem. Soc. (2021), 143, 3707-3713 - link

• 270 | D. Villarón, M. A. Siegler, S. J. Wezenberg
  A photoswitchable strapped calix[4]pyrrole receptor: highly effective chloride binding and release
  Chem. Sci. (2021), 12, 3188-3193 - link

• 269 | A. Pannwitz, H. Saaring, N. Beztsinna, X. Li, M. A. Siegler, S. Bonnet
  Mimicking Photosystem I with a Transmembrane Light Harvester and Energy Transfer‐Induced Photoreduction in Phospholipid Bilayers
  Chem. Eur. J. (2021), 27, 3013–3018 - link

• 268 | V. Yadav , M. A. Siegler, D. P. Goldberg
  Temperature-Dependent Reactivity of a Non-heme FeIII(OH)(SR) Complex: Relevance to Isopenicillin N Synthase
  J. Am. Chem. Soc. (2021), 143, 46–52 - link

• 267 | J. N. Capilato, M. A. Siegler, R. Rowshanpour, T. Dudding, T. Lectka
  Cooperative Noncovalent Interactions Lead to a Highly Diastereoselective Sulfonyl-Directed Fluorination of Steroidal α,β-Unsaturated Hydrazones
  J. Org. Chem. (2021), 86, 1300–1307 - link

• 266 | E. Pérez–Gutiérrez, M. J. Percino, W. Bernal, M. Cerón, P. Ceballos, M. S. Rivadeneyra, M. A.Siegler, S. Thamotharane
  Fluorescence tuning with a single dye embedded in a polymer matrix and its Application on multicolor OLEDs
  Dyes Pigm. (2021), 186, 108979 - link

2020

• 265 | F. J. Claire, M. A. Solomos, J. Kim, G. Wang, M. A. Siegler, M. F. Crommie, Thomas J. Kempa
  Structural and electronic switching of a single crystal 2D metal-​organic framework prepared by chemical vapor deposition
  Nat. Commun (2020), 11, 5524 - link

• 264 | H. Lim, M. L. Baker, R. E. Cowley, S. Kim, M. Bhadra, M. A. Siegler, T. Kroll, D. Sokaras, T-C. Weng, D. R. Biswas, D. M. Dooley, K. D. Karlin, B. Hedman, K. O. Hodgson, E. I. Solomon
  Kβ X-​ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase
  Inorg. Chem. (2020), 59, 16567–16581 - link

• 263 | N. W. G. Smits, B. van Dijk, I. de Bruin, S. L. T. Groeneveld, M. A. Siegler, D. G. H. Hetterscheid
  Influence of Ligand Denticity and Flexibility on the Molecular Copper Mediated Oxygen Reduction Reaction
  Inorg. Chem. (2020), 59, 16398–16409 - link

• 262 | Y. Hu, F. Florio, Z. Chen, W. Adam Phelan, M. A. Siegler, Z. Zhou1, Y. Guo, R. Hawks, J. Jiang, J. Feng, L. Zhang, B. Wang, Y. Wang, D. Gall, E. F. Palermo, Z. Lu, X. Sun, T-M. Lu, H. Zhou, Y. Ren, E. Wertz,R. Sundararaman, J. Shi
  A chiral switchable photovoltaic ferroelectric 1D perovskite
  Science Advances (2020), 6, eaay4213 - link

• 261 | J. T. Ferguson, Q. Jiang, Eric A. Marro, Ma. A. Siegler, R. S. Klausen
  Long-range coupling in cyclic silanes
  Dalton Trans. (2020), 49, 14951-14961 - link

• 260 | N. P. van Leest, W. Stroek, M. A. Siegler, J. I. van der Vlugt, B. de Bruin
  Ligand-Mediated Spin-State Changes in a Cobalt-Dipyrrin-Bisphenol Complex
  Inorg. Chem. (2020), 59, 12903–12912 - link

• 259 | F. Ghorbani, S. Andrew Harry, J. N. Capilato, C. Ross Pitts, J. Joram, G. N. Peters, J. D. Tovar, I. Smajlagic, M. A. Siegler, T. Dudding, T. Lectka
  Carbonyl-Directed Aliphatic Fluorination: A Special Type of Hydrogen Atom Transfer Beats Out Norrish II
  J. Am. Chem. Soc. (2020), 142, 14710–14724 - link

• 258 | S. S. Elsayed, G. Genta-Jouve, V. J. Carrión, P. H. Nibbering, M. A. Siegler, W. de Boer, T. Hankemeier, G. P. van Wezel
  Atypical Spirotetronate Polyketides Identified in the Underexplored Genus Streptacidiphilus
  J. Org. Chem. (2020), 85, 10648–10657 - link

• 257 | M. Kazim, L. Guan, A. Chopra, R. Sun, M. A. Siegler, T. Lectka
  Switching a HO···π Interaction to a Nonconventional OH···π Hydrogen Bond: A Completed Crystallographic Puzzle
  J. Org. Chem. (2020), 85, 9801–9807 - link

• 256 | C. A. Evans, A. Zuluaga, D. Vasquez Matute, S. Baradaran-Noviri, N. Perez-Cervantes, M. A.Siegler
  Synthesis and biological evaluation of thioadatanserin and its dialkylated products as partial 5-HTR_1A agonists and 5-HTR_2A antagonists for potential use in depression and anxiety disorders
  Bioorganic Med. Chem. Lett. (2020), 30, 127358 - link

• 255 | T. Wu, S. N. MacMillan, K. Rajabimoghadam, M. A. Siegler, K. M. Lancaster, I. Garcia-Bosch
  Structure, Spectroscopy, and Reactivity of a Mononuclear Copper Hydroxide Complex in Three Molecular Oxidation States
  J. Am. Chem. Soc. (2020), 142, 12265–12276 - link

• 254 | A. Busemann, C. Araman, I. Flaspohler, A. Pratesi, X-Q. Zhou, V. H. S. van Rixel, M. A. Siegler, L. Messori, S. I. van Kasteren, S. Bonnet
  Alkyne Functionalization of a Photoactivated Ruthenium Polypyridyl Complex for Click-Enabled Serum Albumin Interaction Studies
  Inorg. Chem. (2020), 59, 7710–7720 - link

• 253 | X-Q. Zhou, M. Xiao, V. Ramu, J. Hilgendorf, X. Li, P. Papadopoulou, M. A. Siegler, A. Kros, W. Sun, S. Bonnet
  The Self-Assembly of a Cyclometalated Palladium Photosensitizer into Protein-Stabilized Nanorods Triggers Drug Uptake In Vitro and In Vivo
  J. Am. Chem. Soc. (2020), 142, 10383–10399 - link

• 252 | V. Yadav, R. J. Rodriguez, M. A. Siegler, D. P. Goldberg
  Determining the Inherent Selectivity for Carbon Radical Hydroxylation versus Halogenation with Fe^III(OH)(X) Complexes: Relevance to the Rebound Step in Non-heme Iron Halogenases
  J. Am. Chem. Soc. (2020), 142, 7259-7264 - link

• 251 | M. Kazim, M. A. Siegler, T. Lectka
  Close Amide NH···F Hydrogen Bonding Interactions in 1,8-Disubstituted Naphthalenes
  J. Org. Chem. (2020), 85, 6195-6200 - link

• 250 | W. D. Kerber, D. S. Hartnett, A. Wanga, C. Hawkins Mafrice, M. A.Siegler
  Enhanced relative stability of heterobimetallic Fe(II)​, Zn(II)​, and Mg(II) clusters supported by a μ-​phenoxo bridge
  Inorg. Chim. Acta (2020), 506, 119547 - link

• 249 | K. K. Singh, M. A. Siegler, V. Sara Thoi
  Unusual Reactivity of a Thiazole-Based Mn Tricarbonyl Complex for CO2 Activation
  Organometallics (2020), 39, 988-994 - link

• 248 | N. P. van Leest, M. A. Tepaske, J-P. H. Oudsen, B. Venderbosch, N. R. Rietdijk, M. A. Siegler. M. Tromp, J. I. van der Vlugt, B. de Bruin
  Ligand Redox Noninnocence in [Co^III(TAML)]^0/–) Complexes Affects Nitrene Formation
  J. Am. Chem. Soc. (2020), 142, 552–563 - link

• 247 | D. A. Burns, E. M. Press, M. A. Siegler, R. S. Klausen, V. Sara Thoi
  2D Oligosilyl Metal–Organic Frameworks as Multi‐state Switchable Materials
  Angew. Chem. Int. Ed. (2020), 59, 763–768 - link

2019

• 246 | J. P. T. Zaragoza, D. C. Cummins, M. Q. E. Mubarak, M. A. Siegler, S. P. de Visser, D. P. Goldberg
  Hydrogen Atom Abstraction by High-Valent Fe(OH) versus Mn(OH) Porphyrinoid Complexes: Mechanistic Insights from Experimental and Computational Studies
  Inorg. Chem. (2019), 58, 16761-16770 - link

• 245 | G. D. York, M. A. Siegler, D. D. Patel, T. Lectka
  Synthesis and X-Ray crystallography of a substituted trityl fluoride: Ordering power of a C-F bond
  J. Fluor. Chem. (2019), 228, 109377 - link

• 244 | G. B. Wijeratne, M. Bhadra, M. A. Siegler, K. D. Karlin
  Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release
  J. Am. Chem. Soc. (2019), 141, 17962-17967 - link

• 243 | E. A. Marro, C. P. Folster, E. M. Press, H. Im, J. T. Ferguson, M. A. Siegler, R. S. Klausen
  Stereocontrolled Syntheses of Functionalized cis- and trans-Siladecalins
  J. Am. Chem. Soc. (2019), 141, 17926-17936 - link

• 242 | M. Kazim, H. Foy, M. A. Siegler, T. Dudding, T. Lectka
  Discovery and Mechanistic Study of a Totally Organic C_(aryl)–C_(alkyl)Oxygen Insertion Reaction
  J. Org. Chem. (2019), 84, 14349-14353 - link

• 241 | R. Plessius, N. Orth, I. Ivanović-Burmazović, M. A. Siegler, J. N. H. Reek, J. I. van der Vlugt
  Reversible multi-electron storage in dual-site redox-active supramolecular cages
  Chem. Commun. (2019), 55, 12619-12622 - link

• 240 | K. M. van Vliet, L. H. Polak, M. A. Siegler, J. I. van der Vlugt, C. Fonseca Guerra, B. de Bruin
  Efficient Copper-Catalyzed Multicomponent Synthesis of N-Acyl Amidines via Acyl Nitrenes
  J. Am. Chem. Soc. (2019), 141, 15240-15249 - link

• 239 | C. Rebreyend, V. Mouarrawis, M. A. Siegler, J. I. van der Vlugt, B. de Bruin
  Steric Protection of Rhodium‐Nitridyl Radical Species
  Eur. J. Inorg. Chem. (2019), 2019, 4249-4255 - link

• 238 | M. Lankelma, V. Vreeken, M. A. Siegler, J. I. van der Vlugt
  Dinuclear Gold Complexes Supported by Wide Bite Angle Diphosphines for Preorganization-Induced Selective Dual-Gold Catalysis
  Inorganics (2019), 7, 28 - link

• 237 | C. P. Folster, P. N. Nguyen, M. A. Siegler, R. S. Klausen
  Tunable SiN Hybrid Conjugated Materials
  Organometallics (2019), 38, 2902-2909 - link

• 236 | A. M. Confer, S. Sabuncu, M. A. Siegler, P. Moënne-Loccoz, D. P. Goldberg
  Mononuclear, Nonheme, High-Spin {FeNO}^7/8 Complexes Supported by a Sterically Encumbered N₄S-Thioether Ligand
  Inorg. Chem. (2019), 58, 9576-9580 - link

• 235 | J. J. Liu, M. A. Siegler, K. D. Karlin, P. Moënne‐Loccoz
  Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O₂ and NO and Mechanistic Insights into Metal‐Mediated Peroxynitrite Decomposition
  Angew. Chem. Int. Ed. (2019), 58, 10936-10940 - link

• 234 | V. Yadav, J. B. Gordon, M. A. Siegler, D. P. Goldberg
  Dioxygen-Derived Nonheme Mononuclear Fe^III(OH) Complex and Its Reactivity with Carbon Radicals
  J. Am. Chem. Soc. (2019), 141, 10148-10153 - link

• 233 | K. Rajabimoghadam, Y. Darwish, U. Bashir, D. Pitman,S. Eichelberger, M. A. Siegler, I. Garcia-Bosch
  Tunable intramolecular multicenter H-bonding interactions in first-row metal complexes bearing bidentate redox-active ligands
  J. Coord. Chem. (2019), 72, 1346-1357 - link

• 232 | V. H. S. van Rixel, A. Busemann, M. F. Wissingh, S. L. Hopkins, B. Siewert, C. van de Griend, Ma. A. Siegler, T. Marzo, F. Papi, M. Ferraroni, P. Gratteri, C. Bazzicalupi, L. Messori, S. Bonnet
  Induction of a Four‐Way Junction Structure in the DNA Palindromic Hexanucleotide 5′‐d(CGTACG)‐3′ by a Mononuclear Platinum Complex
  Angew. Chem. Int. Ed. (2019), 58, 9378-9382 - link

• 231 | M. M. Li, F. J. Claire, M. A. Solomos, S. M. Tenney, S. A. Ivanov, M. A. Siegler, T. J. Kempa
  Molecular chains of coordinated dimolybdenum isonicotinate paddlewheel clusters
  RSC Adv. (2019), 9, 16492-16495 - link

• 230 | M. Kazim, M. A. Siegler, T. Lectka
  A Protonated Quinone Methide Stabilized by a Combination of Partial Aromatization and π-Interaction: Spectroscopic and Crystallographic Analysis
  J. Org. Chem. (2019), 84, 8284-8288 - link

• 229 | R. Trammell, L. D’Amore, A. Cordova, P. Polunin, N. Xie, M. A. Siegler, P. Belanzoni, M. Swart, I. Garcia-Bosch
  Directed Hydroxylation of sp² and sp³ C–H Bonds Using Stoichiometric Amounts of Cu and H₂O₂
  Inorg. Chem. (2019), 58, 7584-7592 - link

• 228 | M. J. Percino, M. Cerón, E. Pérez‐Gutiérrez, V. Perumal, M. A. Siegler, T. Subbiah, P. Ceballos, P. Gordillo‐Guerra, J. Bonilla‐Cruz, F. E. Longoria, T. Lara
  Preferential Orientation of Crystals and its Influence on the Emission Wavelength of Acrylonitrile Derivatives Treated with Polar Solvents
  Cryst. Res. Technol. (2019), 54, - link

• 227 | P. Venkatesan, M. Cerón, E. Pérez‐Gutiérrez, A. E. Castillo, S. Thamotharan, F. Robles, M. A. Siegler, J. Percino
  Experimental and Theoretical Insights into the Optical Properties and Intermolecular Interactions in Push‐Pull Bromide Salts
  ChemistryOpen (2019), 8, 483-496 - link

• 226 | X-Q. Zhou, A. Busemann, M. S. Meijer, M. A. Siegler, S. Bonnet
  The two isomers of a cyclometallated palladium sensitizer show different photodynamic properties in cancer cells
  Chem. Commun. (2019), 55, 4695-4698 - link

• 225 | M. Kazim, M. A. Siegler, T. Lectka
  A Case of Serendipity: Synthesis, Characterization, and Unique Chemistry of a Stable, Ring-Unsubstituted Aliphatic p-Quinone Methide
  Org. Lett. (2019), 21, 2326-2329 - link

• 224 | J. B. Gordon, A. C. Vilbert, M. A. Siegler, K. M. Lancaster, P. Moënne-Loccoz, David P. Goldberg
  A Nonheme Thiolate-​Ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity
  J. Am. Chem. Soc. (2019), 141, 3641-3653 link

• 223 | M. Devillard, A. Ehlers, M. A. Siegler, J. I. van der Vlugt
  Selective Carbanion–Pyridine Coordination of a Reactive P,N Ligand to Rh^I
  Chem. Eur. J. (2019), 25, 3875-3883 - link

• 222 | S. Luo, M. A. Siegler, E. Bouwman
  Transition Metal Compounds of Pyridine‐Amide‐Functionalized Carbene Ligands: Synthesis, Structure, and Electrocatalytic Properties in Proton Reduction
  Eur. J. Inorg. Chem. (2019), 2019, 617-627 - link

• 221 | S. S. Saund, S. L. Goldschmid, K. Ng, V. J. Stewart, M. A Siegler, V. S. Thoi
  Exploring Ligand Non-Innocence of Coordinatively-Versatile Diamidodipyrrinato Cobalt Complexes
  Chem. Commun. (2019), 55, 1825-1828 - link

• 220 | T. K. Purkait, E. M. Press, E. A. Marro, M. A. Siegler, R. S. Klausen
  Low-Energy Electronic Transition in SiB Rings
  Organometallics (2019), 38, 1688-1698 - link

• 219 | J‐A. Cuello‐Garibo, C. C. James, M. A. Siegler, S. L. Hopkins, S. Bonnet
  Selective Preparation of a Heteroleptic Cyclometallated Ruthenium Complex Capable of Undergoing Photosubstitution of a Bidentate Ligand
  Chem. Eur. J. (2019), 25, 1260-1268 - link

• 218 | L. N. Lameijer, C. van de Griend, S L. Hopkins, A-G. Volbeda, S. H. C. Askes, M. A. Siegler, S Bonnet
  Photochemical Resolution of a Thermally Inert Cyclometalated Ru(phbpy)(N–N)(Sulfoxide)⁺ Complex
  J. Am. Chem. Soc. (2019), 141, 352-362 - link

• 217 | F. Jiang, M. A. Siegler, E. Bouwman
  Synthesis and characterization of a series of transition metal compounds of thioether and disulfide ligands
  Inorg. Chim. Acta (2019), 486, 135–140 - link

2018

• 216 | F. Jiang, M. A. Siegler, E. Bouwman
  The Reactivity of FeII and CoII Disulfide Compounds with Dihydrogen Peroxide
  Eur. J. Inorg. Chem. (2018), 2018, 4696-4701 - link

• 215 | K. Rajabimoghadam, Y. Darwish, U. Bashir, D. Pitman, S. Eichelberger, M. A. Siegler, M. Swart, I. Garcia-Bosch
  Catalytic Aerobic Oxidation of Alcohols by Copper Complexes Bearing Redox-Active Ligands with Tunable H-Bonding Groups
  J. Am. Chem. Soc. (2018), 140, 16625-16634 - link

• 214 | J. B. Gordon, J. P. McGale, J. R. Prendergast, Z. Shirani-Sarmazeh, M. A. Siegler, G. N. L. Jameson, D. P. Goldberg
  Structures, Spectroscopic Properties, and Dioxygen Reactivity of 5- and 6-Coordinate Nonheme Iron(II) Complexes: A Combined Enzyme/Model Study of Thiol Dioxygenases
  J. Am. Chem. Soc. (2018), 140, 14807–14822 - link

• 213 | F. J. Claire, S. M. Tenney, M. M. Li, M. A. Siegler, J. S. Wagner, A. S. Hall, T. J. Kempa
  Hierarchically Ordered Two-Dimensional Coordination Polymers Assembled from Redox-Active Dimolybdenum Clusters
  J. Am. Chem. Soc. (2018), 140, 10673-10676 - link

• 212 | F. Jiang, M. A. Siegler, X. Sun, L. Jiang, C. Fonseca Guerra, E. Bouwman
  Redox Interconversion between Cobalt(III) Thiolate and Cobalt(II) Disulfide Compounds
  Inorg. Chem. (2018), 57, 8796-8805 - link

• 211 | M. Bhadra, J. Y. C. Lee, R. E. Cowley, S. Kim, M. A. Siegler, E. I. Solomon, K. D. Karlin
  Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes
  J. Am. Chem. Soc. (2018), 140, 9042-9045 - link

• 210 | F. Jiang, M. A.Siegler, E. Bouwman
  A tetranuclear fluorido-bridged iron compound: Fluoride abstraction from the tetrafluoridoborate anion
  Inorg. Chem. Commun. (2018), 94, 53-56 - link

• 209 | R. E. Messersmith, M. A. Siegler, J. D. Tovar
  A Heptacyclic Heptacycle: A Doubly Naphtho[b]thiophene Fused Borepin
  Synlett (2018), , Ahead of Print - link

• 208 | E. A. Marro, E. M. Press, M. A. Siegler, R. S. Klausen
  Directional Building Blocks Determine Linear and Cyclic Silicon Architectures
  J. Am. Chem. Soc. (2018), 140, 5976-5986 - link

• 207 | E. P. Hoffman, V. Riddle, M. A. Siegler, D. Dickerson, M. Backonja, W. G. Kramer, K. Nagaraju, H. Gordish-Dressman, J. M. Damsker, J. M. McCall
  Phase 1 trial of vamorolone, a first-in-class steroid, shows improvements in side effects via biomarkers bridged to clinical outcomes
  Steroids (2018), 134, 43-52 - link

• 206 | J. P. T. Zaragoza, M. A. Siegler, D. P. Goldberg
  A Reactive Manganese(IV)–Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds
  J. Am. Chem. Soc. (2018), 140, 4380-4390 - link

• 205 | T. M. Pangia, C. G. Davies, J. R. Prendergast, J. B. Gordon, M. A. Siegler, G. N. L. Jameson, D. P. Goldberg
  Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex
  J. Am. Chem. Soc. (2018), 140, 4191-4194 - link

• 204 | S. Luo, D. F. Bruggeman, M. A. Siegler, E. Bouwman
  Can pendant pyridyl arm assist the proton delivery in electrocatalysis?
  Chem. Eur. J. (2018), 477, 24-30 - link

• 203 | L. N. Lameijer, T. G. Brevé, V. H. S. van Rixel, Sven H. C. Askes, M. A. Siegler, S. Bonnet
  Effects of the Bidentate Ligand on the Photophysical Properties, Cellular Uptake, and (Photo)cytotoxicity of Glycoconjugates Based on the [Ru(tpy)(NN)(L)]²⁺ Scaffold
  Chem. Eur. J. (2018), , Ahead of Print - link

• 202 | K. G. Kottrup, S. D’Agostini, P. H. van Langevelde, M. A. Siegler, D. G. H. Hetterscheid
  Catalytic Activity of an Iron-Based Water Oxidation Catalyst: Substrate Effects of Graphitic Electrodes
  ACS Catal. (2018), 8, 1052-1061 - link

• 201 | V. H. S. van Rixel, G. F. Moolenaar, M. A Siegler, L. Messori, S. Bonnet
  Controlling with light the interaction between trans tetrapyridyl ruthenium complexes and an oligonucleotide
  Dalton Trans. (2018), 47, 507-516 - link

• 200 | S. Luo, M. A. Siegler, E. Bouwman
  Dinuclear Nickel Complexes of Thiolate-Functionalized Carbene Ligands and Their Electrochemical Properties
  Organometallics (2018), 37, 740-747 - link

2017

• 199 | G. Gezer, D. D. Jiménez, M. A. Siegler, E. Bouwman
  Synthesis and Characterization of Trinuclear [Ni₂Ru] Complexes with Bridging Thiolate or Selenolate Donors for Electrocatalytic Proton Reduction
  Eur. J. Inorg. Chem. (2017), 2017, 5027-5032 - link

• 198 | R. E. Messersmith, S. Yadav, M. A. Siegler, H. Ottosson, J. D. Tovar
  Benzo[b]thiophene Fusion Enhances Local Borepin Aromaticity in Polycyclic Heteroaromatic Compounds
  J. Org. Chem (2017), 82, 13440-13448 - link

• 197 | E. A. Marro, E. M. Press, T. K. Purkait, D. Jimenez, M. A. Siegler, R. S. Klausen
  Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides
  Chem. Eur. J. (2017), 23, 15633-15637 - link

• 196 | L. Guan, M. G. Holl, C. R. Pitts, M. D Struble, M. A. Siegler, T. Lectka
  Through-space Activation can Override Substituent Effects in Electrophilic Aromatic Substitution
  J. Am. Chem. Soc. (2017), 139, 14913-14916 - link

• 195 | G. Gezer, S. Verbeek, M. A Siegler, E. Bouwman
  Nickel-Ruthenium-Based Complexes as Biomimetic Models of [NiFe] and [NiFeSe] Hydrogenases for Dihydrogen Evolution
  Dalton Trans. (2017), 46, 13590-13596 - link

• 194 | J. P. T. Zaragoza, T. H. Yosca, M. A. Siegler, P. Moënne-Loccoz, M. T. Green, D. P. Goldberg
  Direct Observation of Oxygen Rebound with an Iron-Hydroxide Complex
  J. Am. Chem. Soc. (2017), 139, 13640-13643 - link

• 193 | M. Devillard, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
  Transition-Metal-Free Cleavage of CO
  Chem. Eur. J. (2017), 23, 13628-13632 - link

• 192 | D. D. Bume, C. R. Pitts, F. Ghorbani, S. A. Harry, J. N. Capilato, M. A. Siegler, T. Lectka
  Ketones as directing groups in photocatalytic sp³ C–H fluorination Disproportionation
  Chem. Sci. (2017), 8, 6918-6923 link

• 191 | G. B. Wijeratne, S. Hematian, M. A. Siegler, K. D. Karlin
  Copper(I) / NO_(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex – Redox Reversal Giving Copper(I) / NO_(g) Disproportionation
  J. Am. Chem. Soc. (2017), 139, 13276-13279 link

• 190 | H. J. Jang, S. L. Hopkins, M. A. Siegler, Sylvestre Bonnet
  Frontier orbitals of photosubstitutionally active ruthenium complexes: an experimental study of the spectator ligands’ electronic properties influence on photoreactivity
  Dalton Trans. (2017), 46, 9969-9980 - link

• 189 | B. Siewert, M. Langerman, Y. Hontani, J. T. M. Kennis, V. H. S. van Rixel, B. Limburg, M. A. Siegler, V. Talens Saez, R. E. Kieltyka, S. Bonnet
  Turning on the red phosphorescence of a [Ru(tpy)(bpy)(Cl)]Cl complex by amide substitution: self-aggregation, toxicity, and cellular localization of an emissive ruthenium-based amphiphile
  Chem. Commun. (2017), 53, 11126-11129 - link

• 188 | R. Trammell, Y. Y. See, A. T. Herrmann, N. Xie, D. E. Díaz, M A. Siegler, P S. Baran, I. Garcia-Bosch
  Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp³ C–H Bonds
  J. Org. Chem. (2017), 82, 7887-7904 - link

• 187 | G. Gezer, D. Durán Jiménez, M. A. Siegler, Elisabeth Bouwman
  Electrocatalytic proton reduction by a model for [NiFeSe] hydrogenases
  Dalton Trans. (2017), 46, 7506-7514 - link

• 186 | V. Vreeken, L. Baij, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
  N-Atom transfer via thermal or photolytic activation of a Co-azido complex with a PNP pincer ligand
  Dalton Trans. (2017), 46, 7145-7149 - link

• 185 | T. F. van Dijkman, H. M. de Bruijn, T. G. Brevé, B. van Meijeren, M. A. Siegler, E. Bouwman
  Extremely bulky copper(I) complexes of [HB(3,5-{1-naphthyl}2pz)3]– and [HB(3,5-{2-naphthyl}2pz)3]– and their self-assembly on graphene
  Dalton Trans. (2017), 46, 6433-4446 - link

• 184 | J.A. Cuello-Garibo, E. Pérez-Gallent, L. van der Boon, M. A. Siegler, and Sylvestre Bonnet
  Influence of the Steric Bulk and Solvent on the Photoreactivity of Ruthenium Polypyridyl Complexes Coordinated to L-​Proline
  Inorg. Chem (2017), 56, 4818-4828 - link

• 183 | V. Vreeken, M. A. Siegler, J. I. van der Vlugt
  Controlled Interconversion of a Dinuclear Au Species Supported by a Redox-Active Bridging PNP Ligand Facilitates Ligand-to-Gold Electron Transfer
  Chem. Eur. J. (2017), 23, 5585-5594 - link

• 182 | B. Bagh, D. L. J. Broere, V. Sinha, P. F. Kuijpers, N. van Leest, B. de Bruin, S. Demeshko, M. A. Siegler, J. I. van der Vlugt
  Catalytic Synthesis of N-Heterocycles via Direct C(sp3)−H Amination using an Air-stable Iron(III) Species with a Redox-Active Ligand
  J. Am. Chem. Soc. (2017), 139, 5117-5124 - link

• 181 | C. R. Pitts, M. A. Siegler, T. Lectka
  Intermolecular Aliphatic C–F···H–C Interaction in the Presence of “Stronger” Hydrogen Bond Acceptors: Crystallographic, Computational, and IR Studies
  J. Org. Chem. (2017), 82, 3996-4000 - link

• 180 | J. Percino, M. Cerón, P. Venkatesan, P. Ceballos, A. Bañuelos, O. Rodríguez, M. A. Siegler, F. Robles, V. M. Chapela, G. Soriano-Moro, E. Pérez-Gutiérrez, J. Bonilla-Cruz, S. Thamotharan
  Two Different Emissions of (2Z)-2-(4-Bromophenyl)-3-[4-(dimethylamino)phenyl]prop-2-enenitrile Due to Crystal Habit and Size: Synthesis, Optical, and Supramolecular Characterization
  Cryst. Growth Des. (2017), 17, 1679-1694 - link

• 179 | D. R. Levine, R. E. Messersmith, M. A. Siegler, J. D. Tovar
  Ring fusion isomers of dithienoborepins: perturbations of electronic structure, aromaticity, and reactivity in boron-containing polycyclic heteroaromatics
  Can. J. Chem. (2017), 95, 381-389 - link

• 178 | C. R. Pitts, D. D. Bume, S. A. Harry, M. A. Siegler, T. Lectka
  Multiple Enone-Directed Reactivity Modes Lead to the Selective Photochemical Fluorination of Polycyclic Terpenoid Derivatives
  J. Am. Chem. Soc. (2017), 139, 2208-2211 - link

• 177 | E. E. Joslin, J. P. T. Zaragoza , M. A. Siegler, D. P. Goldberg
  meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine
  Chem. Commun. (2017), 53, 1961-1964 - link

• 176 | S. M. Adam, I. Garcia-Bosch, A. W. Schaefer, S. K. Sharma, M. A. Siegler, E. I. Solomon, K. D. Karlin
  Critical Aspects of Heme-​Peroxo-​Cu Complex Structure and Nature of Proton Source Dictate Metal-​Operoxo Breakage versus Reductive O-​O Cleavage Chemistry
  J. Am. Chem. Soc. (2017), 139, 472-481 - link

• 175 | E. M. Press, E. A. Marro, S. K. Surampudi, M. A. Siegler, J. A. Tang, R. S. Klausen
  Synthesis of a Fragment of Crystalline Silicon: Poly(Cyclosilane)
  Angew. Chem. Int. Ed. (2017), 56, 568-572 - link

2016

• 174 | X. Liu, M. A. Siegler, M. Hilbers, E. Bouwman
  Synthesis, structure and photoluminescence properties of lanthanoid coordination polymers based on tetra(3,5-dicarboxyphenoxymethyl)methane
  Polyhedron (2016), 123, 1-8 - link

• 173 | S. Sahu, B. Zhang, C. J. Pollock, M. Dürr, C. G. Davies, A. M. Confer, I. Ivanović-Burmazović, M. A. Siegler, G. N. L. Jameson, C. Krebs, D. P. Goldberg
  Aromatic C–F Hydroxylation by Nonheme Iron(IV)–Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations
  J. Am. Chem. Soc. (2016), 138, 12791-12802 - link

• 172 | M. J. Percino, M. Cerón, O. Rodríguez, G Soriano-Moro, M. E. Castro, V. M. Chapela, M. A. Siegler, E. Pérez-Gutiérrez
  Conformational and molecular structures of α,​β-​unsaturated acrylonitrile derivatives: photophysical properties and their frontier orbitals
  Molecules (2016), 21, 389/1-389/19 - link

• 171 | I. Garcia-Bosch, M. A. Siegler
  Copper-​Catalyzed Oxidation of Alkanes with H₂O₂ under a Fenton-​like Regime
  Angew. Chem. Int. Ed. (2016), 55, 12873-12876 - link

• 170 | S. Luo, M. A. Siegler, E. Bouwman
  Nickel Complexes of Pyridine-​Functionalized N-​Heterocyclic Carbenes: Syntheses, Structures, and Activity in Electrocatalytic Hydrogen Production
  Eur. J. Inorg. Chem. (2016), 2016, 4693-4700 - link

• 169 | J. Percino, M. Cerón, P. Ceballos, G. Soriano-Moro, O. Rodríguez, V. M. Chapela, M. E. Castro, J. Bonilla-Cruz, Maxime A. Siegler
  Changes in the luminescence emission of α,β-unsaturated acrylonitrile derivatives: morphology, polymorphism and solvent effect
  CrystEngComm (2016), 18, 7554-7572 - link

• 168 | D. L. J. Broere, R. Plessius, J. Tory, S. Demeshko, B. de Bruin, M. A. Siegler, F. Hartl, J. I. van der Vlugt
  Localized Mixed-Valence and Redox Activity within a Triazole-Bridged Dinucleating Ligand upon Coordination to Palladium
  Chem. Eur. J. (2016), 22, 13965-13975 - link

• 167 | D. L. J. Broere, N. P. van Leest, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
  Reversible Redox Chemistry and Catalytic C(sp³)–H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand
  Inorg. Chem. (2016), 55, 8603-8611 - link

• 166 | E. E. Joslin, J. P. T. Zaragoza, R. A. Baglia, M. A. Siegler, D. P. Goldberg
  The Influence of Peripheral Substituent Modification on P^V, Mn^III, and Mn^V(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities
  Inorg. Chem. (2016), 55, 8646-8660 - link

• 165 | M. D. Struble, L. Guan, M. A. Siegler, T. Lectka
  A C–F Bond Directed Diels–Alder Reaction
  J. Org. Chem. (2016), 81, 8087-8090 - link

• 164 | L. S. Jongbloed, D. García-López, R. van Heck, M. A. Siegler, J. J. Carbó, J. I. van der Vlugt
  Arene C(sp²)-H Metalation at Ni^II Modeled with a Reactive PONC_Ph Ligand
  Inorg. Chem. Int. Ed. (2016), 55, 8041-8047 - link

• 163 | V. Vreeken,D. L. J. Broere, A. C. H. Jans, M. Lankelma, J. N. H. Reek, M. A. Siegler, J. I. van der Vlugt
  Well-Defined Dinuclear Gold Complexes for Preorganization-Induced Selective Dual Gold Catalysis
  Angew. Chem. Int. Ed. (2016), 55, 10042-10046 - link

• 162 | S. K. Sharma, H. Kim, P. J. Rogler, M. A. Siegler, K. D. Karlin
  Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization
  J. Biol. Inorg. Chem. (2016), 21, 729-743 - link

• 161 | M. G. Holl, M. D. Struble, M. A. Siegler, T. Lectka
  The close interaction of a C-F bond with a carbonyl π–system: Attractive, repulsive, or both?
  J. Fluorine Chem. (2016), 188, 126-130 - link

• 160 | B. Siewert, V. H. S. van Rixel, E. J. van Rooden, S. L. Hopkins, M. J. B. Moester, F. Ariese, M. A. Siegler, S. Bonnet
  Chemical Swarming: Depending on Concentration, an Amphiphilic Ruthenium Polypyridyl Complex Induces Cell Death via Two Different Mechanisms
  Chem. Eur. J. (2016), 22, 10960-10968 - link

• 159 | R. C. Conyers, J. R. Mazzone, M. A. Siegler, G. H. Posner
  Highly regiocontrolled and stereocontrolled syntheses of polysubstituted aminocyclohexanes: mild inverse-electron-demand Diels–Alder cycloadditions of electrophilic 2-pyridones
  Tetrahedron Lett. (2016), 57, 3344-3348 - link

• 158 | B. Bagh, D. L. J. Broere, M. A. Siegler, J. I. van der Vlugt
  Redox-Active-Ligand-Mediated Formation of an Acyclic Trinuclear Ruthenium Complex with Bridging Nitrido Ligands
  Angew. Chem. Int. Ed. (2016), 55, 8381-8385 - link

• 157 | B. N. DiMarco, T. C. Motley, R. S. Balok, G. Li, M. A. Siegler, R. M O'Donnell, K. Hu, G. J. Meyer
  A Distance Dependence to Lateral Self-Exchange Across Nanocrystalline TiO₂. A Comparative Study of Three Homologous RuIII/II Polypyridyl Compounds
  J. Phys. Chem. C,. (2016), 120, 14226-14235 - link

• 156 | R. E. Messersmith, M. A. Siegler, J. D. Tovar
  Aromaticity Competition in Differentially Fused Borepin-Containing Polycyclic Aromatics
  J. Org. Chem. (2016), 81, 5595-5605 - link

• 155 | R. Cao, C. Saracini, J. W. Ginsbach, M. T. Kieber-Emmons, M. A. Siegler, E. I. Solomon, S. Fukuzumi, K. D. Karlin
  RPeroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy
  J. Am. Chem. Soc. (2016), 138, 7055-7066 - link

• 154 | X. Liu, M. A. Siegler, E. Bouwman
  Ratiometric Thermometer Based on a Lanthanoid Coordination Polymer
  Eur. J. Inorg. Chem. (2016), 2016, 2984-2988 - link

• 153 | M. G. Holl, M. D. Struble, P. Singal, M. A. Siegler, T. Lectka
  Positioning a Carbon–Fluorine Bond over the π Cloud of an Aromatic Ring: A Different Type of Arene Activation
  Angew. Chem. Int. Ed. (2016), 55, 8266-8269 - link

• 152 | V. H. S. van Rixel, B. Siewert, S. L. H. Hopkins, S. H.C. Askes, A. Busemann, M. A. Siegler, S. Bonnet
  Green light-induced apoptosis in cancer cells by a tetrapyridyl ruthenium prodrug offering two trans coordination sites
  Chem. Sci. (2016), 7, 4922-4929 - link

• 151 | J. Jung, H. M. Neu, P. Leeladee, M. A. Siegler, K. Ohkubo, D. P. Goldberg, S. Fukuzumi
  Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine
  Inorg. Chem. (2016), 55, 3218-3228 - link

• 150 | T. F. van Dijkman, M. A. Siegler, E. Bouwman
  Copper(I) Complexes of Naphthyl-Substituted Fluorinated Trispyr­azolylborate Ligands with Ethene and Carbon Monoxide
  Eur. J. Inorg. Chem. (2016), 2016, 2586-2594 - link

• 149 | I. Garcia-Bosch, R. E. Cowley, D. E. Díaz, M A. Siegler, W. Nam, E. I. Solomon, K. D. Karlin
  Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu₂O₂ Core with Unexpected Structure and Reactivity
  Chem. Eur. J. (2016), 22, 5133-5137 - link

• 148 | A. C. McQuilken, H. Matsumura, M. Dürr, A. M. Confer, J/ P. Sheckelton, M. A. Siegler, T. M. McQueen, I. Ivanović-Burmazović, P. Moënne-Loccoz, D. P. Goldberg
  Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}⁷ Complex with Dioxygen
  J. Am. Chem. Soc. (2016), 138, 3107–3117 - link

• 147 | H. L. van de Wouw, J. Y. Lee, M. A. Siegler, R. S. Klausen
  Innocent BN bond substitution in anthracene derivatives
  Org. Biomol. Chem. (2016), 14, 3256-3263 - link

• 146 | W. A. Phelan, S. M. Koohpayeh, P. Cottingham, J. A. Tutmaher, J. C. Leiner, M. D. Lumsden, C. M. Lavelle, X. P. Wang, C. Hoffmann, M. A. Siegler, N. Haldolaarachchige, D. P. Young, T. M. McQueen
  On the Chemistry and Physical Properties of Flux and Floating Zone Grown SmB₆ Single Crystals
  Sci. Rep. (2016), 6, 20860 - link

• 145 | D. L. J. Broere, D. K. Modde, E. Blokker, M. A. Siegler, J. I. van der Vlugt
  Metal–Metal Interactions in Heterobimetallic Complexes with Dinucleating Redox-Active Ligands
  Angew. Chem. Int. Ed. (2016), 55, 2406-2410 link

• 144 | W.D. Kerber, J. T. Goheen, K. A. Perez, M. A. Siegler
  Enhanced Stability of the Fe^II/Mn^II State in a Synthetic Model of Heterobimetallic Cofactor Assembly
  Inorg. Chem. (2016), 55, 848–857 - link

• 143 | S. Zheng, N. R. M. Reintjens, M. A. Siegler, O. Roubeau, E. Bouwman, A. Rudavskyi, R. W. A. Havenith, S Bonnet
  Stabilization of the Low-Spin State in a Mononuclear Iron(II) Complex and High-Temperature Cooperative Spin Crossover Mediated by Hydrogen Bonding
  Chem. Eur. J. (2016), 22, 331-339 - link

• 142 | J. P. T. Zaragoza, M. A. Siegler, D. P. Goldberg
  Rhenium(V)–oxo corrolazines: isolating redox-active ligand reactivity
  Chem. Commun. (2016), 52, 167-170 - link

2015

• 141 | T. F. van Dijkman, M. A. Siegler, E. Bouwman
  Highly tunable fluorinated trispyrazolylborates [HB(3-CF₃-5-{4-RPh}pz)₃]– (R = NO2, CF3, Cl, F, H, OMe and NMe₂) and their copper(I) complexes
  Dalton Trans. (2015), 44, 21109-21123 - link

• 140 | A. E. Pascui, K. van Rees, D. W. Zant, D. L. J. Broere, M. A. Siegler, J. I. van der Vlugt
  Macrocyclic Platinum(II) Complexes with a Bifunctional Diphosphine Ligand
  Eur. J. Inorg. Chem. (2015), 34, 5687-5693 - link

• 139 | T. F. van Dijkman, H. M. de Bruijn, M. A. Siegler, E. Bouwman
  Bright Cyan Phosphorescence of a (Phosphane)copper(I) Complex of the Tri­hydrido­pyrazolylborate Ligand H₃B(3,5-Ph₂Pz)^–
  Eur. J. Inorg. Chem. (2015), 2015, 5387-5394 - link

• 138 | R. A. Baglia, K. A. Prokop-Prigge, H. M. Neu, M. A. Siegler, D. P. Goldberg
  Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction
  J. Am. Chem. Soc. (2015), 137, 10874-10877 - link

• 137 | M. D. Struble, M. Gargiulo Holl, M. T. Scerba, M. A. Siegler, T. Lectka
  Search for a Symmetrical C-F-C Fluoronium Ion in Solution: Kinetic Isotope Effects, Synthetic Labeling, Computational, Solvent and Rate Studies
  J. Am. Chem. Soc. (2015), 137, 11476-11490 - link

• 136 | S. Hematian, I. Kenkel, T. E. Shubina, M. Dürr, J. J. Liu, M. A. Siegler, I. Ivanovic-Burmazovic, K. D. Karlin
  Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO_(g) to Nitrite Conversion Utilizing μ-oxo Heme-Fe^III–O–Cu^II(L) Constructs
  J. Am. Chem. Soc. (2015), 137, 6602-6615 - link

• 135 | J. P. T. Zaragoza, R. A. Baglia, M. A. Siegler, D. P. Goldberg
  Strong Inhibition of O-Atom Transfer Reactivity for Mn^IV(O)(π-Radical-Cation)(Lewis Acid) versus Mn^V(O) Porphyrinoid Complexes
  J. Am. Chem. Soc. (2015), 137, 6531-6540 - link

• 134 | V. Vreeken, M. A. Siegler, B. de Bruin, J. N. H. Reek, M. Lutz, J. I. van der Vlugt
  C-H Activation of Benzene by a Photoactivated Ni^II(azide): Formation of a Transient Nickel Nitrido Complex
  Angew. Chem. Int. Ed. (2015), 54, 7055-7059 - link

• 133 | E.C.M. Ording-Wenker, M. A. Siegler, M. Lutz, E. Bouwman
  Catalytic Catechol Oxidation by Copper Complexes: Development of a Structure-Activity Relationship
  Dalton Trans. (2015), 44, 12196-12209 - link

• 132 | H. M. Neu, J. Jung, R. A. Baglia, M. A. Siegler, K. Ohkubo, S. Fukuzumi, D. P. Goldberg
  Light-Driven, Proton-Controlled, Catalytic Aerobic C–H Oxidation Mediated by a Mn(III) Porphyrinoid Complex
  J. Am. Chem. Soc (2015), 137, 4614-4617 - link

• 131 | M. D. Struble, M. G. Holl, G. Coombs, M. A. Siegler, T. Lectka
  Synthesis of a Tight Intramolecular OH---Olefin Interaction, Probed by IR, 1H NMR and Quantum Chemistry
  J. Org. Chem. (2015), 80, 4803-4807 - link

• 130 | P. Kumar, Y-M. Lee, Y J. Park, M. A. Siegler, K. D. Karlin, W. Nam
  Reactions of Co(III)–Nitrosyl Complexes with Superoxide and Their Mechanistic Insights
  J. Am. Chem. Soc (2015), 137, 4284-4287 - link

• 129 | D. L. J. Broere, S. Demeshko, B. de Bruin, E. A. Pidko, J. N. H. Reek, M. A. Siegler, M. Lutz, J. I. van der Vlugt
  Dinuclear Palladium Complexes with Two Ligand-CenteredRadicals and a Single Bridging Ligand: Subtle Tuning of MagneticProperties
  Chem. Eur. J. (2015), 21, 5879-5886 - link

• 128 | X. Guo, J. Zhou, M. A. Siegler, A. E. Bragg, H. E. Katz
  Visible-Light-Triggered Molecular Photoswitch Based on Reversible E/Z Isomerization of a 1,2-Dicyanoethene Derivative
  Angew. Chem. Int. Ed. (2015), 54, 4782-4786 - link

• 127 | S. Kim, J. W. Ginsbach, J. Yoon Lee, R. L. Peterson, J. J. Liu, M. A. Siegler, A. A. Sarjeant, E. I. Solomon, K. D. Karlin
  Amine Oxidative N-Dealkylation via Cupric Hydroperoxide Cu-OOH Homolytic Cleavage Followed by Site-Specific Fenton Chemistry
  J. Am. Chem. Soc. (2015), 137, 2867-2874 - link

• 126 | S. Kim, J. Yoon Lee, R. E. Cowley, J. W. Ginsbach, M. A. Siegler, E. I. Solomon, K. D. Karlin
  A N3S_(thioether)-Ligated Cu^II-Superoxo with Enhanced Reactivity
  J. Am. Chem. Soc. (2015), 137, 2796-2799 - link

• 125 | E. C.M. Ording-Wenker, M. A. Siegler, E. Bouwman
  Coordination of new disulfide ligands to Cu^I and Cu^II: Does a Cu^IIμ-thiolate complex form?
  Inorg. Chim. Acta (2015), 428, 193-202 - link

• 124 | S. Kakuda, C. Rolle, K. Ohkubo, M. A. Siegler, K. D. Karlin , S. Fukuzumi
  Lewis Acid-Induced Change from Four- to Two-Electron Reduction of Dioxygen Catalyzed by Copper Complexes Using Scandium Triflate
  J. Am. Chem. Soc. (2015), 137, 3330-3337 - link

• 123 | S. Long, P. Zhou, K. L Theiss, M. A Siegler and T. Li
  Solid-State Identity of 2-Hydroxynicotinic Acid and Its Polymorphism
  CrystEngComm (2015), 17, 5195-5205 - link

• 122 | S. Surampudi, M.-L. Yeh, M. A. Siegler, J. F. Martinez Hardigree, T. A. Kasl, H. E. Katz, R.S. Klausen
  Increased Carrier Mobility in End-Functionalized Oligosilanes
  Chem. Sci. (2015), 6, 1905-1909 - link

• 121 | A. M. Fry, O. T. Sweeney, W. A. Phelan, N. Drichko, M A. Siegler, T. M. McQueen
  Unique edge-sharing sulfate-transition metal coordination in Na₂M(SO₄)₂ (M=Ni and Co)
  J. Solid State Chem. (2015), 222, 129-135 - link

• 120 | D. L. J. Broere, L. L. Metz, B. de Bruin, J. N. H. Reek, M. A. Siegler, J. I. van der Vlugt
  Redox-Active Ligand-Induced Homolytic Bond Activation
  Angew. Chem. Int. Ed. (2015), 54, 1516-1520 - link

2014

• 119 | S. Hong, K. D. Sutherlin, J. Park, E. Kwon, M. A. Siegler, E. I. Solomon, W. Nam
  Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex
  Nat. Commun. (2014), 5:5440, link

• 118 | A. Khrimian, S. Shirali, K. E. Vermillion, M. A. Siegler, F. Guzman, K. Chauhan, J. R. Aldrich, D. C. Weber
  Determination of the Stereochemistry of the Aggregation Pheromone of Harlequin Bug, Murgantia histrionica
  J. Chem. Ecol. (2014), 40, 1260-1268 - link

• 117 | S. Zheng, M. A. Siegler, O. Roubeau, S. Bonnet
  Influence of Selenocyanate Ligands on the Transition Temperature and Cooperativity of bapbpy-Based Fe(II) Spin-Crossover Compounds
  Inorg. Chem. (2014), 53, 13162-13173 - link

• 116 | E. C. M. Ording-Wenker, M. van der Plas, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
  Protonation of a Biologically Relevant Cu^II μ-Thiolate Complex: Ligand Dissociation or Formation of a Protonated Cu^I Disulfide Species?
  Chem. Eur. J. (2014), 51, 16913-16921 - link

• 115 | W. D. Kerber, K. A. Perez, C. Ren, M. A. Siegler
  Speciation of Ferric Phenoxide Intermediates during the Reduction of Iron(III)−μ-Oxo Dimers by Hydroquinone
  Inorg. Chem. (2014), 53, 11507-11516 - link

• 114 | S. Sahu, M. G. Quesne, C. G. Davies, M. Dürr, I. Ivanović-Burmazović, M. A. Siegler, G. N. L. Jameson, S. P. de Visser, D. P. Goldberg
  Direct Observation of a Nonheme Iron(IV)−Oxo Complex That Mediates Aromatic C−F Hydroxylation
  J. Am. Chem. Soc. (2014), 136, 13542-13545 - link

• 113 | E. C.M. Ording-Wenker, M. van der Plas, M. A. Siegler, S. Bonnet, F. M. Bickelhaupt, C. Fonseca Guerra, E. Bouwman
  Thermodynamics of the Cu^II μ-Thiolate and Cu^I Disulfide Equilibrium: A Combined Experimental and Theoretical Study
  Inorg. Chem. (2014), 53, 8494-8504 - link

• 112 | M. D. Struble, C. Kelly, M. A. Siegler, T. Lectka
  Search for a Strong, Virtually “No-Shift” Hydrogen Bond: A Cage Molecule with an Exceptional OH^...F Interaction
  Angew. Chem. Int. Ed. (2014), 53, 8924-8928 - link

• 111 | A. Khrimian, A. Zhang, D. C. Weber, H-Y. Ho, J. R. Aldrich, K. E. Vermillion, M. A. Siegler, S. Shirali, F. Guzman, T. C. Leskey
  Discovery of the Aggregation Pheromone of the Brown Marmorated Stink Bug (Halyomorpha halys) through the Creation of Stereoisomeric Libraries of 1-Bisabolen-3-ols
  J. Nat. Prod. (2014), 77, 1708-1717 - link

• 110 | C. R. Pitts, S. Bloom, R. Woltornist, D. Auvenshine, L. R. Ryzhkov, M. A. Siegler, T. Lectka
  Direct, Catalytic Monofluorination of sp3 C H Bonds: A Radical-Based Mechanism with Ionic Selectivity
  J. Am. Chem. Soc. (2014), 136, 9780-9791 - link

• 109 | M. J. Percino, M. Cerón, P. Ceballos, G. Soriano-Moro, M. E. Castro, V. M. Chapela, J. Bonilla-Cruz, M. Reyes-Reyes, R. López-Sandoval, M. A. Siegler
  Important role of molecular packing and intermolecular interactions in two polymorphs of (Z)-2-phenyl-3-(4-(pyridin-2-yl)phenyl)acrylonitrile. Preparation, structures, and optical properties
  J. Mol. Struct. (2014), 1078, 74-82 - link

• 108 | S. Kim, J. W. Ginsbach, A. I. Billah, M. A. Siegler, C. D. Moore, E. I. Solomon, K. D. Karlin
  Tuning of the Copper-Thioether Bond in Tetradentate N₃S_(thioether) Ligands; O-O Bond Reductive Cleavage via a [Cu^II₂(µ-1,2-peroxo)]²⁺/[Cu^III₂(µ-oxo)₂]²⁺ Equilibrium
  J. Am. Chem. Soc. (2014), 136, 8063-8071 - link

• 107 | L. R. Widger, Y. Jiang, A. C. McQuilken, T. Yang, M. A. Siegler, H. Matsumura, P. Moenne-Loccoz, S. P. de Visser, D. P. Goldberg
  Thioether-ligated iron(II) and iron(III)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere
  Dalton Trans. (2014), 43, 7522-7532 - link

• 106 | D. R. Levine, M. A. Siegler, J. D. Tovar
  Thiophene-fused borepins as directly functionalizable boron-containing p-electron systems
  J. Am. Chem. Soc. (2014), 136, 7132–7139 - link

• 105 | A. Talanov, W. A. Phelan, Z. A. Kelly, M. A. Siegler, T. M. McQueen
  Control of the Iridium Oxidation State in the Hollandite Iridate Solid Solution K_1-xIr₄O₈
  Inorg. Chem. (2014), 53, 4500-4507 - link

• 104 | S. Kim, M. A. Siegler, K. D. Karlin
  Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction
  Chem. Commun. (2014), 50, 2844-2846 - link

• 103 | R. C. Conyers, J. R. Mazzone, M. A. Siegler, A. K. Tripathi, D. J. Sullivan, B. T. Mott, G. H. Posner
  The survival times of malaria-infected mice are prolonged more by several new two-carbon-linked artemisinin-derived dimer carbamates than by the trioxane antimalarial drug artemether
  Bioorg. Med. Chem. Lett. (2014), 24, 1285-1289 - link

• 102 | L. R. Widger, C. G. Davies, T. Yang, M. A. Siegler, O. Troeppner, G. N. L. Jameson, I. Ivanovic-Burmazovic, D. P. Goldberg
  Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres
  J. Am. Chem. Soc. (2014), 136, 2699-2702 - link

• 101 | S. Hematian, M. A. Siegler, K. D. Karlin
  Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity
  J. Biol. Inorg. Chem. (2014), 19, 515-528 - link

• 100 | A. Garza-Ortiz, P. U. Maheswari, M. Lutz, M. A. Siegler, J. Reedijk
  Tuning the cytotoxic properties of new ruthenium(III) and ruthenium(II) complexes with a modified bis(arylimino)pyridine Schiff base ligand using bidentate pyridine-based ligands
  J. Biol. Inorg. Chem. (2014), 19, 675-689 - link

• 99 | S. Akerboom, M. S. Meijer, M. A. Siegler, W. T. Fu, E. Bouwman
  Structure, photo- and triboluminescence of the lanthanoid dibenzoylmethanates: HNEt₃[Ln(dbm)₄]
  J. Lumin. (2014), 145, 278-282 - link

• 98 | M. D. Struble, J. Strull, K. Patel, M. A. Siegler, T. Lectka
  Modulating 'Jousting' C-F---H-C interactions with a Bit of Hydrogen Bonding
  J. Org. Chem. (2014), 79, 1-6 - link

2013

• 97 | S. Akerboom, Jos J. M. H. van den Elshout, I. Mutikainen, M. A. Siegler, W. T. Fu, E. Bouwman
  Substituted Phenanthrolines as Antennae in Luminescent Eu^III Complexes
  Eur. J. Inorg. Chem. (2013), 2013, 6137-6146- link

• 96 | E. C. M. Ording-Wenker, M. A. Siegler, M. Lutz, E. Bouwman
  Cu^I Thiolate Reactivity with Dioxygen: The Formation of Cu^II Sulfinate and Cu^II Sulfonate Species via a Cu^II Thiolate Intermediate
  Inorg. Chem. (2013), 52, 13113-13122 - link

• 95 | R. L. Peterson, J. W. Ginsbach, R. E. Cowley, M. F. Qayyum, R. A. Himes, M. A. Siegler, C. D. Moore, B. Hedman, K. O. Hodgson, S. Fukuzumi, E. L. Solomon, K. D. Karlin
  Stepwise Protonation and Electron-Transfer Reduction of a Primary Copper-Dioxygen Adduct
  J. Am. Chem. Soc. (2013), 135, 16454-16467 - link

• 94 | A. Garza-Ortiz, P. Uma Maheswari, M. Siegler, A. L. Spek, J. Reedijk
  A new family of Ru(II) complexes with a tridentate pyridine Schiff-base ligand and bidentate co-ligands: synthesis, characterization, structure and in vitro cytotoxicity studies
  New J. Chem. (2013), 37, 3450-3460 - link

• 93 | R. D. Slack, M. A. Siegler, G. H. Posner
  Highly stereocontrolled and regiocontrolled syntheses of polyoxygenated [2.2.2]oxabicyclic synthons
  Tetrahedron Letters (2013), 54, 6267-6270 - link

• 92 | A. C. McQuilken, Y. Ha, K. D. Sutherlin, M. A. Siegler, K. O. Hodgson, B. Hedman, E. I. Solomon, G. N. L. Jameson, D. P. Goldberg
  Preparation of Non-heme {FeNO}⁷ Models of Cysteine Dioxygenase: Sulfur versus Nitrogen Ligation and Photorelease of Nitric Oxide
  J. Am. Chem. Soc. (2013), 135, 14024–14027 - link

• 91 | L. R. Widger, Y. Jiang, M. A. Siegler, D. Kumar, R. Latifi, S. P. de Visser, G. N. L. Jameson, D. P. Goldberg
  Synthesis and Ligand Non-Innocence of Thiolate-Ligated (N4S) Iron(II) and Nickel(II) Bis(imino)pyridine Complexes
  Inorg. Chem. (2013), 52, 10467-10480 - link

• 90 | W. Ward, B. H. Farnum, M. A. Siegler, G. J. Meyer
  Chloride Ion-Pairing with Ru(II) Polypyridyl Compounds in Dichloromethane
  J. Phys. Chem. A (2013), 117, 8883-8894 - link

• 89 | A. Bahreman, B. Limburg, M. A. Siegler, E. Bouwman, S. Bonnet
  Spontaneous Formation in the Dark, and Visible Light-Induced Cleavage, of a Ru-S Bond in Water: A Thermodynamic and Kinetic Study
  Inorg. Chem. (2013), 52, 9456-9469 - link

• 88 | S. Oldenhof, B. de Bruin, M. Lutz, M. A. Siegler, F. Patureau, J. I. van der Vlugt, J. N. H. Reek
  Base-Free Production of H₂ by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex
  Chem. Eur. J. (2013), 19, 11507-11511 - link

• 87 | S. Sahu, L. R. Widger, M. G. Quesne, S. P. de Visser, H. Matsumura, P. Moenne-Loccoz, M. A. Siegler, D. P. Goldberg
  Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach
  J. Am. Chem. Soc. (2013), 135, 10590-10593 - link

• 86 | M. D. Struble, M. T. Scerba, M. Siegler, T. Lectka
  Evidence for a Symmetrical Fluoronium Ion in Solution
  Science (2013), 340, 57-60 - link

• 85 | P. Leeladee, G. N. L. Jameson, M. A. Siegler, D. Kumar, Sam P. de Visser, D. P. Goldberg
  Generation of a High-Valent Iron Imido Corrolazine Complex and NR Group Transfer Reactivity
  Inorg. Chem. (2013), 52, 4668-4682 - link

• 84 | L. R. Widger, M. A. Siegler, D. P. Goldberg
  Sulfide oxidation by O₂: Synthesis, structure and reactivity of novel sulfide-incorporated Fe(II) bis(imino)pyridine complexes
  Polyhedron (2013), 58, 179-189 - link

• 83 | B. T. Mott, A. Tripathi, M. A. Siegler, C. D. Moore, D. J. Sullivan, G. H. Posner
  Synthesis and Antimalarial Efficacy of Two-Carbon-Linked, Artemisinin-Derived Trioxane Dimers in Combination with Known Antimalarial Drugs
  J. Med. Chem, (2013), 56, 2630-2641 - link

• 82 | S. Zheng, M. A. Siegler, J. C. Sanchez , W-T. Fu, S. Bonnet
  Effect of Metal Dilution on the Thermal Spin Transition of [Fe_xZn_1-x(bapbpy)(NCS)₂]
  Eur. J. Inorg. Chem. (2013), 5-6, 1033-1042 - link

2012

• 81 | S. Kim, C. Saracini, M. A. Siegler, N. Drichko, K. D. Karlin
  Coordination Chemistry and Reactivity of a Cupric Hydroperoxide Species Featuring a Proximal H-Bonding Substituent
  Inorg. Chem. (2012), 51, 12603-12605. Link


• 80 | S. Hematian, M. A. Siegler, K. D. Karlin
  Heme/Copper Assembly Mediated Nitrite and Nitric Oxide Interconversion
  J. Am. Chem. Soc. (2012), 134, 18912-18915. Link


• 79 | A. Yokoyama, J. E. Han, J. Cho, M. Kubo, T. Ogura, M. A. Siegler, K. D. Karlin, W. Nam
  Chromium(IV)-Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity
  J. Am. Chem. Soc. (2012), 134, 15269-15272. Link


• 78 | M. A. Siegler, S. Parkin, C. P. Brock
  [Ni(MeCN)(H₂O)₂(NO₃)₂]^.(15-crown-5)^.MeCN: detailed study of a four-phase sequence that includes an intermediate modulated phase
  Acta Cryst. B (2012), 68, 389-400. Link


• 77 | A. Bahreman, B. Limburg, M. A. Siegler, R. Koning, A. J. Koster, S. Bonnet
  Ruthenium Polypyridyl Complexes Hopping at Anionic Lipid Bilayers through a Supremolecular Bond Sensitive to Visible Light
  Chem. Eur. J. (2012), 18, 10271-10280. Link


• 76 | R. A. Ghiladi, A. L. Rheingold, M. A. Siegler, K. D. Karlin
  Synthesis and characterization of new trinuclear copper complexes
  Inorg. Chim. Acta (2012), 389, 131-137. Link


• 75 | D. R. Levine, A. Caruso, M. A. Siegler, J. D. Tovar
  Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings
  Chem. Commun. (2012), 48, 6256-6258. Link


• 74 | A. C. McQuilken, Y. Jiang, M. A. Siegler and D. P. Goldberg
  Addition of Dioxygen to an N₄S(thiolate) Iron(II) Cysteine Dioxygenase Model Gives a Structurally Characterized Sulfinato-Iron(II) Complex
  J. Am. Chem. Soc. (2012), 134, 8758-8761. Link


• 73 | W. B. Heuer, H-L. Xia, W. Ward, Z. Zhou, W. H. Pearson, M. A. Siegler, A. A. Narducci Sarjeant, M. Abrahamsson, G. J. Meyer
  New Dicarboxylic Acid Bipyridine Ligand for Ruthenium Polypyridyl Sensitization of TiO₂
  Inorg. Chem. (2012), 51, 3981-3988. Link


• 72 | Y. M. Badiei, Y. Jiang, L. R. Widger, M. A. Siegler, D. P. Goldberg
  Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: Unexpected transmetalation mediated by LiAlH₄
  Inorg. Chim. Acta (2012), 382, 19-26. Link


• 71 | F. W. Patureau, C. Worch, M. A. Siegler, A. L. Spek, C. Bolm, J. N. H. Reek
  SIAPhos: Phosphorylated Sulfonimidamides and their Use in Iridium-Catalized Aymmetric Hydrogenations of Sterically Hindered Cyclic Enamides
  Adv. Synth. Catal. (2012), 354, 59-64. Link


• 70 | M. Scerba, S. Bloom, N. Haselton, M. Siegler, J. Jake, T. Lectka
  Interaction of a C-F Bond with the pi-System of a C=C Bond or "Head On" with a Proximate C-H Bond
  J. Org. Chem. (2012), 77, 1605-1609. Link


• 69 | D. Guthrie, N. Kim, M. Siegler, C. Moore, J. Toscano
  Development of N-Substitued Hydroxylamines as Efficient Nitroxyl (HNO) Donors
  J. Am. Chem. Soc. (2012), 134, 1962-1965. Link


• 68 | F. W. Patureau, M. A. Siegler, A. L. Spek, A. J. Sandee, S. Juge, S. Aziz, A. Berkessel, J. N. H. Reek
  Supramolecular Hydrogen-Bonding Tautomeric Sulfonamido-Phosphinamides: A Perfect P-Chirogenic Memory
  Eur. J. Inorg. Chem. (2012), 3, 496-503. Link

2011

• 67 | Z. Arcis-Castíllo, S. Zheng, M. A. Siegler, O. Roubeau, S. Bedoui and S. Bonnet
  Tuning the Transition Temperature and Cooperativity of bapbpy-Based Mononuclear Spin-Crossover Compounds: Interplay between Molecular and Crystal Engineering
  Chem. Eur. J. (2011), 17, 14826-14836. Link


• 66 | M. A. Siegler, X. Hao, S. Parkin, C. P. Brock
  [Ni(H₂O)₆](NO₃)₂^.(15-crown-5)^.2H₂O: three phase transitions and an intermediate modulated phase stable over a range of ca. 40 K
  Acta Cryst. B (2011), 67, 486-498. Link


• 65 | N. J. M. Pijnenburg, M. Lutz, M. A. Siegler, A. Spek, G. van Koten, R. J. M. Klein Gebbink
  The role of the dendritic support in the catalytic performance of peripheral pincer Pd-complexes
  New J. Chem. (2011), 35, 2356-2365. Link


• 64 | M. T. Scerba, C. M. Leavitt, M. E. Diener, A. F. DeBlase, T. L. Guasco, M. A. Siegler, N. Bair, M. A. Johnson, T. Lectka
  NH⁺-F Hydrogen Bonding in a Fluorinated "Proton Sponge" Derivative: Integration of Solution, Solid-State, Gas-Phase, and Computational Studies
  J. Org. Chem. (2011), 76, 7975-7984. Link


• 63 | R. E. Goldbach, I. Rodriguez-Garcia, J. H. van Lenthe, M. A. Siegler, S. Bonnet
  N-Acetylmethionine and Biotin as Photocleavable Protective Groups for Ruthenium Polypyridyl Complexes
  Chem. Eur. J. (2011), 17, 9924-9929. Link


• 62 | C. P. Hencken, D. T. Genna, M. A. Siegler, G. H. Posner
  Highly Stereocontrolled and Regiocontrolled Syntheses of 2,3,4-Trisubstituted Alkanoates and Lactones
  J. Org. Chem. (2011), 76, 5149-5155. Link


• 61 | M. Hojahmat, G. Zheng, M. Siegler, S. Parkin, M. Biermann, P. A. Crooks
  (S)-1-(2-Chlorophenyl)-2-oxocyclohexan-1-aminium D-tartrate
  Acta Cryst. E (2011), 67, 736. Link


• 60 | J. A. van Rijn, E. Gouré, M. A. Siegler, A. L. Spek, E. Drent, E. Bouwman
  The intriguing substitution behavior of CO with bidentate phosphine ligands induced by a gem-dialkyl effect
  J. Organ. Chem. (2011), 696, 1899-1903. Link


• 59 | D. K. Moon, A. Tripathi, D. Sullivan, M. A. Siegler, S. Parkin, G. H. Posner
  A single, low, oral dose of a 5-carbon-linked trioxane dimer orthoester plus mefloquine cures malaria-infected mice
  Bioorg. Med. Chem. Lett. (2011), 21, 2773-2775. Link


• 58 | M. A. Siegler, S. Parkin, R. J. Angel, C. P. Brock
  Detailed study of the phase transition in [Ni(H₂O)₆](NO₃)₂^.(15-crown-5)^.H₂O and analysis in terms of mean-field theory
  Acta Cryst. B (2011), 67, 130-143. Link


• 57 | W. I. Dzik, A. L. Fuente, M. A. Siegler, A. L. Spek, J. N. H. Reek, B. de Bruin
  Open-Shell Organometallic [MII(dbcot(bislutidylamine)]²⁺ Complexes (M = Rh, Ir): Unexpected Base-Assisted Reduction of the Metal Instead of Amine Ligand Deprotonation
  Organometallics (2011), 30, 1902-1913. Link


• 56 | D. J. M. Snelders, M. A. Siegler, L. von Chrzanowski, A. L. Spek, G. van Koten, R. J. M. Klein Gebbink
  Coulombic inter-ligand repulsion effects on the Pt(II) coordination chemistry of oligocationic, ammonium-functionalized triarylphosphines
  Dalton Trans. (2011), 40, 2588-2600. Link


• 55 | D. Achey, S. Ardo, H-L. Xia, M. A. Siegler and G. J. Meyer
  Sensitization of TiO₂ by the MLCT Excited State of Co(I) Coordination Compounds
  J. Phys. Chem. Lett. (2011), 2, 305-308. Link


• 54 | R. L. Peterson, R. A. Himes, H. Kotani, T. Suenobu, L. Tian, M. A. Siegler, E. I. Solomon, S. Fukuzumi, K. D. Karlin
  Cupric-Superoxo Mediated Inter-Molecular C-H Activation Chemistry
  J. Am. Chem. Soc. (2011), 133, 1702-1705. Link


• 53 | S. Long, M. A. Siegler, A. Mattei, T. Li
  Phase Transition from Two Z' = 1 Forms to a Z' = 2 Form of a Concomitant Conformational Polymorphic System
  Cryst. Growth & Des. (2011), 11, 414-421. Link


• 52 | Y. M. Badiei, M. A. Siegler, D. P. Goldberg
  O₂ Activation by Bis(imino)pyridine Iron(II)-Thiolate Complexes
  J. Am. Chem. Soc. (2011), 133, 1274-1277. Link

2010

• 51 | J. Li, M. Siegler, M. Lutz, A. L. Spek, R. J. M. Klein Gebbink and G. van Koten
  PCN- and PCS-Pincer Palladium Complexes as Tandem Catalysts in Homoallylation Reactions
  Adv. Synth. Catal. (2010), 352, 2474-2488. Link


• 50 | S. Bonnet, M. A. Siegler, J. H. van Lenthe, M. Lutz, A. L. Spek, G. van Koten, R. J. M. Klein Gebbink
  Ruthenium-to-Platinum Interactions in η⁶,η¹ NCN-Pincer Arene Heterobimetallic Complexes: an Experimental and Theoretical Study
  Eur. J. Inorg. Chem. (2010), 29, 4667-4677. Link


• 49 | D. T. Genna, C. P. Hencken, M. A. Siegler, G. H. Posner
  α-Chloro-β,γ-Ethylenic Esters: Enantiocontrolled Synthesis and Substitutions
  Org. Lett. (2010), 12, 4694-4697. Link


• 48 | Y. Jiang, L. R. Widger, G. D. Kasper, M. A. Siegler, D. P. Goldberg
  Iron(II)-Thiolate S-Oxygenation by O₂: Synthetic Models of Cysteine Dioxygenase
  J. Am. Chem. Soc. (2010), 132, 12214-12215. Link


• 47 | M. A. Siegler, S. Bonnet, A. M. M. Schreurs, R. J. M. Klein Gebbink, G. van Koten, A. L. Spek
  On the two closely related phases of [Ru(C₅Me₅)(η⁶-1,3-(Me₂NCH₂)₂C₆H₄)](BF₄) and the reversible solid-solid order-disorder phase transition
  J. Chem. Cryst. (2010), 40, 753-760. Link


• 46 | M. A. Siegler, E. Stavitski
  On the sequence of three related phases of [Ni(H₂O)₂(15-crown-5)](HSO₄)₂ in the T-range 110-295 K
  Acta Cryst. B (2010), 66, 430-440. Link


• 45 | J. Meeuwissen, R. Detz, A. J. Sandee, B. de Bruin, M. A. Siegler, A. L. Spek, J. N. H. Reek
  Ureaphosphanes as Hybrid, Anionic or Supramolecular Bidentate Ligands for Asymmetric Hydrogenation Reactions
  Eur. J. Inorg. Chem. (2010), 19, 2992-2997. Link


• 44 | J. Wassenaar, M. A. Siegler, A. L. Spek, B. de Bruin, J. N. H. Reek, J. I. van der Vlugt
  Versatile New C₃-Symmetric Tripodal Tetraphosphine Ligands; Structural Flexibility to Stabilize Cu^I and Rh^I Species and Tune Their Reactivity
  Inorg. Chem. (2010), 49, 6495-6508. Link


• 43 | A. Caruso Jr., M. A. Siegler, J. D. Tovar
  Synthesis of Functionalizable Boron-Containing -Electron Materials that Incorporate Formally Aromatic Fused Borepin Rings
  Angew. Chem. Int. Ed. (2010), 49, 4213-4217. Link


• 42 | M. Rubio, M. A. Siegler, A. L. Spek, J. N. H. Reek
  Heterotopic silver-NHC complexes: from coordination polymers to supramolecular assemblies
  Dalton Trans. (2010), 39, 5432-5435. Link


• 41 | J. Meeuwissen, A. J. Sandee, B. de Bruin, M. A. Siegler, A. L. Spek, J. N. H. Reek
  Phosphinoureas: Cooperative Ligands in Rhodium-Catalyzed Hydroformylation? On the Possibility of a Ligand-Assisted Reductive Elimination of the Aldehyde
  Organometallics (2010), 29, 2413-2421. Link


• 40 | J. Wassenaar, E. Jansen, W-J. van Zeist, F. M. Bickelhaupt, M. A. Siegler, A. L. Spek, J. N. H. Reek
  Catalyst selection based on intermediate stability measured by mass spectrometry
  Nat. Chem. (2010), 2, 417-421. Link


• 39 | M. A. Siegler, J. H. Prewitt, S. P. Kelley, S. Parkin, J. P. Selegue, C. P. Brock
  More examples of the 15-crown-5^...H₂O-M-OH₂^...15-crown-5 motif, M = Al³⁺, Cr³⁺ and Pd²⁺
  Acta Cryst. B (2010), 66, 213-221. Link


• 38 | Y. Cabon, H. Kleijn, M. A. Siegler, A. L. Spek, R. J. M. Klein Gebbink, B-J. Deelman
  Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands
  Dalton Trans. (2010), 39, 2423-2427. Link


• 37 | J. Wassenaar, B. de Bruin, M. A. Siegler, A. L. Spek, J. N. H. Reek, J. I. van der Vlugt
  Activation of H₂ by a highly distorted RhII complex with a new C₃-symmetric tripodal tetraphosphine ligand
  Chem. Commun. (2010), 46, 1232-1234. Link


• 36 | G. Berthon-Gelloz, M. A. Siegler, A. L. Spek, B. Tinanta, J. N. H. Reek, I. E. Markó
  IPr* an easily accessible highly hindered N-heterocyclic carbene
  Dalton Trans. (2010), 39, 1444-1446. Link

2009

• 35 | J. I. van der Vlugt, M. A. Siegler, M. Janssen, D. Vogt, A. L. Spek
  A Cationic Ag^I(PNP^tBu) Species Acting as PNP Transfer Agent: Facile Synthesis of Pd(PNP^tBu)(alkyl) Complexes and Their Reactivity Compared to PCP^tBu Analogues
  Organometallics (2009), 28, 7025-7032. Link


• 34 | J. A. van Rijn, M. A. Siegler, A. L. Spek, E. Bouwman, E. Drent
  Ruthenium-Diphosphine-Catalyzed Allylation of Phenols: A gem-Dialkyl-Type Effect Induces High Selectivity toward O-Allylation
  Organometallics (2009), 28, 7006-7014. Link


• 33 | Y. Lee, G-Y. Park, H. R. Lucas, P. L. Vajda, K. Kamaraj, M. A. Vance, A. E. Milligan, J. S. Woertink, M. A. Siegler, A. A. Narducci Sarjeant, L. N. Zakharov, A. L. Rheingold, E. I. Solomon, K. D. Karlin
  Copper(I)/O₂ Chemistry with Imidazole Containing Tripodal Tetradentate Ligands Leading to µ-1,2-Peroxo-Dicopper(II) Species
  Inorg. Chem. (2009), 48, 11297-11309. Link


• 32 | M. Rubio, E. Jellema, M. A. Siegler, A. L. Spek, J. N. H. Reek, B. de Bruin
  Supramolecular NHC ligands: on the influence of ZnII-templates on the activity of RhI(cod) complexes in 'carbene polymerization'
  Dalton Trans. (2009), 41, 8970-8976. Link


• 31 | M. A. N. Virboul, M. Lutz, M. A. Siegler, A. L. Spek, G. van Koten, R. J. M. Klein Gebbink
  One-Pot Synthesis and Immobilisation of Sulfonate-Tethered N-Heterocyclic Carbene Complexes on Polycationic Dendrimers
  Chem. Eur. J. (2009), 15, 9981-9986. Link


• 30 | J. Li, M. A. Siegler, M. Lutz, A. L. Spek, R. J. M. Klein Gebbink, G. van Koten
  Chiral ortho-Palladated and -Platinated Arylphosphite Complexes
  Organometallics (2009), 28, 5323-5332. Link


• 29 | S. Warsink, P. Hauwert, M. A. Siegler, A. L. Spek, C. J. Elsevier
  Palladium(0) pre-catalysts with heteroditopic NHC-amine ligands by transmetallation from their silver(I) complexes
  Appl. Organometal. Chem. (2009), 23, 225-228. Link


• 28 | R. Angamuthu, L. L. Gelauff, M. A. Siegler, A. L. Spek, E. Bouwman
  A molecular cage of nickel(II) and copper(I): a [{Ni(L)₂}₂(CuI)₆] cluster resembling the active site of nickel-containing enzymes
  Chem. Commun. (2009), 19, 2700-2702. Link


• 27 | F. W. Patureau, S. de Boer, M. Kuil, J. Meeuwissen, PA. R. Breuil, M. A. Siegler, A. L. Spek, A. J. Sandee, B. de Bruin, J. N. H. Reek
  Sulfonamido-Phosphoramidite Ligands in Cooperative Dinuclear Hydrogenation Catalysis
  J. Am. Chem. Soc. (2009), 131, 6683-6685. Link


• 26 | J. Wassenaar, S. van Zutphen, G. Mora, P. Le Floch, M. A. Siegler, A. L. Spek, J. N. H. Reek
  INDOLPhosphole and INDOLPhos Palladium-Allyl Complexes in Asymmetric Allylic Alkylations
  Organometallics (2009), 28, 2724-2734. Link


• 25 | S. Bonnet, J. Li, M. A. Siegler, L. S. von Chrzanowski, A. L. Spek, G. van Koten, R. J.M. Klein Gebbink
  Synthesis and Resolution of Planar-Chiral Ruthenium-Palladium Complexes with ECE' Pincer Ligands
  Chem. Eur. J. (2009), 15, 3340-3343. Link


• 24 | S. Bonnet, J. H. van Lenthe, M. A. Siegler, A. L. Spek, G. van Koten, R. J. M. Klein Gebbink
  Bimetallic η⁶, η¹ NCN-Pincer Ruthenium Palladium Complexes with η⁶-RuCp Coordination: Synthesis, X-ray Structures, and Catalytic Properties
  Organometallics (2009), 28, 2325-2333. Link


• 23 | S. Bonnet, G. Molnár, J. Sánchez Costa, M. A. Siegler, A. L. Spek, A. Bousseksou, W. Fu, P. Gamez, J. Reedijk
  Influence of Sample Preparation, Temperature, Light, and Pressure on the Two-Step Spin Crossover Mononuclear Compound [Fe(bapbpy)(NCS)₂]
  Chem. Mater. (2009), 21, 1123-1136. Link


• 22 | M. A. Siegler, M. Lutz
  Ni(salen): a System That Forms Many Solvates with Interacting Ni Atoms
  Cryst. Growth & Des. (2009), 9, 1194-1200. Link

2008

• 21 | M. A. Siegler, X. Hao, S. Parkin, C. P. Brock
  Five more phases of the structural family [M(H₂O)₂(15-crown-5)](NO₃)₂
  Acta Cryst. B (2008), 64, 738-749. Link


• 20 | M. A. Siegler, S. Parkin, J. P. Selegue, C. P. Brock
  The elusive [Ni(H₂O)(15-crown-5)]²⁺ cation and related co-crystals of Ni(II) hydrates and 15-crown-5
  Acta Cryst. B (2008), 64, 725-737. Link


• 19 | S. Bonnet, M. A. Siegler, J. Sánchez Costa, G. Molnár, A. Bousseksou, A. L. Spek, P. Gamez, J. Reedijk
  A two-step spin-crossover mononuclear iron(II) complex with a [HS-LS-LS] intermediate phase
  Chem. Commun. (2008), 43, 5619-5621. Link


• 18 | S. Long, S. Parkin, M. A. Siegler, A. Cammers, T. Li
  Polymorphism and Phase Behaviors of 2-(Phenylamino)nicotinic Acid
  Cryst. Growth & Des. (2008), 8, 4006-4013. Link


• 17 | S. Long, S. Parkin, M. Siegler, C. P. Brock, A. Cammers, T. Li
  Polymorphism of an Organic System Effected by the Directionality of Hydrogen-Bonding Chains
  Cryst. Growth & Des. (2008), 8, 3137-3140. Link


• 16 | SA. Garza-Ortiz, P. U. Maheswari, M. Siegler, A. L. Spek, J. Reedijk
  Ruthenium(III) Chloride Complex with a Tridentate Bis(arylimino)pyridine Ligand: Synthesis, Spectra, X-ray Structure, 9-Ethylguanine Binding Pattern, and In Vitro Cytotoxicity
  Inorg. Chem (2008), 47, 6964-6973. Link


• 15 | J. Chen, S. Subramanian, S. Parkin, M. Siegler, K. Gallup, C. Haughn, D. C. Martin, J. E. Anthony
  The influence of side chains on the structures and properties of functionalized pentacenes
  J. Mater. Chem. (2008), 63, 1961-1969. Link


• 14 | M. A. Siegler, H. Kooijman, A. L. Spek
  (S)-6-Methyl-ε-caprolactone
  Acta Cryst. E (2008), 64, 607. Link


• 13 | M. A. Siegler, H. Kooijmam, A. L. Spek
  (4aS,5R,7R,8S,8aR)-8-(1,3-Dioxolan-2-yl)-7,8-dimethyl-5-(1-methylethenyl)perhydronaphthalen-2one
  Acta Cryst. E (2008), 64, 337. Link

2007

• 12 | M. A. Siegler, Y. Fu, G. H. Simpson, D. P. King, S. Parkin, C. P. Brock
  An unexpected co-crystal with a variable degree of order: 1 :1 rac-1,2-cyclohexanediol/triphenylphosphine oxide
  Acta Cryst. B (2007), 63, 912-925. Link


• 11 | Y-H Xu, M. Siegler, S. Long
  (3aR,7aR)-Bis(4-nitrophenyl) 2-oxoperhydrobenzo[d]imidazole-1,3-dicarboxylate
  Acta Cryst. E (2007), 63, 3835. Link


• 10 | M. Zhong, M. Siegler, S. Long
  tert-Butyl N-[(1R,2R)-2-(isothiocyanato)-cyclohexyl]carbamate
  Acta Cryst. E (2007), 63, 3589. Link


• 9 | S. Long, M. Siegler, T. Li
  2,4,6-Trimethylbenzenaminium chloride
  Acta Cryst. E (2007), 63, 3080. Link


• 8 | V. N. Sonar, J. R. Ring, M. Siegler, P. A. Crooks
  (E)-1-[(2-Chlorophenyl)methyleneamino]guanidinium chloride
  Acta Cryst. E (2007), 63, 974-975. Link


• 7 | V. N. Sonar, S. Neelakantan, M. Siegler, P. A. Crooks
  (E)-1-[(2-Methoxyphenyl)methyleneamino]guanidinium chloride
  Acta Cryst. E (2007), 63, 535-536. Link


• 6 | S. Long, M. Siegler, T. Li
  6-Chloronicotinic acid
  Acta Cryst. E (2007), 63, 279-281. Link

2006

• 5 | S. Long, M. Siegler, T. Li
  2-Oxo-1,2-dihydropyridine-3-carboxylic acid
  Acta Cryst. E (2006), 62, 5664-5665. Link


• 4 | M. Siegler, S. Long
  (4R,5R)-4,5-Diphenylimidazolidin-2-one
  Acta Cryst. E (2006), 62, 5310-5311. Link


• 3 | S. Long, M. Siegler, T. Li
  N-(3-Chloro-2-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxamide
  Acta Cryst. E (2006), 62, 4278-4279. Link


• 2 | S. Long, M. Siegler, T. Li
  2-(2-Isopropylanilino)pyridine-3-carboxylic acid
  Acta Cryst. E (2006), 62, 4211-4213. Link

2005

• 1 | X. Hao, M. A. Siegler, S. Parkin, C. P. Brock
  [M(H₂O)₂(15-crown-5)](NO₃)₂: A System Rich in Polymorphic and Modulated Phases
  Cryst. Growth & Des. (2005), 5, 2225-2232. Link