"All we have discovered is that it starts with a single individual - always a child - and then spreads explosively, like the formation of crystals round the first nucleus in a saturated solution." Arthur C. Clarke (Childhood's End, 1953)



Publications

 
 


2017

  • 27 | G. Gezer, D. D. Jiménez, M. A. Siegler, E. Bouwman
    Synthesis and Characterization of Trinuclear [Ni2Ru] Complexes with Bridging Thiolate or Selenolate Donors for Electrocatalytic Proton Reduction
    Eur. J. Inorg. Chem. (2017), 2017, 5027-5032 - link
  • 26 | V. H. S. van Rixel, G. F. Moolenaar, M. A Siegler, L. Messori, S. Bonnet
    Controlling with light the interaction between trans tetrapyridyl ruthenium complexes and an oligonucleotide
    Dalton Trans. (2017), , Accepted Manuscript - link
  • 25 | R. E. Messersmith, S. Yadav, M. A. Siegler, H. Ottosson, J. D. Tovar
    Benzo[b]thiophene Fusion Enhances Local Borepin Aromaticity in Polycyclic Heteroaromatic Compounds
    J. Org. Chem (2017), , Just Accepted Manuscript - link
  • 24 | E. A. Marro, E. M. Press, T. K. Purkait, D. Jimenez, M. A. Siegler, R. S. Klausen
    Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides
    Chem. Eur. J. (2017), 23, 15633-15637 - link
  • 23 | L. Guan, M. G. Holl, C. R. Pitts, M. D Struble, M. A. Siegler, T. Lectka
    Through-space Activation can Override Substituent Effects in Electrophilic Aromatic Substitution
    J. Am. Chem. Soc. (2017), 139, 14913-14916 - link
  • 22 | S. Luo, M. A. Siegler, E. Bouwman
    Dinuclear Nickel Complexes of Thiolate-Functionalized Carbene Ligands and Their Electrochemical Properties
    Organometallics (2017), , Article ASAP - link
  • 21 | G. Gezer, S. Verbeek, M. A Siegler, E. Bouwman
    Nickel-Ruthenium-Based Complexes as Biomimetic Models of [NiFe] and [NiFeSe] Hydrogenases for Dihydrogen Evolution
    Dalton Trans. (2017), 46, 13590-13596 - link
  • 20 | J. P. T. Zaragoza, T. H. Yosca, M. A. Siegler, P. Moënne-Loccoz, M. T. Green, D. P. Goldberg
    Direct Observation of Oxygen Rebound with an Iron-Hydroxide Complex
    J. Am. Chem. Soc. (2017), 139, 13640-13643 - link
  • 19 | M. Devillard, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
    Transition-Metal-Free Cleavage of CO
    Chem. Eur. J. (2017), 23, 13628-13632 - link
  • 18 | D. D. Bume, C. R. Pitts, F. Ghorbani, S. A. Harry, J. N. Capilato, M. A. Siegler, T. Lectka
    Ketones as directing groups in photocatalytic sp3 C–H fluorination Disproportionation
    Chem. Sci. (2017), 8, 6918-6923 - link
  • 17 | G. B. Wijeratne, S. Hematian, M. A. Siegler, K. D. Karlin
    Copper(I) / NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex – Redox Reversal Giving Copper(I) / NO(g) Disproportionation
    J. Am. Chem. Soc. (2017), 139, 13276-13279 link
  • 16 | H. J. Jang, S. L. Hopkins, M. A. Siegler, Sylvestre Bonnet
    Frontier orbitals of photosubstitutionally active ruthenium complexes: an experimental study of the spectator ligands’ electronic properties influence on photoreactivity
    Dalton Trans. (2017), 46, 9969-9980 - link
  • 15 | B. Siewert, M. Langerman, Y. Hontani, J. T. M. Kennis, V. H. S. van Rixel, B. Limburg, M. A. Siegler, V. Talens Saez, R. E. Kieltyka, S. Bonnet
    Turning on the red phosphorescence of a [Ru(tpy)(bpy)(Cl)]Cl complex by amide substitution: self-aggregation, toxicity, and cellular localization of an emissive ruthenium-based amphiphile
    Chem. Commun. (2017), 53, 11126-11129 - link
  • 14 | R. Trammell, Y. Y. See, A. T. Herrmann, N. Xie, D. E. Díaz, M A. Siegler, P S. Baran, I. Garcia-Bosch
    Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp3 C–H Bonds
    J. Org. Chem. (2017), 82, 7887-7904 - link
  • 13 | G. Gezer, D. Durán Jiménez, M. A. Siegler, Elisabeth Bouwman
    Electrocatalytic proton reduction by a model for [NiFeSe] hydrogenases
    Dalton Trans. (2017), 46, 7506-7514 - link
  • 12 | V. Vreeken, L. Baij, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
    N-Atom transfer via thermal or photolytic activation of a Co-azido complex with a PNP pincer ligand
    Dalton Trans. (2017), 46, 7145-7149 - link
  • 11 | T. F. van Dijkman, H. M. de Bruijn, T. G. Brevé, B. van Meijeren, M. A. Siegler, E. Bouwman
    Extremely bulky copper(I) complexes of [HB(3,5-{1-naphthyl}2pz)3]– and [HB(3,5-{2-naphthyl}2pz)3]– and their self-assembly on graphene
    Dalton Trans. (2017), 46, 6433-4446 - link
  • 10 | J.A. Cuello-Garibo, E. Pérez-Gallent, L. van der Boon, M. A. Siegler, and Sylvestre Bonnet
    Influence of the Steric Bulk and Solvent on the Photoreactivity of Ruthenium Polypyridyl Complexes Coordinated to L-​Proline
    Inorg. Chem (2017), 56, 4818-4828 - link
  • 9 | V. Vreeken, M. A. Siegler, J. I. van der Vlugt
    Controlled Interconversion of a Dinuclear Au Species Supported by a Redox-Active Bridging PNP Ligand Facilitates Ligand-to-Gold Electron Transfer
    Chem. Eur. J. (2017), 23, 5585-5594 - link
  • 8 | B. Bagh, D. L. J. Broere, V. Sinha, P. F. Kuijpers, N. van Leest, B. de Bruin, S. Demeshko, M. A. Siegler, J. I. van der Vlugt
    Catalytic Synthesis of N-Heterocycles via Direct C(sp3)−H Amination using an Air-stable Iron(III) Species with a Redox-Active Ligand
    J. Am. Chem. Soc. (2017), 139, 5117-5124 - link
  • 7 | C. R. Pitts, M. A. Siegler, T. Lectka
    Intermolecular Aliphatic C–F···H–C Interaction in the Presence of “Stronger” Hydrogen Bond Acceptors: Crystallographic, Computational, and IR Studies
    J. Org. Chem. (2017), 82, 3996-4000 - link
  • 6 | J. Percino, M. Cerón, P. Venkatesan, P. Ceballos, A. Bañuelos, O. Rodríguez, M. A. Siegler, F. Robles, V. M. Chapela, G. Soriano-Moro, E. Pérez-Gutiérrez, J. Bonilla-Cruz, S. Thamotharan
    Two Different Emissions of (2Z)-2-(4-Bromophenyl)-3-[4-(dimethylamino)phenyl]prop-2-enenitrile Due to Crystal Habit and Size: Synthesis, Optical, and Supramolecular Characterization
    Cryst. Growth Des. (2017), 17, 1679-1694 - link
  • 5 | D. R. Levine, R. E. Messersmith, M. A. Siegler, J. D. Tovar
    Ring fusion isomers of dithienoborepins: perturbations of electronic structure, aromaticity, and reactivity in boron-containing polycyclic heteroaromatics
    Can. J. Chem. (2017), 95, 381-389 - link
  • 4 | C. R. Pitts, D. D. Bume, S. A. Harry, M. A. Siegler, T. Lectka
    Multiple Enone-Directed Reactivity Modes Lead to the Selective Photochemical Fluorination of Polycyclic Terpenoid Derivatives
    J. Am. Chem. Soc. (2017), 139, 2208-2211 - link
  • 3 | E. E. Joslin, J. P. T. Zaragoza , M. A. Siegler, D. P. Goldberg
    meso-N-Methylation of a porphyrinoid complex: activating the H-atom transfer capability of an inert ReV(O) corrolazine
    Chem. Commun. (2017), 53, 1961-1964 - link
  • 2 | S. M. Adam, I. Garcia-Bosch, A. W. Schaefer, S. K. Sharma, M. A. Siegler, E. I. Solomon, K. D. Karlin
    Critical Aspects of Heme-​Peroxo-​Cu Complex Structure and Nature of Proton Source Dictate Metal-​Operoxo Breakage versus Reductive O-​O Cleavage Chemistry
    J. Am. Chem. Soc. (2017), 139, 472-481 - link
  • 1 | E. M. Press, E. A. Marro, S. K. Surampudi, M. A. Siegler, J. A. Tang, R. S. Klausen
    Synthesis of a Fragment of Crystalline Silicon: Poly(Cyclosilane)
    Angew. Chem. Int. Ed. (2017), 56, 568-572 - link


2016

  • 33 | X. Liu, M. A. Siegler, M. Hilbers, E. Bouwman
    Synthesis, structure and photoluminescence properties of lanthanoid coordination polymers based on tetra(3,5-dicarboxyphenoxymethyl)methane
    Polyhedron (2016), 123, 1-8 - link
  • 32 | S. Sahu, B. Zhang, C. J. Pollock, M. Dürr, C. G. Davies, A. M. Confer, I. Ivanović-Burmazović, M. A. Siegler, G. N. L. Jameson, C. Krebs, D. P. Goldberg
    Aromatic C–F Hydroxylation by Nonheme Iron(IV)–Oxo Complexes: Structural, Spectroscopic, and Mechanistic Investigations
    J. Am. Chem. Soc. (2016), 138, 12791-12802 - link
  • 31 | M. J. Percino, M. Cerón, O. Rodríguez, G Soriano-Moro, M. E. Castro, V. M. Chapela, M. A. Siegler, E. Pérez-Gutiérrez
    Conformational and molecular structures of α,​β-​unsaturated acrylonitrile derivatives: photophysical properties and their frontier orbitals
    Molecules (2016), 21, 389/1-389/19 - link
  • 30 | I. Garcia-Bosch, M. A. Siegler
    Copper-​Catalyzed Oxidation of Alkanes with H2O2 under a Fenton-​like Regime
    Angew. Chem. Int. Ed. (2016), 55, 12873-12876 - link
  • 29 | S. Luo, M. A. Siegler, E. Bouwman
    Nickel Complexes of Pyridine-​Functionalized N-​Heterocyclic Carbenes: Syntheses, Structures, and Activity in Electrocatalytic Hydrogen Production
    Eur. J. Inorg. Chem. (2016), 2016, 4693-4700 - link
  • 28 | J. Percino, M. Cerón, P. Ceballos, G. Soriano-Moro, O. Rodríguez, V. M. Chapela, M. E. Castro, J. Bonilla-Cruz, Maxime A. Siegler
    Changes in the luminescence emission of α,β-unsaturated acrylonitrile derivatives: morphology, polymorphism and solvent effect
    CrystEngComm (2016), 18, 7554-7572 - link
  • 27 | D. L. J. Broere, R. Plessius, J. Tory, S. Demeshko, B. de Bruin, M. A. Siegler, F. Hartl, J. I. van der Vlugt
    Localized Mixed-Valence and Redox Activity within a Triazole-Bridged Dinucleating Ligand upon Coordination to Palladium
    Chem. Eur. J. (2016), 22, 13965-13975 - link
  • 26 | D. L. J. Broere, N. P. van Leest, B. de Bruin, M. A. Siegler, J. I. van der Vlugt
    Reversible Redox Chemistry and Catalytic C(sp3)–H Amination Reactivity of a Paramagnetic Pd Complex Bearing a Redox-Active o-Aminophenol-Derived NNO Pincer Ligand
    Inorg. Chem. (2016), 55, 8603-8611 - link
  • 25 | E. E. Joslin, J. P. T. Zaragoza, R. A. Baglia, M. A. Siegler, D. P. Goldberg
    The Influence of Peripheral Substituent Modification on PV, MnIII, and MnV(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivities
    Inorg. Chem. (2016), 55, 8646-8660 - link
  • 24 | M. D. Struble, L. Guan, M. A. Siegler, T. Lectka
    A C–F Bond Directed Diels–Alder Reaction
    J. Org. Chem. (2016), 81, 8087-8090 - link
  • 23 | L. S. Jongbloed, D. García-López, R. van Heck, M. A. Siegler, J. J. Carbó, J. I. van der Vlugt
    Arene C(sp2)-H Metalation at NiII Modeled with a Reactive PONCPh Ligand
    Inorg. Chem. Int. Ed. (2016), 55, 8041-8047 - link
  • 22 | V. Vreeken,D. L. J. Broere, A. C. H. Jans, M. Lankelma, J. N. H. Reek, M. A. Siegler, J. I. van der Vlugt
    Well-Defined Dinuclear Gold Complexes for Preorganization-Induced Selective Dual Gold Catalysis
    Angew. Chem. Int. Ed. (2016), 55, 10042-10046 - link
  • 21 | S. K. Sharma, H. Kim, P. J. Rogler, M. A. Siegler, K. D. Karlin
    Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization
    J. Biol. Inorg. Chem. (2016), 21, 729-743 - link
  • 20 | M. G. Holl, M. D. Struble, M. A. Siegler, T. Lectka
    The close interaction of a C-F bond with a carbonyl π–system: Attractive, repulsive, or both?
    J. Fluorine Chem. (2016), 188, 126-130 - link
  • 19 | B. Siewert, V. H. S. van Rixel, E. J. van Rooden, S. L. Hopkins, M. J. B. Moester, F. Ariese, M. A. Siegler, S. Bonnet
    Chemical Swarming: Depending on Concentration, an Amphiphilic Ruthenium Polypyridyl Complex Induces Cell Death via Two Different Mechanisms
    Chem. Eur. J. (2016), 22, 10960-10968 - link
  • 18 | R. C. Conyers, J. R. Mazzone, M. A. Siegler, G. H. Posner
    Highly regiocontrolled and stereocontrolled syntheses of polysubstituted aminocyclohexanes: mild inverse-electron-demand Diels–Alder cycloadditions of electrophilic 2-pyridones
    Tetrahedron Lett. (2016), 57, 3344-3348 - link
  • 17 | B. Bagh, D. L. J. Broere, M. A. Siegler, J. I. van der Vlugt
    Redox-Active-Ligand-Mediated Formation of an Acyclic Trinuclear Ruthenium Complex with Bridging Nitrido Ligands
    Angew. Chem. Int. Ed. (2016), 55, 8381-8385 - link
  • 16 | B. N. DiMarco, T. C. Motley, R. S. Balok, G. Li, M. A. Siegler, R. M O'Donnell, K. Hu, G. J. Meyer
    A Distance Dependence to Lateral Self-Exchange Across Nanocrystalline TiO2. A Comparative Study of Three Homologous RuIII/II Polypyridyl Compounds
    J. Phys. Chem. C,. (2016), 120, 14226-14235 - link
  • 15 | R. E. Messersmith, M. A. Siegler, J. D. Tovar
    Aromaticity Competition in Differentially Fused Borepin-Containing Polycyclic Aromatics
    J. Org. Chem. (2016), 81, 5595-5605 - link
  • 14 | R. Cao, C. Saracini, J. W. Ginsbach, M. T. Kieber-Emmons, M. A. Siegler, E. I. Solomon, S. Fukuzumi, K. D. Karlin
    RPeroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy
    J. Am. Chem. Soc. (2016), 138, 7055-7066 - link
  • 13 | X. Liu, M. A. Siegler, E. Bouwman
    Ratiometric Thermometer Based on a Lanthanoid Coordination Polymer
    Eur. J. Inorg. Chem. (2016), 2016, 2984-2988 - link
  • 12 | M. G. Holl, M. D. Struble, P. Singal, M. A. Siegler, T. Lectka
    Positioning a Carbon–Fluorine Bond over the π Cloud of an Aromatic Ring: A Different Type of Arene Activation
    Angew. Chem. Int. Ed. (2016), 55, 8266-8269 - link
  • 11 | V. H. S. van Rixel, B. Siewert, S. L. H. Hopkins, S. H.C. Askes, A. Busemann, M. A. Siegler, S. Bonnet
    Green light-induced apoptosis in cancer cells by a tetrapyridyl ruthenium prodrug offering two trans coordination sites
    Chem. Sci. (2016), 7, 4922-4929 - link
  • 10 | J. Jung, H. M. Neu, P. Leeladee, M. A. Siegler, K. Ohkubo, D. P. Goldberg, S. Fukuzumi
    Photocatalytic Oxygenation of Substrates by Dioxygen with Protonated Manganese(III) Corrolazine
    Inorg. Chem. (2016), 55, 3218-3228 - link
  • 9 | T. F. van Dijkman, M. A. Siegler, E. Bouwman
    Copper(I) Complexes of Naphthyl-Substituted Fluorinated Trispyr­azolylborate Ligands with Ethene and Carbon Monoxide
    Eur. J. Inorg. Chem. (2016), 2016, 2586-2594 - link
  • 8 | I. Garcia-Bosch, R. E. Cowley, D. E. Díaz, M A. Siegler, W. Nam, E. I. Solomon, K. D. Karlin
    Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2O2 Core with Unexpected Structure and Reactivity
    Chem. Eur. J. (2016), 22, 5133-5137 - link
  • 7 | A. C. McQuilken, H. Matsumura, M. Dürr, A. M. Confer, J/ P. Sheckelton, M. A. Siegler, T. M. McQueen, I. Ivanović-Burmazović, P. Moënne-Loccoz, D. P. Goldberg
    Photoinitiated Reactivity of a Thiolate-Ligated, Spin-Crossover Nonheme {FeNO}7 Complex with Dioxygen
    J. Am. Chem. Soc. (2016), 138, 3107–3117 - link
  • 6 | H. L. van de Wouw, J. Y. Lee, M. A. Siegler, R. S. Klausen
    Innocent BN bond substitution in anthracene derivatives
    Org. Biomol. Chem. (2016), 14, 3256-3263 - link
  • 5 | W. A. Phelan, S. M. Koohpayeh, P. Cottingham, J. A. Tutmaher, J. C. Leiner, M. D. Lumsden, C. M. Lavelle, X. P. Wang, C. Hoffmann, M. A. Siegler, N. Haldolaarachchige, D. P. Young, T. M. McQueen
    On the Chemistry and Physical Properties of Flux and Floating Zone Grown SmB6 Single Crystals
    Sci. Rep. (2016), 6, 20860 - link
  • 4 | D. L. J. Broere, D. K. Modde, E. Blokker, M. A. Siegler, J. I. van der Vlugt
    Metal–Metal Interactions in Heterobimetallic Complexes with Dinucleating Redox-Active Ligands
    Angew. Chem. Int. Ed. (2016), 55, 2406-2410 link
  • 3 | W.D. Kerber, J. T. Goheen, K. A. Perez, M. A. Siegler
    Enhanced Stability of the FeII/MnII State in a Synthetic Model of Heterobimetallic Cofactor Assembly
    Inorg. Chem. (2016), 55, 848–857 - link
  • 2 | S. Zheng, N. R. M. Reintjens, M. A. Siegler, O. Roubeau, E. Bouwman, A. Rudavskyi, R. W. A. Havenith, S Bonnet
    Stabilization of the Low-Spin State in a Mononuclear Iron(II) Complex and High-Temperature Cooperative Spin Crossover Mediated by Hydrogen Bonding
    Chem. Eur. J. (2016), 22, 331-339 - link
  • 1 | J. P. T. Zaragoza, M. A. Siegler, D. P. Goldberg
    Rhenium(V)–oxo corrolazines: isolating redox-active ligand reactivity
    Chem. Commun. (2016), 52, 167-170 - link


2015

  • 22 | T. F. van Dijkman, M. A. Siegler, E. Bouwman
    Highly tunable fluorinated trispyrazolylborates [HB(3-CF3-5-{4-RPh}pz)3]– (R = NO2, CF3, Cl, F, H, OMe and NMe2) and their copper(I) complexes
    Dalton Trans. (2015), 44, 21109-21123 - link
  • 21 | A. E. Pascui, K. van Rees, D. W. Zant, D. L. J. Broere, M. A. Siegler, J. I. van der Vlugt
    Macrocyclic Platinum(II) Complexes with a Bifunctional Diphosphine Ligand
    Eur. J. Inorg. Chem. (2015), 34, 5687-5693 - link
  • 20 | T. F. van Dijkman, H. M. de Bruijn, M. A. Siegler, E. Bouwman
    Bright Cyan Phosphorescence of a (Phosphane)copper(I) Complex of the Tri­hydrido­pyrazolylborate Ligand H3B(3,5-Ph2Pz)
    Eur. J. Inorg. Chem. (2015), 2015, 5387-5394 - link
  • 19 | R. A. Baglia, K. A. Prokop-Prigge, H. M. Neu, M. A. Siegler, D. P. Goldberg
    Mn(V)(O) versus Cr(V)(O) Porphyrinoid Complexes: Structural Characterization and Implications for Basicity Controlling H-Atom Abstraction
    J. Am. Chem. Soc. (2015), 137, 10874-10877 - link
  • 18 | M. D. Struble, M. Gargiulo Holl, M. T. Scerba, M. A. Siegler, T. Lectka
    Search for a Symmetrical C-F-C Fluoronium Ion in Solution: Kinetic Isotope Effects, Synthetic Labeling, Computational, Solvent and Rate Studies
    J. Am. Chem. Soc. (2015), 137, 11476-11490 - link
  • 17 | S. Hematian, I. Kenkel, T. E. Shubina, M. Dürr, J. J. Liu, M. A. Siegler, I. Ivanovic-Burmazovic, K. D. Karlin
    Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-FeIII–O–CuII(L) Constructs
    J. Am. Chem. Soc. (2015), 137, 6602-6615 - link
  • 16 | J. P. T. Zaragoza, R. A. Baglia, M. A. Siegler, D. P. Goldberg
    Strong Inhibition of O-Atom Transfer Reactivity for MnIV(O)(π-Radical-Cation)(Lewis Acid) versus MnV(O) Porphyrinoid Complexes
    J. Am. Chem. Soc. (2015), 137, 6531-6540 - link
  • 15 | V. Vreeken, M. A. Siegler, B. de Bruin, J. N. H. Reek, M. Lutz, J. I. van der Vlugt
    C-H Activation of Benzene by a Photoactivated NiII(azide): Formation of a Transient Nickel Nitrido Complex
    Angew. Chem. Int. Ed. (2015), 54, 7055-7059 - link
  • 14 | E.C.M. Ording-Wenker, M. A. Siegler, M. Lutz, E. Bouwman
    Catalytic Catechol Oxidation by Copper Complexes: Development of a Structure-Activity Relationship
    Dalton Trans. (2015), 44, 12196-12209 - link
  • 13 | H. M. Neu, J. Jung, R. A. Baglia, M. A. Siegler, K. Ohkubo, S. Fukuzumi, D. P. Goldberg
    Light-Driven, Proton-Controlled, Catalytic Aerobic C–H Oxidation Mediated by a Mn(III) Porphyrinoid Complex
    J. Am. Chem. Soc. (2015), 137, 4614-4617 - link
  • 12 | M. D. Struble, M. G. Holl, G. Coombs, M. A. Siegler, T. Lectka
    Synthesis of a Tight Intramolecular OH---Olefin Interaction, Probed by IR, 1H NMR and Quantum Chemistry
    J. Org. Chem. (2015), 80, 4803-4807 - link
  • 11 | P. Kumar, Y-M. Lee, Y J. Park, M. A. Siegler, K. D. Karlin, W. Nam
    Reactions of Co(III)–Nitrosyl Complexes with Superoxide and Their Mechanistic Insights
    J. Am. Chem. Soc. (2015), 137, 4284-4287 - link
  • 10 | D. L. J. Broere, S. Demeshko, B. de Bruin, E. A. Pidko, J. N. H. Reek, M. A. Siegler, M. Lutz, J. I. van der Vlugt
    Dinuclear Palladium Complexes with Two Ligand-CenteredRadicals and a Single Bridging Ligand: Subtle Tuning of MagneticProperties
    Chem. Eur. J. (2015), 21, 5879-5886 - link
  • 9 | X. Guo, J. Zhou, M. A. Siegler, A. E. Bragg, H. E. Katz
    Visible-Light-Triggered Molecular Photoswitch Based on Reversible E/Z Isomerization of a 1,2-Dicyanoethene Derivative
    Angew. Chem. Int. Ed. (2015), 54, 4782-4786 - link
  • 8 | S. Kim, J. W. Ginsbach, J. Yoon Lee, R. L. Peterson, J. J. Liu, M. A. Siegler, A. A. Sarjeant, E. I. Solomon, K. D. Karlin
    Amine Oxidative N-Dealkylation via Cupric Hydroperoxide Cu-OOH Homolytic Cleavage Followed by Site-Specific Fenton Chemistry
    J. Am. Chem. Soc. (2015), 137, 2867-2874 - link
  • 7 | S. Kim, J. Yoon Lee, R. E. Cowley, J. W. Ginsbach, M. A. Siegler, E. I. Solomon, K. D. Karlin
    A N3S(thioether)-Ligated CuII-Superoxo with Enhanced Reactivity
    J. Am. Chem. Soc. (2015), 137, 2796-2799 - link
  • 6 | E. C.M. Ording-Wenker, M. A. Siegler, E. Bouwman
    Coordination of new disulfide ligands to CuI and CuII: Does a CuIIμ-thiolate complex form?
    Inorg. Chim. Acta (2015), 428, 193-202 - link
  • 5 | S. Kakuda, C. Rolle, K. Ohkubo, M. A. Siegler, K. D. Karlin , S. Fukuzumi
    Lewis Acid-Induced Change from Four- to Two-Electron Reduction of Dioxygen Catalyzed by Copper Complexes Using Scandium Triflate
    J. Am. Chem. Soc. (2015), 137, 3330-3337 - link
  • 4 | S. Long, P. Zhou, K. L Theiss, M. A Siegler and T. Li
    Solid-State Identity of 2-Hydroxynicotinic Acid and Its Polymorphism
    CrystEngComm (2015), 17, 5195-5205 - link
  • 3 | S. Surampudi, M.-L. Yeh, M. A. Siegler, J. F. Martinez Hardigree, T. A. Kasl, H. E. Katz, R.S. Klausen
    Increased Carrier Mobility in End-Functionalized Oligosilanes
    Chem. Sci. (2015), 6, 1905-1909 - link
  • 2 | A. M. Fry, O. T. Sweeney, W. A. Phelan, N. Drichko, M A. Siegler, T. M. McQueen
    Unique edge-sharing sulfate-transition metal coordination in Na2M(SO4)2 (M=Ni and Co)
    J. Solid State Chem. (2015), 222, 129-135 - link
  • 1 | D. L. J. Broere, L. L. Metz, B. de Bruin, J. N. H. Reek, M. A. Siegler, J. I. van der Vlugt
    Redox-Active Ligand-Induced Homolytic Bond Activation
    Angew. Chem. Int. Ed. (2015), 54, 1516-1520 - link

2014

  • 22 | S. Hong, K. D. Sutherlin, J. Park, E. Kwon, M. A. Siegler, E. I. Solomon, W. Nam
    Crystallographic and spectroscopic characterization and reactivities of a mononuclear non-haem iron(III)-superoxo complex
    Nat. Commun. (2014), 5:5440, link
  • 21 | A. Khrimian, S. Shirali, K. E. Vermillion, M. A. Siegler, F. Guzman, K. Chauhan, J. R. Aldrich, D. C. Weber
    Determination of the Stereochemistry of the Aggregation Pheromone of Harlequin Bug, Murgantia histrionica
    J. Chem. Ecol. (2014), 40, 1260-1268 - link
  • 20 | S. Zheng, M. A. Siegler, O. Roubeau, S. Bonnet
    Influence of Selenocyanate Ligands on the Transition Temperature and Cooperativity of bapbpy-Based Fe(II) Spin-Crossover Compounds
    Inorg. Chem. (2014), 53, 13162-13173 - link
  • 19 | E. C. M. Ording-Wenker, M. van der Plas, M. A. Siegler, C. Fonseca Guerra, E. Bouwman
    Protonation of a Biologically Relevant CuII μ-Thiolate Complex: Ligand Dissociation or Formation of a Protonated CuI Disulfide Species?
    Chem. Eur. J. (2014), 51, 16913-16921 - link
  • 18 | W. D. Kerber, K. A. Perez, C. Ren, M. A. Siegler
    Speciation of Ferric Phenoxide Intermediates during the Reduction of Iron(III)−μ-Oxo Dimers by Hydroquinone
    Inorg. Chem. (2014), 53, 11507-11516 - link
  • 17 | S. Sahu, M. G. Quesne, C. G. Davies, M. Dürr, I. Ivanović-Burmazović, M. A. Siegler, G. N. L. Jameson, S. P. de Visser, D. P. Goldberg
    Direct Observation of a Nonheme Iron(IV)−Oxo Complex That Mediates Aromatic C−F Hydroxylation
    J. Am. Chem. Soc. (2014), 136, 13542-13545 - link
  • 16 | E. C.M. Ording-Wenker, M. van der Plas, M. A. Siegler, S. Bonnet, F. M. Bickelhaupt, C. Fonseca Guerra, E. Bouwman
    Thermodynamics of the CuII μ-Thiolate and CuI Disulfide Equilibrium: A Combined Experimental and Theoretical Study
    Inorg. Chem. (2014), 53, 8494-8504 - link
  • 15 | M. D. Struble, C. Kelly, M. A. Siegler, T. Lectka
    Search for a Strong, Virtually “No-Shift” Hydrogen Bond: A Cage Molecule with an Exceptional OH...F Interaction
    Angew. Chem. Int. Ed. (2014), 53, 8924-8928 - link
  • 14 | A. Khrimian, A. Zhang, D. C. Weber, H-Y. Ho, J. R. Aldrich, K. E. Vermillion, M. A. Siegler, S. Shirali, F. Guzman, T. C. Leskey
    Discovery of the Aggregation Pheromone of the Brown Marmorated Stink Bug (Halyomorpha halys) through the Creation of Stereoisomeric Libraries of 1-Bisabolen-3-ols
    J. Nat. Prod. (2014), 77, 1708-1717 - link
  • 13 | C. R. Pitts, S. Bloom, R. Woltornist, D. Auvenshine, L. R. Ryzhkov, M. A. Siegler, T. Lectka
    Direct, Catalytic Monofluorination of sp3 C H Bonds: A Radical-Based Mechanism with Ionic Selectivity
    J. Am. Chem. Soc. (2014), 136, 9780-9791 - link
  • 12 | M. J. Percino, M. Cerón, P. Ceballos, G. Soriano-Moro, M. E. Castro, V. M. Chapela, J. Bonilla-Cruz, M. Reyes-Reyes, R. López-Sandoval, M. A. Siegler
    Important role of molecular packing and intermolecular interactions in two polymorphs of (Z)​-​2-​phenyl-​3-​(4-​(pyridin-​2-​yl)​phenyl)​acrylonitrile. Preparation, structures, and optical properties
    J. Mol. Struct. (2014), 1078, 74-82 - link
  • 11 | S. Kim, J. W. Ginsbach, A. I. Billah, M. A. Siegler, C. D. Moore, E. I. Solomon, K. D. Karlin
    Tuning of the Copper-​Thioether Bond in Tetradentate N3S(thioether) Ligands; O-​O Bond Reductive Cleavage via a [CuII2(μ-​1,​2-​peroxo)​]​2+​/[CuIII2(μ-​oxo)​2]​2+ Equilibrium
    J. Am. Chem. Soc. (2014), 136, 8063-8071 - link
  • 10 | L. R. Widger, Y. Jiang, A. C. McQuilken, T. Yang, M. A. Siegler, H. Matsumura, P. Moenne-Loccoz, S. P. de Visser, D. P. Goldberg
    Thioether-​ligated iron(II) and iron(III)​-​hydroperoxo​/alkylperoxo complexes with an H-​bond donor in the second coordination sphere
    Dalton Trans. (2014), 43, 7522-7532 - link
  • 9 | D. R. Levine, M. A. Siegler, J. D. Tovar
    Thiophene-​fused borepins as directly functionalizable boron-​containing π-​electron systems
    J. Am. Chem. Soc. (2014), 136, 7132–7139 - link
  • 8 | A. Talanov, W. A. Phelan, Z. A. Kelly, M. A. Siegler, T. M. McQueen
    Control of the Iridium Oxidation State in the Hollandite Iridate Solid Solution K1-​xIr4O8
    Inorg. Chem. (2014), 53, 4500-4507 - link
  • 7 | S. Kim, M. A. Siegler, K. D. Karlin
    Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction
    Chem. Commun. (2014), 50, 2844-2846 - link
  • 6 | R. C. Conyers, J. R. Mazzone, M. A. Siegler, A. K. Tripathi, D. J. Sullivan, B. T. Mott, G. H. Posner
    The survival times of malaria-infected mice are prolonged more by several new two-carbon-linked artemisinin-derived dimer carbamates than by the trioxane antimalarial drug artemether
    Bioorg. Med. Chem. Lett. (2014), 24, 1285-1289 - link
  • 5 | L. R. Widger, C. G. Davies, T. Yang, M. A. Siegler, O. Troeppner, G. N. L. Jameson, I. Ivanovic-Burmazovic, D. P. Goldberg
    Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres
    J. Am. Chem. Soc. (2014), 136, 2699-2702 - link
  • 4 | S. Hematian, M. A. Siegler, K. D. Karlin
    Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity
    J. Biol. Inorg. Chem. (2014), 19, 515-528 - link
  • 3 | A. Garza-Ortiz, P. U. Maheswari, M. Lutz, M. A. Siegler, J. Reedijk
    Tuning the cytotoxic properties of new ruthenium(III) and ruthenium(II) complexes with a modified bis(arylimino)pyridine Schiff base ligand using bidentate pyridine-based ligands
    J. Biol. Inorg. Chem. (2014), 19, 675-689 - link
  • 2 | S. Akerboom, M. S. Meijer, M. A. Siegler, W. T. Fu, E. Bouwman
    Structure, photo- and triboluminescence of the lanthanoid dibenzoylmethanates: HNEt3[Ln(dbm)4]
    J. Lumin. (2014), 145, 278-282 - link
  • 1 | M. D. Struble, J. Strull, K. Patel, M. A. Siegler, T. Lectka
    Modulating 'Jousting' C-F---H-C interactions with a Bit of Hydrogen Bonding
    J. Org. Chem. (2014), 79, 1-6 - link


2013

  • 16 | S. Akerboom, Jos J. M. H. van den Elshout, I. Mutikainen, M. A. Siegler, W. T. Fu, E. Bouwman
    Substituted Phenanthrolines as Antennae in Luminescent EuIII Complexes
    Eur. J. Inorg. Chem. (2013), 2013, 6137-6146- link
  • 15 | E. C. M. Ording-Wenker, M. A. Siegler, M. Lutz, E. Bouwman
    CuI Thiolate Reactivity with Dioxygen: The Formation of CuII Sulfinate and CuII Sulfonate Species via a CuII Thiolate Intermediate
    Inorg. Chem. (2013), 52, 13113-13122 - link
  • 14 | R. L. Peterson, J. W. Ginsbach, R. E. Cowley, M. F. Qayyum, R. A. Himes, M. A. Siegler, C. D. Moore, B. Hedman, K. O. Hodgson, S. Fukuzumi, E. L. Solomon, K. D. Karlin
    Stepwise Protonation and Electron-Transfer Reduction of a Primary Copper-Dioxygen Adduct
    J. Am. Chem. Soc. (2013), 135, 16454-16467 - link
  • 13 | A. Garza-Ortiz, P. Uma Maheswari, M. Siegler, A. L. Spek, J. Reedijk
    A new family of Ru(II) complexes with a tridentate pyridine Schiff-base ligand and bidentate co-ligands: synthesis, characterization, structure and in vitro cytotoxicity studies
    New J. Chem. (2013), 37, 3450-3460 - link
  • 12 | R. D. Slack, M. A. Siegler, G. H. Posner
    Highly stereocontrolled and regiocontrolled syntheses of polyoxygenated [2.2.2]oxabicyclic synthons
    Tetrahedron Letters (2013), 54, 6267-6270 - link
  • 11 | A. C. McQuilken, Y. Ha, K. D. Sutherlin, M. A. Siegler, K. O. Hodgson, B. Hedman, E. I. Solomon, G. N. L. Jameson, D. P. Goldberg
    Preparation of Non-heme {FeNO}7 Models of Cysteine Dioxygenase: Sulfur versus Nitrogen Ligation and Photorelease of Nitric Oxide
    J. Am. Chem. Soc. (2013), 135, 10590-10593 - link
  • 10 | L. R. Widger, Y. Jiang, M. A. Siegler, D. Kumar, R. Latifi, S. P. de Visser, G. N. L. Jameson, D. P. Goldberg
    Synthesis and Ligand Non-Innocence of Thiolate-Ligated (N4S) Iron(II) and Nickel(II) Bis(imino)pyridine Complexes
    Inorg. Chem. (2013), 52, 10467−10480 - link
  • 9 | W. Ward, B. H. Farnum, M. A. Siegler, G. J. Meyer
    Chloride Ion-Pairing with Ru(II) Polypyridyl Compounds in Dichloromethane
    J. Phys. Chem. A (2013), 117, 8883−8894 - link
  • 8 | A. Bahreman, B. Limburg, M. A. Siegler, E. Bouwman, S. Bonnet
    Spontaneous Formation in the Dark, and Visible Light-Induced Cleavage, of a Ru-S Bond in Water: A Thermodynamic and Kinetic Study
    Inorg. Chem. (2013), 52, 9456-9469 - link
  • 7 | S. Oldenhof, B. de Bruin, M. Lutz, M. A. Siegler, F. Patureau, J. I. van der Vlugt, J. N. H. Reek
    Base-Free Production of H2 by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex
    Chem. Eur. J. (2013), 19, 11507-11511 - link
  • 6 | S. Sahu, L. R. Widger, M. G. Quesne, S. P. de Visser, H. Matsumura, P. Moenne-Loccoz, M. A. Siegler, D. P. Goldberg
    Secondary coordination sphere influence on the reactivity of nonheme iron(II) complexes: an experimental and DFT approach
    J. Am. Chem. Soc. (2013), 135, 10590-10593 - link
  • 5 | M. D. Struble, M. T. Scerba, M. Siegler and T. Lectka
    Evidence for a Symmetrical Fluoronium Ion in Solution
    Science (2013), 340, 57-60 - link
  • 4 | P. Leeladee, G. N. L. Jameson, M. A. Siegler, D. Kumar, Sam P. de Visser and D. P. Goldberg
    Generation of a High-Valent Iron Imido Corrolazine Complex and NR Group Transfer Reactivity
    Inorg. Chem. (2013), 52, 4668−4682 - link
  • 3 | L. R. Widger, M. A. Siegler and D. P. Goldberg
    Sulfide oxidation by O2: Synthesis, structure and reactivity of novel sulfide-incorporated Fe(II) bis(imino)pyridine complexes
    Polyhedron (2013), 58, 179−189 - link
  • 2 | B. T. Mott, A. Tripathi, M. A. Siegler, C. D. Moore, D. J. Sullivan and G. H. Posner
    Synthesis and Antimalarial Efficacy of Two-Carbon-Linked, Artemisinin-Derived Trioxane Dimers in Combination with Known Antimalarial Drugs
    J. Med. Chem, (2013), 56, 2630−2641 - link
  • 1 | S. Zheng, M. A. Siegler, J. C. Sanchez , W-T. Fu and S. Bonnet
    Effect of Metal Dilution on the Thermal Spin Transition of [FexZn1-x(bapbpy)(NCS)2]
    Eur. J. Inorg. Chem. (2013), 5-6, 1033−1042 - link


2012

  • 11 | S. Kim, C. Saracini, M. A. Siegler, N. Drichko, and K. D. Karlin
    Coordination Chemistry and Reactivity of a Cupric Hydroperoxide Species Featuring a Proximal H-Bonding Substituent
    Inorg. Chem. (2012), 51, 12603-12605 - link
  • 10 | S. Hematian, M. A. Siegler, and K. D. Karlin
    Heme/Copper Assembly Mediated Nitrite and Nitric Oxide Interconversion
    J. Am. Chem. Soc., (2012), 134, 18912-18915 - link
  • 9 | A. Yokoyama, J. E. Han, J. Cho, M. Kubo, T. Ogura, M. A. Siegler, K. D. Karlin, and W. Nam
    Chromium(IV)-Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity
    J. Am. Chem. Soc., (2012), 134, 15269-15272 - link
  • 8 | A. Bahreman, B. Limburg, M. A. Siegler, R. Koning, A. J. Koster and S. Bonnet
    Ruthenium Polypyridyl Complexes Hopping at Anionic Lipid Bilayers through a Supremolecular Bond Sensitive to Visible Light
    Chem. Eur. J. (2012), 18, 10271−10280 - link
  • 7 | R. A. Ghiladi, A. L. Rheingold, M. A. Siegler and K. D. Karlin
    Synthesis and characterization of new trinuclear copper complexes
    Inorg. Chim. Acta (2012), 389, 131−137 - link
  • 6 | D. R. Levine, A. Caruso, M. A. Siegler and J. D. Tovar
    Meta-B-entacenes: new polycyclic aromatics incorporating two fused borepin rings
    Chem. Commun. (2012), 48, 6256−6258- link
  • 5 | A. C. McQuilken, Y. Jiang, M. A. Siegler and D. P. Goldberg
    Addition of Dioxygen to an N4S(thiolate) Iron(II) Cysteine Dioxygenase Model Gives a Structurally Characterized Sulfinato-Iron(II) Complex
    J. Am. Chem. Soc. (2012), 134, 8758−8761- link
  • 4 | W. B. Heuer, H-L. Xia, W. Ward, Z. Zhou, W. H. Pearson, M. A. Siegler, A. A. Narducci Sarjeant, M. Abrahamsson and G. J. Meyer
    New Dicarboxylic Acid Bipyridine Ligand for Ruthenium Polypyridyl Sensitization of TiO2
    Inorg. Chem. (2012), 51, 3981-3988 - link
  • 3 | Y. M. Badiei, Y. Jiang, L. R. Widger, M. A. Siegler and D. P. Goldberg
    Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: Unexpected transmetalation mediated by LiAlH4
    Inorg. Chim. Acta (2012), 382, 19−26 - link
  • 2 | M. Scerba, S. Bloom, N. Haselton, M. Siegler, J. Jake and T. Lectka
    Interaction of a C-F Bond with the pi-System of a C=C Bond or "Head On" with a Proximate C-H Bond
    J. Org. Chem. (2012), 134, 1962−1965 - link
  • 1 | D. Guthrie, N. Kim, M. Siegler, C. Moore and J. Toscano
    Development of N-Substitued Hydroxylamines as Efficient Nitroxyl (HNO) Donors
    J. Am. Chem. Soc. (2012), 134, 1962−1965 - link


2011

  • 8 | Z. Arcis-Castíllo, S. Zheng, M. A. Siegler, O. Roubeau, S. Bedoui and S. Bonnet
    Tuning the Transition Temperature and Cooperativity of bapbpy-Based Mononuclear Spin-Crossover Compounds: Interplay between Molecular and Crystal Engineering
    Chem. Eur. J. (2011), 17, 14826−14836 - link
  • 7 | M. T. Scerba, C. M. Leavitt, M. E. Diener, A. F. DeBlase, T. L. Guasco, M. A. Siegler, N. Bair, M. A. Johnson and T. Lectka
    NH+−F Hydrogen Bonding in a Fluorinated "Proton Sponge" Derivative: Integration of Solution, Solid-State, Gas-Phase, and Computational Studies
    J. Org. Chem. (2011), 76, 7975−7984 - link
  • 6 | R. E. Goldbach, I. Rodriguez-Garcia, J. H. van Lenthe, M. A. Siegler and S. Bonnet
    N-Acetylmethionine and Biotin as Photocleavable Protective Groups for Ruthenium Polypyridyl Complexes
    Chem. Eur. J. (2011), 17, 9924−9929- link
  • 5 | C. P. Hencken, D. T. Genna, M. A. Siegler and G. H. Posner
    Highly Stereocontrolled and Regiocontrolled Syntheses of 2,3,4-Trisubstituted Alkanoates and Lactones
    J. Org. Chem. (2011), 76, 5149−5155 - link
  • 4 | D. Achey, S. Ardo, H–L. Xia, M. A. Siegler and G. J. Meyer
    Sensitization of TiO2 by the MLCT Excited State of Co(I) Coordination Compounds
    J. Phys. Chem. Lett. (2011), 2, 305−308 - link
  • 3 | R. L. Peterson, R. A. Himes, H. Kotani, T. Suenobu, L. Tian, M. A. Siegler, E. I. Solomon, S. Fukuzumi and K. D. Karlin
    Cupric-Superoxo Mediated Inter-Molecular C-H Activation Chemistry
    J. Am. Chem. Soc. (2011), 133, 1702−1705 - link
  • 2 | Y. M. Badiei, M. A. Siegler and D. P. Goldberg
    O2 Activation by Bis(imino)pyridine Iron(II)−Thiolate Complexes
    J. Am. Chem. Soc. (2011), 133, 1274−1277 - link
  • 1 | D. K. Moon, A. Tripathi, D. Sullivan, M. A. Siegler, S. Parkin and G. H. Posner
    A single, low, oral dose of a 5-carbon-linked trioxane dimer orthoester plus mefloquine cures malaria-infected mice
    Bioorg. Med. Chem. Lett. (2011), 21, 2773−2775 - link


2010

  • 5 | D. T. Genna, C. P. Hencken, M. A. Siegler and G. H. Posner
    α-Chloro-β,γ-Ethylenic Esters: Enantiocontrolled Synthesis and Substitutions
    Org. Lett. (2010), 12, 4694-4697 - link

  • 4 | Y. Jiang, L. R. Widger, G. D. Kasper, M. A. Siegler and D. P. Goldberg
    Iron(II)-Thiolate S-Oxygenation by O2: Synthetic Models of Cysteine Dioxygenase
    J. Am. Chem. Soc. (2010), 132, 12214-12215 - link

  • 3 | M. A. Siegler and E. Stavitski
    On the sequence of three related phases of [Ni(H2O)2(15-crown-5)](HSO4)2 in the T-range 110-295 K
    Acta Cryst. (2010), B66, 430-440 - link

  • 2 | M. A. Siegler, S. Bonnet, A. M. M. Schreurs, R. J. M. Klein Gebbink, G. van Koten & A. L. Spek
    On the two closely related phases of [Ru(C5Me5)(η6-1,3-(Me2NCH2)2C6H4)](BF4) and the reversible solid-solid order-disorder phase transition
    J. Chem. Cryst. (2010), 40, 753-760 - link

  • 1 | A. Caruso Jr., M. A. Siegler and J. D. Tovar
    Synthesis of Functionalizable Boron-Containing -Electron Materials that Incorporate Formally Aromatic Fused
    Borepin Rings
    Angew. Chem. Int. Ed. (2010), 49, 4213−4217. Link


2009

  • 1 | Y. Lee, G-Y. Park, H. R. Lucas, P. L. Vajda, K. Kamaraj, M. A. Vance, A. E. Milligan, J. S. Woertink, M. A. Siegler, A. A. Narducci Sarjeant, L. N. Zakharov, A. L. Rheingold, E. I. Solomon and K. D. Karlin
    Copper(I)/O2 Chemistry with Imidazole Containing Tripodal Tetradentate Ligands Leading to μ-1,2-Peroxo-Dicopper(II) Species
    Inorg. Chem. (2009), 48, 11297−11309. Link